科碧恩.普拉克-環(huán)境及食安危機(jī)下中國聚乳酸工業(yè)的第二期發(fā)展及挑戰(zhàn)

3/26/2024

科碧恩-普拉克(中國)涂浩明

2015-12上海HaomingTu環(huán)境及食安危機(jī)下中國聚乳酸工業(yè)的

第二期發(fā)展及挑戰(zhàn)

3/26/20242Challengetotraditionpolymerindustry

-傳統(tǒng)橡塑行業(yè)面臨的挑戰(zhàn)PlasticPollution¬sustainable(consumepetrochemicalresource)

白色污染且非可持續(xù)發(fā)展（消耗石化資源）3/26/20243PlasticPollution-白色污染3/26/20244Challengetotraditionpolymerindustry

-傳統(tǒng)橡塑行業(yè)面臨的挑戰(zhàn)Debateonfoodcontactsafetyandbodycontactsafety

爭議-食品接觸安全及人體接觸安全ConcernsaboutStyrene(關(guān)于苯乙烯類塑料制品食品接觸安全的憂慮)3/26/20245“Lastmonth,76scientistswroteajointlettertoCongress

notingthattheWorldHealthOrganizationalsolistedformaldehydeasaknowncarcinogen,andstyreneasapossiblecarcinogen.TheydefendedtheReportonCarcinogensas“consistentwithinternationalscientificconsensus.”**ExtractfromthelettertoCongress:“StyreneisregulatedasaHazardousAirPollutantbyEPA,andconsideredpossiblycarcinogenictohumansbytheWorldHealthOrganization.The12thROClistingofstyreneas“reasonablyanticipatedtobeahumancarcinogen”isconsistentwithinternationalscientificconsensusregardingstyrene’stoxicity.“TheCancerLobbyBy

NICHOLASD.KRISTOFPublished:October6,20123/26/20246ConcernsaroundStyrene

ECHA/RAC:Damagingtheunbornchild

苯乙烯單體對胎兒的危害EuropeanChemicalAgency(ECHA)NewsAlert:By

CommitteeforRiskAssessment(RAC)

Helsinki,07December2012

“RACagreedtoclassifystyreneascausingdamagetothehearingorgansthroughprolongedorrepeatedexposureviainhalationandasasubstancesuspectedofdamagingtheunbornchild““ForbotheffectstheRACopiniondeviatedfromtheproposalfromDenmarkwhohadoriginallyproposedtoclassifystyreneascausingdamagetothenervoussystemthroughprolongedorrepeatedexposureviainhalationandasasubstancewhichmaydamagetheunbornchild.“http://echa.europa.eu/view-article/-/journal_content/c89bdb13-09e9-497c-8e73-ddae13a842c83/26/20247MOPS:MovingoutofPolyStyrene(&ABS)

(Globalmarket>10milliontons)

脫離苯乙烯類塑料運(yùn)動(dòng)：千萬噸市場規(guī)模

MajorPSusersconsider“movingoutofPS”duetothefood/healthsafetyconcerns,styrene/PSprice,sustainability,etc.PLA(rigid)andPP(soft/flexible)aretheircandidatestoreplacePS,ABS,etc.Styreneproducersstopexpansionorshutdownoldplantsduetosafetyconcernsonstyreneasapotentialcarcinogenicchemical.Pricegoesupto1.6USD/kg.PS：Pricegoesto~1.90Euro/kg(~2.4USD/kg)inEuropeduetoshortageandtherisingpriceofstyrene.PSpriceinAsiaisstilllownow.November7,2012

[Source:ICISnews]:EuropeanstyrenepricesareexpectedtosoarfollowingShellChemicals'declaration

offorcemajeureonstyreneatitsMoerdijksite.3/26/20248Concernsaboutmelaminetableware…….

關(guān)于密胺（三聚氰胺-甲醛樹脂）餐具食品接觸安全的憂慮新聞圖片：遭查封的密胺餐具在更換產(chǎn)品標(biāo)簽后再次流入市場，繼續(xù)銷售(京華時(shí)報(bào)2009年)新聞圖片:(密胺)“置物盤”勿當(dāng)餐具使用(網(wǎng)易新聞2012年)2015年8月起,“臺(tái)北市政府各機(jī)關(guān)、學(xué)校之辦公廳舍及校區(qū)推動(dòng)禁用一次性及美耐皿餐具”。危害:(1)2009年臺(tái)灣市售美耐皿餐具100%均檢出三聚氰胺析出。

(2)2011年高雄醫(yī)學(xué)大學(xué)職業(yè)安全衛(wèi)生研究所指出美耐皿餐具是島內(nèi)三成人

三聚氰胺暴露的主要來源.

(3)臺(tái)灣衛(wèi)生與福利部認(rèn)為，雖然美耐皿餐具三聚氰胺析出島內(nèi)標(biāo)準(zhǔn)為2.5ppm，

但在使用過程中，三聚氰胺析出會(huì)在人體中不斷積累，三聚氰胺析出也將

隨著餐具老化而增加甚至超標(biāo),實(shí)際上2.5ppm的標(biāo)準(zhǔn)難以執(zhí)行！MelaminetablewareisforbiddenbyTaipeiGovernment3/26/20249臺(tái)北市長柯文哲出席

“友善臺(tái)北好餐具標(biāo)章”活動(dòng)內(nèi)容來源：http:///cn/newspapers/20150723000491-260102http:///tw/tw-mswx/news/2009/06-01/1715325.shtml/xw/twxw/2011/10/2621363.htmlhttp:///s?wd=paperuri%3A%284a9ef55e63fa35e15ba0d816001181bc%29&filter=sc_long_sign&sc_ks_para=q%3D%E7%BE%8E%E8%80%90%E7%9A%BF%E9%A4%90%E5%85%B7%E6%BA%B6%E5%87%BA%E9%AB%98%E6%BF%83%E5%BA%A6%E4%B8%89%E8%81%9A%E6%B0%B0%E8%83%BA%E4%B9%8B%E7%9B%B8%E9%97%9C%E7%A0%94%E7%A9%B6&tn=SE_baiduxueshu_c1gjeupa&ie=utf-8http:///cn/realtimenews/20150723002957-260407CorbionPuracPLAcradletocradlelifecycle3/26/202410Bio-based生物質(zhì)來源

Bio-degradable生物可降解

3/26/202411Whatisbioplastic？什么是生物高分子Bio-basedOil-based(fossilfuel)BiodegradableNotBiodegradablePLAPHA(PHB,PHBV…)PPC(~30%biocontent)bio-PETbio-PPBio-PEStarchblends

(PP/starch,PE/starch,~20-30%biocontent)PBATPBS,PBSAPTTPCL

PETPPPEPSABSPVCBioplasticproperty&pricematrix3/26/202412Bioplasticneat

resinRemarkMarket

priceHeatperformanceTensilestrengthElongationatbreakPLLA(highopticalpurity

PLA)Bio-based,100%biocontent,Biodegradable,~18-20

rmb/kg~100-110C(HDT-B)*crystalline~50Mpa~3%PLA(mediumorlowopticalpurity)Bio-based,100%biocontent,Biodegradable,~16-18rmb/kg~50-60C(HDT-B)*amorphous~50Mpa~3%PHA(PHB,PHBV…)Bio-based,100%biocontent,Biodegradable,~35rmb/kg

<85C(VicatVST)~15-30Mpa~10-700%PBAT(PBS,PBSA…)Oil-based,0%biocontent,Biodegradable~25-30rmb/kg

<90

C(VicatVST)~35

MPa~500-700%PPCPartialbio-based,~30%biocontent,Biodegradable~25rmb/kg~45-50C(VicatVST)

>10MPa>30%PP/StarchPE/StarchPartialbio-based,~20-30%biocontent,Notbiodegradable~10-15rmb/kg~85-110C(VicatVST)~15-30MPa>20%3/26/202413GlobalPLAsales:Doubledevery3-4yearsNatureWorks70KTline150KT140KTPLASalesvolume=10KT×2(calendaryear-2003)/3PLAvolumedoubledevery3-4years!CorbionisPuracBiochem+CaravanIngredients+(former)CSMHolding

公司總部位于荷蘭阿姆斯特丹GlobalMarketLeaderinLacticAcid全球乳酸行業(yè)領(lǐng)先者Naturalpreservation&fortificationforFood

(食品)BiobasedingredientsforChemical&Pharma(化學(xué)醫(yī)藥中間體）MonomersforBioplastics(生物塑料)>80yearsofexperience80多年發(fā)展歷程

IntroducingCorbion–科碧恩簡介

Biobasedproducts,poweredbynature,designedbyscience,&deliveredthroughourdedication3/26/2024141983PuracintroducesPLAforthebiomedicalmarket

PURAC醫(yī)用級(jí)PLA投入市場20085kTpaLactideMonomersplantinBarcelona,Spain

西班牙5kt丙交酯工廠投產(chǎn)201275kTpaLactideMonomersplantinRayong,Thailand

泰國75kt丙交酯工廠投產(chǎn)

Globalpresence–科碧恩公司全球分布3/26/202415CorbionPurac’sroleinthePLAvaluechain–科碧恩聚乳酸市場戰(zhàn)略

3/26/202416TechnologyPushDevelopPLApolymerizationWorkwithpartnersonPLAApp’sSupportconversionofPLASugarfeedstockLA&LactideproductionPLApolymerproductionCompoundproductionConversiontoproductsBrandownerRetailerConsumerPartnershipsDevelopmentofPLAsupplychainDevelopmentofmarketsandapplicationsCorefocus-Scale&capacity,costleadership-Best-in-classprocessingtechnology-ApplicationsupportNEWCorbionworkswithandsupportsallplayersinthePLAvaluechainTechnologyPushDevelopPLApolymerizationWorkwithpartnersonPLAApp’sSupportconversionofPLAMarketPullPLApromotion&communicationCreatesustainabilityawarenessWorkwithleadingCorps&(N)GOsHigh-quality,Low-costlactide

高性價(jià)比丙交酯原料單體Madefromnon-GMOrawmaterials非轉(zhuǎn)基因原料單體來源FastPLLAcrystallizationrate高光純PLLA具有較高結(jié)晶速率HighheatperformancePLLA高光純PLLA具有更好耐熱性能PLLApotentialforgooddurability高光純PLLA具有開發(fā)耐久應(yīng)用的潛力UniquePDLAnucleatingtechnology獨(dú)特的高光純PDLA成核劑技術(shù)Advantagesofhighopticalpurity(>99.8%)L&DLactide

高光純L型及D型丙交酯–高光純聚乳酸原料單體3/26/202417協(xié)助推廣開發(fā)聚乳酸產(chǎn)品市場PLAPolymerization:Hisun,Hengtian-Yangtze,Jiuding,SUPLA…聚乳酸合成：海正，恒天長江，九鼎，允友成….PLAcompounding&applicationdevelopment:PolyAlloy,XinDa,RongSolar,Nanyi….

聚乳酸共混改性研發(fā)：臺(tái)灣盛聚，哈爾濱鑫達(dá)，江蘇榮晟，浙江南益….PLAtechnology&innovation:CAS-Beijing,CAS-Ningbo,SichuanUNIV,JiangnanUNIV

聚乳酸技術(shù)創(chuàng)新：中科院北京化學(xué)所，中科院寧波材料所,四川大學(xué)，江南大學(xué)OtherPartners:EsunBrightChina,XinFu

………

其他合作伙伴:易生光華偉業(yè),鑫富，榮盛…..Corbion-Purac’sPLAapplicationdevelopmentpartnerinChina

科碧恩-普拉克在中國的聚乳酸應(yīng)用開發(fā)合作伙伴3/26/202418期待更多合作伙伴！19ConfidentialChinaBioPlasticProjects:Phase1(2014)

PLA:2-10

KT

PHBV

group:1-10KT

PBS/ATgroup:2-20KT

PPC/PBC:1-10KTStarch-blending:>10KT鑫富PBS/AT天安PHBV遠(yuǎn)東PBAT金發(fā)PBSA/T和興PBS意可曼P3/4HB天冠PPC中科金龍PPC中海油PPC國韻P3/4HB九鼎PLA海正PLA蒙西PPC漢豐Starch比奧格Starch長江化纖PLA華麗Starch宏力Starch

三房巷PBC臺(tái)州邦豐PPC華盛PBS/AT金輝PBS/AT屯河PBS/AT同杰良PLA匯盈PBS/ATLimitedPLAproducers:MainlyNatureworks(import),Hisun5KTsmallplants.

聚乳酸樹脂生產(chǎn)廠：NatureWorks(進(jìn)口),國內(nèi)海正為主，其他小廠試生產(chǎn)LimitedPLAfiberproducers:MainlyFENCimporting,FIT(XingNeng/XingGao),BWC,CL

聚乳酸纖維生產(chǎn)廠：遠(yuǎn)東紡織(進(jìn)口),國內(nèi)以新能新高為主，無紡布：必可成，昌隆LimitedlocalGovernmentsupport:onPLAproduction,notPLAmarket

中國政府補(bǔ)貼：以聚乳酸生產(chǎn)為主，而非市場應(yīng)用

ManyPLAproducers:Hisun,Hengtian-Yangtze,Jiuding,SUPLA,Foxconn,COFCO,TJL,…多個(gè)聚乳酸廠及技術(shù)：海正，恒天長江，九鼎，允友成

，富士康，中糧，同杰良

….SOE,10Kscale,governmentregulation,supplychain,compoundingplants,non-wovenfiber

央企介入，萬噸級(jí)廠，吉林江蘇限塑法規(guī)，供應(yīng)鏈建立，共混廠,無紡布/纖維…..ChinaPLAindustry:Phase1(2004-2014)entersPhase2(2015-2020)

中國聚乳酸產(chǎn)業(yè):從第一期(2004-2014)進(jìn)入第二期(2015-2020)3/26/202420群雄并起，進(jìn)入井噴期Phase1:FocusonPLAproductiontechnologybottleneck解決聚乳酸生產(chǎn)技術(shù)瓶頸Phase2:NeedtofocusonPLAmarketandapplication需以聚乳酸的市場及應(yīng)用為主ConfidentialChinaLA/PLA/Fiberphase2:100KTscale2016-2017:接近十萬噸樹脂/纖維允友成SUPLA光華偉業(yè)EsunBC杲信GaoXin中糧COFCO富士康Foxconn海正Hisun昌隆ChLn新能新高FIT/Cha前沿QianYan必可成BWC遠(yuǎn)東化纖FENC曦茂XiMao龍都LongDuYangtze恒天

長江Hengtian同杰良TJL金丹JinDan中糧格拉特B&G百盛BaiSheng豆丁BendsL玉之潤YZR美亞AP武藏野MSN金玉米GoldenC九鼎Jiuding新寧XinNing3/26/202422ChinaPLA/FiberPhase2:ApplicationTechnologyTrends（聚乳酸應(yīng)用技術(shù)趨勢）

PLAcompounding,branching,&copolymerizationtechnologydevelopment

聚乳酸的共混改性,交聯(lián),共聚技術(shù)的開發(fā)ApplicationofPLLAcompoundforhighendsemi-durableparts&tableware

(3C/automotive/foodcontactsafety…)e.g.replacingmelaminetableware

高光純聚乳酸改性料在高端半耐久產(chǎn)品,如餐具等領(lǐng)域應(yīng)用

（3C/汽車/食品接觸安全…)如取代美耐皿餐具ApplicationofPLAfilmblowing/PLAmulchfilm/BOPLAfilm/castingfilmetc…聚乳酸吹膜，農(nóng)地膜，雙向拉伸膜及流延膜的應(yīng)用及改進(jìn)ApplicationofPLAextrusionfoamingandmouldingfoaming(replacingEPS)

聚乳酸擠出發(fā)泡及模壓發(fā)泡的應(yīng)用(取代EPS)ApplicationofPLAfiberanddisposiblenon-wovenhygienefabrics聚乳酸纖維及無紡布一次性衛(wèi)材制品的應(yīng)用

PLAisafamilyof(co-)polymers–聚乳酸簡介3/26/202423R-enantiomer(D)S-enantiomer(L)PDLA(103)175°C

160°CPLAcopolymer>10%RinPLAAmorphousNoTmIncreasingTmandcrystallinityStereoblockPLA(31)200°CStereocomplexPLAStereo

complexPLA

(31)230°CPLLA(103)BasedonPLAhomo-polymers均聚物PLAco-polymers共聚物ImprovedPLAperformanceopensuphighaddedvaluemarkets

不斷提高的聚乳酸材料性能使其應(yīng)用向高附加值領(lǐng)域拓展3/26/202424DisposablesSemi-durablesTimeValue&PerformanceDurablesProgressinPolymerScience37(2012)1657-1677EffectsofopticalpurityandmolecularweightonTgandMAX.crystallinityofPLA–光學(xué)純度和分子量對Tg和最大結(jié)晶度的影響3/26/202425光純越高，Tg相對較高當(dāng)Mn>100kg/mol,Tg保持不變分子量降低&光純提高最大結(jié)晶度及結(jié)晶速率提高RecommendationofPLAgradesfordifferentprocessingtechnologies--適用于不同加工條件下的聚乳酸分子量區(qū)間3/26/202426薄壁注塑注塑吸塑&片材擠出流動(dòng)性結(jié)晶速率最大結(jié)晶度纖維Molecularweightloss&moisturetake-upspeedofPLAversustime–聚乳酸水解降解速率&吸水速率

3/26/202427ProgressinPolymerScience33(2008)820-852CorbionPLAprocessingguidelineTemperature>Tgandwithhighhumidity,FASTPLAhydrolysisdegradation溫度高于Tg時(shí)，快速水解降解Moisturecontentfrom50ppmto250ppmafter15min水分含量從50ppm到250ppm僅需15minCorbionrangeofPDLAresins:PURAPOLD070nucleatingadditiveto

reducecycletimePURAPOLD130forstereocomplexPLA

Benefits:HighstereochemicalpurityFoodcontactapprovedUsingGMOfreebiomassBiobasedPDLAhomopolymerresins–CorbionPurac--PDLA樹脂3/26/202428PDLAresin–drivingperformancePSPVCABSPCPETHDPELDPEPPPLAPLLA/PDLA成核體系Increasingheatperformance立構(gòu)復(fù)合體系PLLA/PDLAAmorphous CrystallineSugarfeedstockLA&LactideproductionPLApolymerproductionCompoundproductionConversiontoproductsBrandownerRetailerConsumer3/26/2024PLLAhomopolymerresin–Hisun--PLLA樹脂Hisun

rangeofPLLAresins:Revode290forInjectionmoldingRevode190

forextrusion&injectionmoldingBenefits:PLLAHighstereochemicalpurityFoodcontactapprovedUsingGMOfreebiomassBiobasedCompostable(EN13432)HisunRevodeproductrange3/26/202430ClosingtheperformancegapvsPS,PP&ABS–PLLA/PDLA共混改性體系熱變形溫度缺口沖擊強(qiáng)度BlendsofPLLA&PDLA

-developmentalsamplesareavailablefortesting-ProcessingHighHeatPLA:Crystallinitydevelopmentininjectionmoldedpart(1mmthick)vs.coolingtime

–PDLA成核體系實(shí)現(xiàn)聚乳酸耐熱制品的快速結(jié)晶3/26/2024325s10s15s20s30s40sDSCoverlayofmineralfilledn-PLLAatdifferentmoldcoolingtimes,

Tmold

100°C,samplesquenchedincoldwaterHighheatPLAT-sensitivePLAmoldcoolingtimes2.5mm

thickness3/26/202433Effectofnucleatingpackageandmoldtemperatureoncrystallizationtime–PDLA成核體系

注塑模具溫度與結(jié)晶時(shí)間關(guān)系Optimummoldcoolingcondition

dependsonformulationandpartgeometryPDLAnucleationallowslowermoldTforthickerpartsPDLAnucleationalways

upto2xfasterwaterimmersiontest@90oCDurabilityevaluationbywaterimmersiontest–水浴老化測試3/26/202434Retentionofmechanicalproperties>50%after72hrswaterimmersiontest@90oC水浴老化測試72小時(shí)，力學(xué)性能保留率>50%CustomertestsofkitchenproductmadewithCorbionPuracBlendB:injectionmoldingtosemi-crystallinePLA–聚乳酸注塑餐具評(píng)估實(shí)驗(yàn)3/26/202435SampleTest1Mold60°C2Mold20°C3Mold20°C

+

30min@100°C4Mold100°CSinkmarks縮痕NoNoNoNo1mheightfalltest(afterIM,Microwaveanddishwashertest)跌落測試OKOKOKOKStaining染色性測試RemovableRemovableRemovableRemovableMicrowavetest(H2O)

微波爐測試OKOKOKOKDishwasher50cycles洗碗機(jī)測試50個(gè)周期FairlyOKNOKNottestedOKScratchresistance耐刮擦測試BetterthanPPBetterthanPPBetterthanPPBetterthanPPCupdimensions:approx.?10cmand20cmheightBenefitsHighheatresistanceBiobased&recyclableExcellenthighglossfinishExcellentimpactresistanceHighdimensionalstabilityallowsfortighttolerancesAdditionalPartners:PLAhousingsforconsumerelectronics–聚乳酸

注塑產(chǎn)品在電子領(lǐng)域的應(yīng)用3/26/202436TheworldsfirstPLAtouchscreencomputerSugarfeedstockLA&LactideproductionPLApolymerproductionCompoundproductionConversiontoproductsBrandownerRetailerConsumerCompoundsmadeforCorbionbyaGermanresearchinstituteNaturalFibers30%NFloadingMatrixmaterials:PLLAL130–PLLAhomopolymerBlendA–NucleatedPLLAblendbyPDLABlendC–Impactmodified,nucleatedPLLAbyPDLANaturalFiberfilledPLAcompounds–聚乳酸/天然纖維復(fù)合材料3/26/202437SugarfeedstockLA&LactideproductionPLApolymerproductionCompoundproductionConversiontoproductsBrandownerRetailerConsumerExcellentHeatPerformanceof30%NF-filledCorbioncompoundsbasedonsemi-crystallinePLLA–30%天然纖維填充聚乳酸復(fù)合材料耐熱性能3/26/202438高耐熱溫度HDT-B160°C,HDT-A>80°C缺口沖擊強(qiáng)度6.5kJ.m-2Benefits:ReducedcarbonfootprintDimensionstabilityThermalresistanceupto140°CwithfiberreinforcementShockresistancedownto-40°CAgeing,chemical&hydrolysisresistanceVerygoodcolorability,naturallookwithbio-fillersScratchresistanceImpactresistanceUVresistance3/26/202439PLAforautomotiveparts–聚乳酸/天然纖維復(fù)合材料在汽車配件領(lǐng)域的應(yīng)用PLAParts:courtesyofR?chlingAirfilterhousingandinteriorautomotivetrimcomponentsNaturalfiberfilledPLABenefits:BiobasedHighheatresistanceRecyclableGoodprocessingeconomicsCanbeprocessedonexistingPSlinesPLAforhighheatthermoforming