科技化工設(shè)計1 4 1附錄一物料平衡書

醋酸鉀為助催化劑的固定床反應器，在0.78MPa，136-185℃溫度下，氣相氧化如表3-1所示：鹽MoleMassVolumeCVapor0000Liquid1111Solid0000----Mass ----Enthalpy ----Molar----KMass CAL/GM-----Molar Mass AverageMolecularComponentMass3.58E-1.41E-01.09E-04.21E-09.25E-9.75E-5.66E-1.57E-4.11E-2.63E-2.77E-6.00E-1.73E-04.53E-CO3-5.04E-01.20E-1.05E-SO3-SO4-HPO4-PO4-- 7.75E- 3.13E- 6.70E- 7.16E-ComponentMass2.07E-2.19E-1.43E-4.69E-4.99E-02.35E-3.61E-6.69E-04.87E-1.40E-3.70E-05.45E-3.07E-1.21E-5.96E-1.47E-1.88E-1.24E-2.51E-2.03E-9.20E-1.72E-1.02E-4.73E-9.54E-4.28E-3.67E-2.29E-5.75E-1.81E-03.80E-1.51E-4.24E-CO3-4.00E-09.26E-3.50E-SO3-SO4-HPO4-PO4--1.68E-1.75E-8.92E-1.24E-6.15E-1.91E-5.19E-2.38E-MoleMassVolumeC53Vapor010Liquid101Solid0000Molar ---Mass ---Enthalpy ---Molar CAL/MOL----Mass CAL/GM----Molar Mass AverageMolecularComponentMass 000 0 000 000 000 002.99E-0 009.58E-0CO3- 005.84E-0 008.77E-0 00 000ComponentMass00001000000000001.22E-0003.93E-0CO3-002.39E-0003.60E-0100000MoleMassVolumeCVapor 001Liquid 100Solid 010Molar ---Mass ---Enthalpy --7.22E--Molar CAL/MOL- ---Mass CAL/GM- ---Molar Mass AverageMolecular ComponentMass 000 000 00 000 000 000 00 00ComponentMass 000 000 100 000 000 000 010品Mole品Mole

廢氣處 有機廢MassVolumeC33Vapor10010Liquid0101Solid00000Molar -----Mass -----Enthalpy -----Molar CAL/MOL-------Mass CAL/GM-------Molar Mass AverageMolecularComponentMass8.43E-9.91E-1.55E-2.41E-9.16E-2.22E-2.92E-7.48E-9.21E-9.18E-4.31E-2.75E-2.29E-8.58E-7.83E-8.32E-8.21E-00000tMass3.63E-1.08E-1.04E-9.98E-6.12E-2.98E-3.23E-1.00E-1.19E-2.91E-1.99E-2.36E-7.98E-3.59E-8.94E-2.32E-000000品MoleMassVolumeCVapor001001Liquid11010Solid00000Molar ------Mass ------Enthalpy ------Molar------KMass CAL/GM-------Molar Mass AverageMolecularComponentMass 3.24E-1.11E-3.64E-3.10E-7.40E- 1.10E-01.09E-8.81E-00 02.56E-1.86E- 2.45E-6.41E- 1.02E-06.90E-0 0000 1.69E-4.75E-01.29E-0 1.02E-00CO3- 1.30E-01.68E-4.62E-0SO3- 4.81E-01.62E-0 9.74E-01.58E-2.89E-0ComponentMassComponentMass4.47E-2.88E-3.87E-9.96E-2.02E-2.06E-02.84E-9.37E-001.62E-01.39E-8.22E-5.06E-7.98E-3.37E-4.31E-2.06E-6.06E-1.40E-06.20E-2.21E-000003.16E-6.55E-09.41E-4.13E-01.41E-01.39E-0CO3-2.42E-01.79E-1.48E-0SO3-8.99E-1.73E-01.73E-01.82E-01.68E-9.26E-000000MoleMassVolumeCVapor001001Liquid11010Solid00000Molar ------Mass ------Enthalpy ------MolarK------MassCAL/GM-------MolarMassAverageMolecular 22.86236 MoleMassVolumeC53Vapor10010010Liquid01101001Solid00000100Molar------Mass------Enthalpy---2.62E--7.22E---MolarCAL/MOL-------MassCAL/GM-------MolarMassAverageMolecularComponentMass 3.58E-000003.24E- 000000 0000000 0000002.45E- 0000 9.75E-000001.02E- 00000 4.11E-000000 000000 6.00E-000000 000000 0000004.75E- 000001.02E-CO3- 000000SO3- 00000SO4- 000000HPO4- 000000PO4-- 000000 3.13E-00000 000000 000000 000000ComponentMass 2.19E-000004.47E- 0010000 0000000 0000003.37E- 00100 5.96E-000001.40E- 00000 2.51E-00000001.02E-00000003.67E-000000000000000000006.55E-04.24E-000001.41E-CO3-0000000SO3-0000001.73E-SO4-0000000HPO4-0000000PO4--01.75E-00000001.91E-000000010000000000010000001004-9全流程物料衡算表（出口）（一品Mole品MoleMassVolumeC3Vapor01001Liquid1010Solid000000Molar ------Mass ------Enthalpy ------Molar CAL/MOL-------Mass CAL/GM-------Molar Mass AverageMolecularComponentMass1.41E-08.43E-9.91E-1.09E-1.55E-2.41E-9.16E-2.22E-4.21E-00000

9.25E-00000 5.66E-2.99E-00000 4.53E-9.58E-00000 000000CO3- 1.05E-5.84E-00000SO3- 000000SO4- 000000HPO4- 000000PO4-- 000000 7.16E-8.77E-00000 07.48E-9.21E- 09.18E-4.31E- 02.75E-2.29E-8.58E- 08.32E-8.21E- 00000ComponentMass 4.69E-03.63E-1.08E- 3.61E-1.04E-9.98E-6.12E- 1.40E-00000 3.07E-00000 1.88E-1.22E-00000 000000 9.20E-000000 9.54E-000000 5.75E-000000 000000 1.51E-3.93E-00000 000000CO3- 3.50E-2.39E-00000SO3- 000000SO4- 000000HPO4- 000000PO4-- 1.24E-000000 2.38E-3.60E-00000 03.23E-1.00E- 01.19E- 02.91E-1.99E-2.36E- 03.59E-8.94E- Mole Mass Volume 13Vapor101001Liquid01010Solid00000Molar ------Mass ------Enthalpy ------Molar CAL/MOL------Mass CAL/GM------Molar Mass AverageMolecularComponentMass 1.11E-3.64E-3.10E-7.40E- 2.92E-1.09E-8.81E-00 02.56E-1.86E- 06.41E- 0006.90E-0 00000 1.11E-00000 1.79E-00000 000000 000000 0001.29E-0 0000CO3- 0001.68E-4.62E-0SO3- 0001.62E-00001.58E-2.89E-000000000000000007.83E-000000000ComponentMass1.89E-2.88E-3.87E-9.96E-2.02E-2.98E-2.84E-9.37E-0001.39E-8.22E-5.06E-04.31E-2.06E-6.06E-0006.20E-2.21E-0000003.86E-000006.22E-000000009.