池州學(xué)院作品 揚(yáng)子石化年產(chǎn)5.5萬(wàn)噸醋酸乙烯酯項(xiàng)目附件2-物料衡算計(jì)算書(shū).docx

1、2019 “東華科技-恒逸石化杯” 第十三屆全國(guó)大學(xué)生化工設(shè)計(jì)競(jìng)賽彳石化揚(yáng)&石北年/ 5.5萬(wàn)噸醋酸乙烯酯項(xiàng)目團(tuán)隊(duì)成員：孫少 阮友咨 趙嘉欣、曾若男、胡譯文 指導(dǎo)老師：王余杰、周阿洋、馬田林、馮建華、陳綱領(lǐng)質(zhì)量流量kg/hr19535.519535.5c2h4kg/hr10446.37936.7702kg/hr1472.0640.191CH3COOHkg/hr6819.161447.79VACkg/hr314.1758014.49H2Okg/hr483.6322095.31CO2kg/hr3.16E-05584.8645n2kg/hr00C3H4Okg/hr0.006278240.00

2、627824C3H6O2kg/hr0.002445120.00244512C4H8O2kg/hr0.03241770.0324177CH3CHOkg/hr0.1759520.175952C6H10O4kg/hr0.03372250.0337225C3H8O3kg/hr00HCO3-kg/hr00CO32-kg/hr00MEAkg/hr1.86E-101.86E-10MEA+kg/hr00MEACOO-kg/hr00H3O+kg/hr00OH'kg/hr00表3-6反應(yīng)器1<01匹物料衡算INOUTStream Name單位R01010UTR0102OUT相態(tài)汽相汽相溫度°

3、;C165165.098壓力kPag750750質(zhì)量汽相分率11質(zhì)量液相分率00質(zhì)量固相分率00質(zhì)量流量kg/hr1598815988c2h4kg/hr5288.115287.7902kg/hr16.342616.1629CH3COOHkg/hr130.753130.276VACkg/hr8239.628239.62H2Okg/hr2312.392312.46CO2kg/hr584.8645584.8645n2kg/hr00C3H4Okg/hr0.002078030.040256C3H6O2kg/hr0.0008137040.0260366c4h8o2kg/hr0.00419680.38786

4、5CH3CHOkg/hr0.05975050.284742C6H10O4kg/hr0.01324240.162521C3H8O3kg/hr00HCO3-kg/hr00CO32-kg/hr00MEAkg/hr1.57E-081.57E-08MEA+kg/hr00MEACOO-kg/hr00H3O+kg/hr00OH'kg/hr00塔設(shè)備（T0101）表3-7 T0101物料衡算Stream Name單位INOUTPOIOIOUTV0102GAST0101DT0101W相態(tài)液相汽相汽相液相溫度°C22.229160.3301151.697172.657壓力kPag16001100

5、850880質(zhì)量汽相分率0110質(zhì)量液相分率1001質(zhì)量固相分率0000質(zhì)量流量kg/hr6245.88238.814544.530.0611c2h4kg/hr07814.27814.050.14685402kg/hr014.097214.09725.09E-05CH3COOHkg/hr5566.230.280645537.3729.1401VACkg/hr0489.371488.7750.596337H20kg/hr679.40810.7793690.1590.0282344C02kg/hr00.22860. 22863.30E-08n2kg/hr0000C3H4Okg/hr00.00207

6、90.0020781.30E-06C3H6O2kg/hr00.0008140.0008145.82E-07C4H8O2kg/hr00.0042030.0041976.16E-06CH3CHOkg/hr00.0597650.0597511.44E-05C6HI0O4kg/hr0.16252100.0132420.149279C3H8O3kg/hr0000HCO3-kg/hr0000CO32-kg/hr0000MEAkg/hr1.57E-080.0002341.57E-080.000233751MEA+kg/hr0000MEACOO-kg/hr0000H3O+kg/hr0000OH'kg/

7、hr00003.1.5 儲(chǔ)罐(V010LV0103)表3-8 V0101物料衡算Stream Name單位X0101OUTV0101GASV0101LIQ相態(tài)液相液相溫度°C40.12320壓力kPag300100質(zhì)量汽相分率00質(zhì)量液相分率11質(zhì)量固相分率00質(zhì)量流量kg/hr6245.86245.8c2h4kg/hr1.91E-33002kg/hr2.85E-550ch3coohkg/hr5566.235566.23VACkg/hr5.95E-370h2okg/hr679.408679.408co2kg/hr1.44E-390n2kg/hr00C3H4Okg/hr1.80E-33

8、0C3H6O2kg/hr3.65E-340C4H8O2kg/hr5.51E-400CH3CHOkg/hr4.11E-390C6H10O4kg/hr0.1625210.162521C3H8O3kg/hr00HCO3-kg/hr00CO32-kg/hr00MEAkg/hr1.57E-081.57E-08MEA+kg/hr00INOUTMEACOO'kg/hr00H3O+kg/hr00OH-kg/hr00表3-9 V0102物料衡算Stream Name單位X0102OUTV0102GASV0102LIQ相態(tài)汽相汽相溫度°C60.330160.3301壓力kPag15001100質(zhì)

9、量汽相分率11質(zhì)量液相分率00質(zhì)量固相分率00質(zhì)量流量kg/hr8328.88328.8c2h4kg/hr7814.27814.2O2kg/hr14.097214.0972CH3COOHkg/hr0.280640.28064VACkg/hr489.371489.371H2Okg/hr10.779310.7793CO2kg/hr0.002286480.00228648n2kg/hr00C3H4Okg/hr0. 2079340. 207934C3H6O2kg/hr0.0008142860.000814286C4H8O2kg/hr0.004202970.00420297CH3CHOkg/hr0.05

10、976490.0597649C6H10O4kg/hr00C3H8O3kg/hr00HCO3-kg/hr00INOUTCO32-kg/hr00MEAkg/hr0.0002337510.000233751MEA+kg/hr00MEACOO-kg/hr00H3O+kg/hr00OH-kg/hr00表3-10 V0103物料衡算OUTStream Name單位02V0103GASV0103LIQ相態(tài)汽相汽相溫度°C4040壓力kPag12001100質(zhì)量汽相分率11質(zhì)量液相分率00質(zhì)量固相分率00質(zhì)量流量kg/hr1443.471443.47c2h4kg/hr0002kg/hr1443.47

11、1443.47CH3COOHkg/hr00VACkg/hr00H2Okg/hr00CO2kg/hr00n2kg/hr00C3H4Okg/hr00C3H6O2kg/hr00C4H8O2kg/hr00CH3CHOkg/hr00C6HI0O4kg/hr00C3H8O3kg/hr00HCO3-kg/hr00CO32-kg/hr00MEAkg/hr00MEA+kg/hr00MEACOO-kg/hr00H3O+kg/hr00OH'kg/hr003.1.6 分流器(X010LX0103)表3-11 X0101物料衡算Stream Name單位CH3COOHP03010UTX0101OUT相態(tài)液相液相

12、液相溫度°C4040.330240.123壓力kPag300300300質(zhì)量汽相分率000質(zhì)量液相分率111質(zhì)量固相分率000質(zhì)量流量kg/hr4503.941741.866245.8c2h4kg/hr01.91E-331.91E-3302kg/hr02.85E-552.85E-55CH3COOHkg/hr4503.941062.295566.23VACkg/hr05.95E-375.95E-37H2Okg/hr0679.408679.408CO2kg/hr01.44E-391.44E-39INOUTn2kg/hr000C3H4Okg/hr01.80E-331.80E-33C3H6O

13、2kg/hr03.65E-343.65E-34C4H8O2kg/hr05.51E-405.51E-40CH3CHOkg/hr04.11E-394.11E-39C6H10O4kg/hr00.1625210.162521C3H8O3kg/hr000HCO3-kg/hr000CO32-kg/hr000MEAkg/hr01.57E-081.57E-08MEA+kg/hr000MEACOO"kg/hr000H3O+kg/hr000OH-kg/hr000表3-12 X0102物料衡算Stream Name單位C2H4E02030UTX0102OUT相態(tài)汽相汽相溫度°C1303060.3

14、301壓力kPag150015001500質(zhì)量汽相分率10.9197441質(zhì)量液相分率00.08025560質(zhì)量固相分率000質(zhì)量流量kg/hr3226.184693.18328.8c2h4kg/hr3226.184547.977814.2O2kg/hr014.087314.0972CH3COOHkg/hr00.01031350.28064VACkg/hr0126.961489.371INOUTH20kg/hr04.0283110.7793CO2kg/hr00.2264860. 228648n2kg/hr000C3H4Okg/hr00.0008834450.00207934C3H6O2kg/h

15、r00.0002967670.000814286C4H8O2kg/hr00.0008977530.00420297CH3CHOkg/hr00.0423060.0597649C6H10O4kg/hr000C3H8O3kg/hr000HCO3-kg/hr000CO32-kg/hr000MEAkg/hr02.17E-070.000233751MEA+kg/hr000MEACOO'kg/hr000H3O+kg/hr000OH"kg/hr000表3-13 X0103物料衡算INOUTStream Name單位E0101OUTV0103GAsX0103OUT相態(tài)汽相汽相汽相溫度°

16、;C16040154.036壓力kPag8001100800質(zhì)量汽相分率111質(zhì)量液相分率000質(zhì)量固相分率000質(zhì)量流量kg/hr14544.51443.4715988c2h4kg/hr7814.0507814.0502kg/hr14.09721443.471457.56CH3COOHkg/hr5537.3705537.37VACkg/hr488.7750488.775H2Okg/hr690.1590690.159CO2kg/hr0.22864500.228645n2kg/hr000C3H4Okg/hr0.0020780300.00207803C3H6O2kg/hr0.00081370400

17、.000813704C4H8O2kg/hr0.004196800.0041968CH3CH0kg/hr0.059750500.0597505C6H10O4kg/hr0.013242400.0132424C3H8O3kg/hr000HCO3-kg/hr000CO32kg/hr000MEAkg/hr1.57E-0801.57E-08MEA+kg/hr000MEACOO"kg/hr000H3O+kg/hr000OH'kg/hr0003.2吸收二氧化碳工段3.2.1 壓縮機(jī)（C0101）表3-14壓縮機(jī)C0201物料衡算目錄第一章概述1第二章物料衡算原理1第三章 物料衡算任務(wù)23.1

18、醋酸乙烯酯合成工段2換熱器（E0101-E0103） 23.1.1 輸送泵（P0101） 5反應(yīng)器（R0101、R0102） 63.1.2 塔設(shè)備（T0101） 8儲(chǔ)罐（V0101-V0103） 103.1.3 分流器（X0101-X0103） 133.2吸收二氧化碳工段16壓縮機(jī)（C0101） 163.2.1 換熱器（E0201-E0204） 17輸送泵（P0201） 223.2.4膜分離設(shè)備（S0201） 23塔設(shè)備（T0201-T0204） 243.2.5 減壓閥（V0201） 29分離器（V0202、V0203） 303.2.6 分流器（X0201-X0204） 323.3醋酸乙烯酯分

19、離工段36換熱器（E0301-E0303） 363.3.1 輸送泵（P0301-P0303） 40塔設(shè)備（T0301-T0303） 433.3.2 分離器（V0301） 46分流器（X0301） 473.4醋酸乙烯酯精制工段49換熱器（E0401） 493.4.1 輸送泵（P0401） 50塔設(shè)備（T0401、T0402） 51壓力kPag1011520質(zhì)量汽相分率11質(zhì)量液相分率00質(zhì)量固相分率00質(zhì)量流量kg/hr5260.445260.44c2h4kg/hr4729.924729.9202kg/hr14.533214.5332CH3COOHkg/hr0.2893110.289311VAC

20、kg/hr504.513504.513H20kg/hr11.112711.1127C02kg/hr0. 2357030.235703n2kg/hr00C3H4Okg/hr0.002143640.00214364C3H6O2kg/hr0.0008394670.000839467C4H8O2kg/hr0.004331960.00433196CH3CHOkg/hr0.06161310.0616131C6HI0O4kg/hr00C3H8O3kg/hr00HCO3-kg/hr00CO32-kg/hr00MEAkg/hr0.0002409820.000240982MEA+kg/hr00MEACOO-kg/

21、hr00H3O+kg/hr00OH'kg/hr00322 換熱器(E020LE0204)表3-15換熱器E0201物料衡算Stream Name單位E0103OUTE0201OUT相態(tài)汽相溫度°C13060壓力kPag650600質(zhì)量汽相分率10.342512質(zhì)量液相分率00.657488質(zhì)量固相分率00質(zhì)量流量kg/hr10511.9c2h4kg/hr1311.6902kg/hr0.994665CH3COOHkg/hr130.03VACkg/hr6843.66H2Okg/hr2224.62CO2kg/hr585.7823n2kg/hr0C3H4Okg/hr0.0335818

22、C3H6O2kg/hr0.0225161C4H8O2kg/hr0.348898CH3CHOkg/hr0.178065C6H10O4kg/hr0.162474C3H8O3kg/hr0HCO3-kg/hr0CO32-kg/hr0MEAkg/hr1.57E-08MEA+kg/hr0MEACOO'kg/hr0H3O+kg/hr0OHkg/hr0INOUT表3-16換熱器吧g物箜衡算INOUTStream Name單位E0201OUTE02020UT相態(tài)溫度°C6040壓力kPag600550質(zhì)量汽相分率0.3425120.261241質(zhì)量液相分率0.6574880.738759質(zhì)量固

23、相分率00質(zhì)量流量kg/hr10511.911811.3c2h4kg/hr1311.691710.5302kg/hr0.9946651.49005CH3COOHkg/hr130.03130.209VACkg/hr6843.667684.18H2Okg/hr2224.622283.79CO2kg/hr585.7823585.7823n2kg/hr00C3H4Okg/hr0.03358180.0372765C3H6O2kg/hr0.02251610.0245404C4H8O2kg/hr0.3488980.372648CH3CHOkg/hr0.1780650.230269C6HI0O4kg/hr0.

24、1624740.162511C3H8O3kg/hr00HCO3-kg/hr00CO32-kg/hr00MEAkg/hr1.57E-08L57E-08MEA+kg/hr00MEACOO-kg/hr00表3-17換熱器£02氣物堂衡算INOUTH3O+kg/hr00OH'kg/hr00表3-17換熱器£02氣物堂衡算INOUTStream Name單位X020301E02030UT相態(tài)汽相溫度°C159.97830壓力kPag15201500質(zhì)量汽相分率10.919744質(zhì)量液相分率00.0802556質(zhì)量固相分率00質(zhì)量流量kg/hr409.518c2h4k

25、g/hr40.047902kg/hr0.00983426CH3COOHkg/hr0.270318VACkg/hr362.416H2Okg/hr6.75103CO2kg/hr2.15E-05n2kg/hr0C3H4Okg/hr0.00119589c3h6o2kg/hr0.000517516C4H8O2kg/hr0.00330425CH3CHOkg/hr0.0174587C6H10O4kg/hr0C3H8O3kg/hr0HCO3-kg/hr0CO32-kg/hr0MEAkg/hr0.000233535MEA+kg/hr0MEACOO-kg/hr0H3O+kg/hr0OH'kg/hr0表3-

26、18換熱器E020物暨衡算INOUTStream Name單位P0201OUTE02040UT相態(tài)液相液相溫度°C119.51825壓力kPag550500質(zhì)量汽相分率00質(zhì)量液相分率11質(zhì)量固相分率00質(zhì)量流量kg/hr1015.531015.53c2h4kg/hr1.27E-211.27E-21O2kg/hr2.29E-262.29E-26CH3COOHkg/hr45.027645.0308VACkg/hr3.46E-063.46E-06H2Okg/hr395.693395.695CO2kg/hr0.01394460.0139453n2kg/hr00C3H4Okg/hr1.17E

27、-091.17E-09C3H6O2kg/hr3.94E-103.94E-10C4H8O2kg/hr3.O3E-1O3.O3E-1OCH3CHOkg/hr2.92E-102.92E-10C6H10O4kg/hr00C3H8O3kg/hr00HCO3-kg/hr0.03610710.0361089表3-18換熱器E020物暨衡算INOUTCO32-kg/hr0.001348430.00134868MEAkg/hr567.365567.363MEA+kg/hr2.819622.81957MEACOO-kg/hr4.572554.57253H3O+kg/hr5.07E-095.07E-09OH'

28、;kg/hr0.01439130.0143913323 輸送泵（P0201）表3-19輸送泵P0201物料衡算INStream Name單位X020401P02010UT相態(tài)液相液相溫度°C118.97119.518壓力kPag100.7550質(zhì)量汽相分率00質(zhì)量液相分率11質(zhì)量固相分率00質(zhì)量流量kg/hr1015.531015.53c2h4kg/hr1.27E-211.27E-21O2kg/hr2.29E-262.29E-26CH3COOHkg/hr45.027645.0276VACkg/hr3.46E-063.46E-06H2Okg/hr395.693395.693CO2kg/

29、hr0.01394460.0139446n2kg/hr00C3H4Okg/hr1.17E-091.17E-09C3H6O2kg/hr3.94E-103.94E-10C4H8O2kg/hr3.O3E-1O3.O3E-1OOUTCH3CHOkg/hr2.92E-102.92E-10C6H10O4kg/hr00C3H8O3kg/hr00HCO3-kg/hr0.03610710.0361071CO32-kg/hr0.001348430.00134843MEAkg/hr567.365567.365MEA+kg/hr2.819622.81962MEACOO'kg/hr4.572554.57255H

30、3O+kg/hr5.07E-095.07E-09OH'kg/hr0.01439130.0143913324膜分離設(shè)備（S0201）表3-20膜分離S0201物料衡算INOUTStream Name單位V0202LIQS020101S020102相態(tài)液相液相溫度°C333壓力kPag101101101質(zhì)量汽相分率000.437044質(zhì)量液相分率110.562956質(zhì)量固相分率000質(zhì)量流量kg/hr167.572141.12726.445C2H4kg/hr11.5266011.526602kg/hr0.0021415300.00214153CH3COOHkg/hr5.94240

31、.0001188485.94228VACkg/hr6.529396.53E-056.52933H2Okg/hr14L13141.1270.0028226CO2kg/hr6.69E-066.69E-096.69E-06N2kg/hr000C3H4Okg/hr9.65E-0509.65E-05C3H6O2kg/hr5.18E-0505.18E-05C4H8O2kg/hr0.00033454300.000334543CH3CHOkg/hr0.0049200300.00492003C6H10O4kg/hr000C3H8O3kg/hr000HCO3-kg/hr000CO3-kg/hr000MEAkg/h

32、r2.4363702.43637MEA+kg/hr000MEACOO-kg/hr000H3O+kg/hr000OH-kg/hr0003.2.5 塔設(shè)備(T020LT0204)表3-21塔設(shè)備T0201物料衡算Stream Name單位CH3COOH1P03020UTV0201OUTT0201DT0201W相態(tài)液相液相汽相液相溫度°C1920.866529.633655.501222.253壓力kPag700700200110110.7質(zhì)量汽相分率000.33770710質(zhì)量液相分率110.66229301INOUT質(zhì)量固相分率00000質(zhì)量流量kg/hr660.5781741.861

33、0588.76832.181212085.7c2h4kg/hr01.91E-33982.6385284.153.6361902kg/hr02.85E-550.7445616.15990.00299311CH3COOHkg/hr660.5781062.29130.194203.7541649.39VACkg/hr05.95E-377211.14634.0327605.59H2Okg/hr0679.4082263.1165.7192826.15CO2kg/hr01.44E-39585.7823585.48120.398412n2kg/hr00000C3H4Okg/hr01.80E-330.0350

34、5680.00296030.0372956c3h6o2kg/hr03.65E-340.02344370.00117980.0248568C4H8O2kg/hr05.51E-400.3605850.00635070.381514CH3CHOkg/hr04.11E-390.1970210.0800340.204707C6H10O4kg/hr00.1625210.1625110.00094630.324095C3H8O3kg/hr00000HCO3-kg/hr00000CO32-kg/hr00000MEAkg/hr01.57E-081.57E-086.07E-113.14E-08MEA+kg/hr0

35、0000MEACOO-kg/hr00000H3O+kg/hr00000OH'kg/hr00000表3-22塔設(shè)備T0202物料衡算Stream Name單位CH3COOH2H2OT0201DT0202DT0202W相態(tài)液相液相汽相汽相液相溫度°C192055.501250.983255.6042INOUT壓力kPag700700110100100.7質(zhì)量汽相分率00110質(zhì)量液相分率11001質(zhì)量固相分率00000質(zhì)量流量kg/hr300.263198.1686832.18126644.851685.768c2h4kg/hr005284.155268.4315.718502k

36、g/hr0016.159916.15050.00936955CH3COOHkg/hr300.2630203.75428.8382475.179VACkg/hr00634.032598.86935.1634H2Okg/hr0198.168165.719204.195159.692CO2kg/hr00585.4812585.4790.217964n2kg/hr00000C3H4Okg/hr000.00296030.0027870.000173222C3H6O2kg/hr000.00117980.0011027.73E-05C4H8O2kg/hr000.00635070.0057390.000611

37、685CH3CHOkg/hr000.0800340.078250.00178446C6HI0O4kg/hr000.00094633.2E-150.000946298C3H8O3kg/hr00000HCO3-kg/hr00000CO32'kg/hr00000MEAkg/hr006.07E-U1.15E-236.07E-11MEA+kg/hr00000MEACOO-kg/hr00000H3O+kg/hr00000OH'kg/hr00000表3-23塔設(shè)備T0203物料衡算INOUTStream Name 單位 X0201O1X02020UTT0203DT0203WII相態(tài)汽相液相汽

38、相液相溫度°C50.983225.66250.52653.2144壓力kPag100500100100.7質(zhì)量汽相分率1010質(zhì)量液相分率0101質(zhì)量固相分率0000質(zhì)量流量kg/hr5505.6316005428.011677.62c2h4kg/hr4147.5904741.440.14502102kg/hr14.5355014.53530.000137219CH3COOHkg/hr25.954445.03086.2317164.7534VACkg/hr538.923.46E-06511.04227.9396H20kg/hr183.776786.609152.243818.291C

39、02kg/hr585.4793.28E-090.2363731.11E-06n2kg/hr0000C3H4Okg/hr0.0025081.17E-090.002240140.000268295c3h6o2kg/hr0.000993.94E-100.0008912370.00010098c4h8o2kg/hr0.00516500.00466650.000498647CH3CHOkg/hr0.07042.92E-100.06653320.0038918C6HI0O4kg/hr2.88E-15000C3H8O3kg/hr0000HCO3-kg/hr00.0019490100.0193178CO32-

40、kg/hr00.12650500.0361598MEAkg/hr1.04E-23760.2152.43661756.248MEA+kg/hr03.4506903.92615MEACOO-kg/hr04.4140606.22519H3O+kg/hr08.22E-1202.24E-10OH'kg/hr00.15174100.0324035表3-24塔設(shè)備T0204物料衡算Stream Name單位T0203WT0204DT0204W相態(tài)液相汽相液相溫度°C53.2144119.949133.726壓力kPag100.7100100.7質(zhì)量汽相分率010質(zhì)量液相分率101質(zhì)量固相分

41、率000質(zhì)量流量kg/hr1677.62323.581354.04c2h4kg/hr0.1450210.1450211.69E-2102kg/hr0.0001372190.0001372193.05E-26CH3COOHkg/hr64.75344.7165960.0369VACkg/hr27.939627.93964.61E-06H2Okg/hr818.291290.715527.591CO2kg/hr1.11E-06585.4180.0185928n2kg/hr000C3H4Okg/hr0.0002682950.0002682931.56E-09C3H6O2kg/hr0.000100980.0001009795.26E-10C4H8O2kg/hr0.0004986470.0004986474.04E-10CH3CHOkg/hr0.00389180.00389183.90E-10C6H10O4kg/hr000C3