河南省鄭州市滎陽市實驗高中高三化學(xué)上學(xué)期10月月考試卷（含解析）.doc

2015-2016學(xué)年河南省鄭州市滎陽市實驗高中高三（上）月考化學(xué)試卷（10月份）一、選擇題（每題3分，共48分）1如圖為霧霾的主要成分示意圖下列說法不正確的是( )a重金屬離子可導(dǎo)致蛋白質(zhì)變性b苯是最簡單的芳香烴c向空氣中大量排放so2和nxoy都能引起酸雨和光化學(xué)煙霧d汽車尾氣的大量排放是造成霧霾天氣的人為因素之一2下列說法不正確的是( )a油脂是高級脂肪酸的甘油酯b油脂與氫氣發(fā)生加成反應(yīng)，可以得到硬化油c油脂在酸性條件或堿性條件下，可以發(fā)生皂化反應(yīng)d日常使用的花生油、豆油、動物油都是油脂，它們可以溶解一些脂溶性維生素3通過對實驗現(xiàn)象的觀察、分析推理得出正確的結(jié)論是化學(xué)學(xué)習(xí)的方法之一對下列實驗事實的解釋不正確的是( )現(xiàn)象解釋或結(jié)論aso2使酸性高錳酸鉀溶液退色so2表現(xiàn)還原性b濃hno3在光照條件下變黃濃hno3不穩(wěn)定，生成有色產(chǎn)物能溶于濃硝酸c某溶液中加入濃naoh溶液加熱，放出氣體能使?jié)駶櫟募t色石蕊試紙變藍該溶液中一定含有nh4+d鋁片放入濃硫酸中，無明顯變化說明鋁與冷的濃硫酸不發(fā)生化學(xué)反應(yīng)aabbccdd4用na表示阿伏加德羅常數(shù)的值，下列說法正確的是( )a11.2 l氧氣中所含有的原子數(shù)為nab7.8g的na2o2中含有的陰離子的數(shù)目為0.2nac0.10mol fe 粉與足量水蒸氣反應(yīng)生成的h2分子數(shù)為0.10nad54g al分別與足量的稀硫酸及氫氧化鈉溶液反應(yīng)失去的電子數(shù)都是6na5在t時，向x g kno3不飽和溶液中加入a g kno3或蒸發(fā)掉b g水，恢復(fù)到t，溶液均達到飽和，據(jù)此，下列推論不正確的是( )a在t時，kno3的溶解度為gb若原溶液中溶質(zhì)的質(zhì)量分數(shù)為，則x=2bc在t時，所配的kno3溶液中溶質(zhì)的質(zhì)量分數(shù)為w%d若將原溶液蒸發(fā)掉2b g水，恢復(fù)到原溫度析出2a g kno36下列離子方程式正確的是( )a0.01mol/l nh4al（so4）2溶液與0.02mol/l ba（oh）2溶液等體積混合nh4+al3+2so42+2ba2+4oh2baso4+al（oh）3+nh3h2obfecl2酸性溶液放在空氣中變質(zhì)：2fe2+4h+o22fe3+2h2oc用ch3cooh溶解caco3：caco3+2h+ca2+h2o+co2d電解mgcl2水溶液的離子方程式：2cl+2h2oh2+cl2+2oh7已知金剛石的燃燒熱為395kj/mol，下表是部分化學(xué)鍵的鍵能數(shù)據(jù)下列選項中正確的是( )化學(xué)鍵cco=oc=o鍵能（kj/mol）348498xax=794.5bx=1142.5c1mol金剛石的能量一定比1mol co2能量高d金剛石燃燒的熱化學(xué)方程式為 2c（s）+o2（g）=2co（g）h=790 kj/mol8如圖為兩個原電池裝置圖，由此判斷下列說法錯誤的是( )a當兩電池轉(zhuǎn)移相同電子時，生成和消耗ni的物質(zhì)的量相同b兩裝置工作時，鹽橋中的陰離子向負極移動，陽離子向正極移動c由此可判斷能夠發(fā)生2cr3+3ni=3ni2+2cr和ni2+sn=sn2+ni的反應(yīng)d由此可判斷cr、ni、sn三種金屬的還原性強弱順序為：crnisn9二氯化二硫（s2cl2）是廣泛用于橡膠工業(yè)的硫化劑，其分子結(jié)構(gòu)如圖所示常溫下，s2cl2是一種橙黃色液體，遇水易水解，并產(chǎn)生能使品紅褪色的氣體，化學(xué)方程式為：2s2cl2+2h2o=so2+3s+4hcl下列說法中錯誤的是( )as2cl2的結(jié)構(gòu)式為clssclb反應(yīng)中so2是還原產(chǎn)物，s是氧化產(chǎn)物cs2cl2為含有極性鍵和非極性鍵的分子d反應(yīng)中，生成1molso2，轉(zhuǎn)移電子為3mol10硫酸鍶（srso4）在水中的沉淀溶解平衡曲線如下下列說法正確的是( )a溫度一定時，ksp（srso4）隨c（so42）的增大而減小b三個不同溫度中，313k時ksp（srso4）最大c283k時，圖中a點對應(yīng)的溶液是不飽和溶液d283k下的srso4飽和溶液升溫到363k后變?yōu)椴伙柡腿芤?1如圖是草酸溶液中h2c2o4、hc2o4三種微粒的分布分數(shù)（某微粒物質(zhì)的量濃度與三種微粒物質(zhì)的量被度和的比值）與ph的關(guān)系圖，下到有關(guān)說法不正確的是( )aph=5的溶液中c（c2o42）c（hc2o4）bnahc2o4溶液中：c（oh）+c（c2o42）=c（h+）+c（h2c2o4）c向nahc2o4溶液中加強酸至ph與a點對應(yīng)時，溶液中2c（na+）=c（hc2o4）+c（h2c2o4）d為使溶液中c（hc2o4）盡可能多一些，溶液的ph最好控制在2.7左右12分子式為c10h12o2的有機物，滿足以下兩個條件：苯環(huán)上有兩個取代基，能與nahco3反應(yīng)生成氣體則滿足條件的該有機物的同分異構(gòu)體有( )a9b10c12d1513在450、5.05107pa時，如果把1體積n2和3體積h2的混合物通入一個裝有催化劑的密閉容器中反應(yīng)達到平衡時，得到含nh352%（體積分數(shù)）的混合氣體在同溫同壓下向密閉容器中通入2體積n2和6體積h2，達到平衡時nh3的體積分數(shù)為( )a大于52%b等于52%c小于52%d不能確定14已知反應(yīng)2no2（g）+o3（g）n2o5（g）+o2（g），若反應(yīng)在恒容密閉容器中進行，下列由該反應(yīng)相關(guān)圖象作出判斷正確的是( )a升高溫度，平衡常數(shù)減小b03內(nèi)，反應(yīng)速率為v（no2）=0.2moll1ct1時僅加入催化劑，平衡正向移動d達平衡時，僅改變x，則x為c（o2）15下列實驗現(xiàn)象預(yù)測正確的是( )a實驗：振蕩后靜置，上層溶液顏色保持不變b實驗：酸性kmno4溶液中出現(xiàn)氣泡，且顏色逐漸褪去c實驗：微熱稀hno3片刻，溶液中有氣泡產(chǎn)生，廣口瓶內(nèi)始終保持無色d實驗：繼續(xù)煮沸溶液至紅褐色，停止加熱，當光束通過體系時可產(chǎn)生丁達爾效應(yīng)16高鐵電池是一種新型可充電電池，與普通高能電池相比，該電池能長時間保持穩(wěn)定的放電電壓高鐵電池的總反應(yīng)為：3zn+2k2feo4+8h2o3zn（oh）2+2fe（oh）3+4koh 下列敘述不正確的是( )a放電時負極反應(yīng)為：3zn6e+6oh3zn（oh）2b充電時陽極反應(yīng)為：fe（oh）33e+5ohfeo42+4h2oc放電時每轉(zhuǎn)移3 mol電子，正極有1 mol k2feo4被還原d充電時陰極溶液的堿性減弱二、填空題（52分）17亞硝酸鈉易溶于水，有堿味，有氧化性，也有還原性nano2大量用于染料工業(yè)和有機合成工業(yè)中，也可用作水泥施工的抗凍劑然而由于nano2有毒性，將含該物質(zhì)的廢水直接排放會引起水體嚴重污染，所以這種廢水必須處理后才能排放處理方法之一如下：_nano2+_ki+_no+_i2+_k2so4+_na2so4+_（1）請完成該化學(xué)方程式并配平（2）在上述反應(yīng)中，若要生成50.8g i2，則電子轉(zhuǎn)移了_個（3）現(xiàn)有25.00ml的ki溶液，用酸化的10.00ml 0.000mol/l的kio3溶液處理（5i+io3+6h+=3i2+3h2o）將生成的i2全部除去后，再加入過量的ki溶液，使之與剩余的kio3反應(yīng)，然后將溶液調(diào)節(jié)至中性，析出的單質(zhì)碘用0.1000mol/l的na2s2o3溶液滴定（2s2o32+i2=s4o6+2i），用去該溶液的體積為21.00ml求剩余的kio3為_ mol，原ki溶液的物質(zhì)的量濃度是_mol/l18（16分）甲烷是天然氣的主要成分，是生產(chǎn)生活中應(yīng)用非常廣泛的一種化學(xué)物質(zhì)（1）一定條件下，用甲烷可以消除氮氧化物（nox）的污染已知：ch4（g）+4no（g）2n2（g）+co2（g）+2h2o（g）h1ch4（g）+4no2（g）4no（g）+co2（g）+2h2o（g）h2現(xiàn)有一份在相同條件下對h2的相對密度為17的no與no2的混合氣體，用16g甲烷氣體催化還原該混合氣體，恰好生成氮氣、二氧化碳氣體和水蒸氣，共放出1042.8kj熱量該混合氣體中no和no2的物質(zhì)的量之比為_已知上述熱化學(xué)方程式中h1=1160kj/mol，則h2=_在一定條件下no氣體可以分解為no2氣體和n2氣體，寫出該反應(yīng)的熱化學(xué)方程式：_（2）以甲烷為燃料的新型電池，其成本大大低于以氫氣為燃料的傳統(tǒng)燃料電池，目前得到廣泛地研究，如圖是目前研究較多的一類固體氧化物燃料電池工作原理示意圖回答下列問題：b極為電池_極，電極反應(yīng)式為_若用該燃料電池作電源，用石墨作電極電解100ml 1mol/l的硫酸銅溶液，當兩極收集到的氣體體積相等時理論上消耗的甲烷的體積為_（標準狀況下），實際上消耗的甲烷體積（折算到標準狀況）比理論上大，可能原因為_19黃鐵礦（主要成分為fes2）是我國大多數(shù)硫酸廠制取硫酸的主要原料某化學(xué)學(xué)習(xí)小組對某黃鐵礦石進行如下實驗探究實驗一測定硫元素的含量、將m1 g該黃鐵礦樣品放入如圖所示裝置（夾持和加熱裝置省略）的石英管中，從a處不斷地緩緩?fù)ㄈ肟諝猓邷刈茻⒐苤械狞S鐵礦樣品至反應(yīng)完全石英管中發(fā)生反應(yīng)的化學(xué)方程式為：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