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ModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-1Chapter4PNandMetal-SemiconductorJunctionsPNjunctionispresentinperhapseverysemiconductordevice.
diodesymbol
N
PVI
–+4.1
BuildingBlocksofthePNJunctionTheoryVIReversebiasForwardbias
Donorions
N-typeP-typeModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-24.1.1
EnergyBandDiagramofaPNJunctionAdepletionlayerexistsatthePNjunctionwheren
0andp
0.EfisconstantatequilibriumEcandEvaresmooth,theexactshapetobedetermined.EcandEvareknownrelativetoEf
N-regionP-region(a)Ef(c)EcEvEf(b)
EcEfEvEvEc(d)
Depletionlayer
Neutral
P-region
NeutralN-regionEcEvEfModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-34.1.2Built-inPotentialCanthebuilt-inpotentialbemeasuredwithavoltmeter?
(b)
(c)(a)
N-typeNdP-typeNaNdNa
Ef
Ec
Ev
qfbi
xNxPx
0
VfbiModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-44.1.2Built-inPotential
N-regionP-regionModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-54.1.3Poisson’sEquationGauss’sLaw:
s:permittivity(~12
oforSi)
:chargedensity(C/cm3)Poisson’sequationDxrE(x)
E(x
+Dx)
xarea
AModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-64.2.1FieldandPotentialintheDepletionLayer
OntheP-sideofthedepletionlayer,
=–qNa
Onthe
N-side,=qNd4.2Depletion-LayerModelsaqNdxde-=E)()(1xxqNCxqNxPsasa-=+-=eeE)()(NsdxxqNx-=eENNNPPPModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-74.2.1FieldandPotentialintheDepletionLayerTheelectricfieldiscontinuousatx=0.Na|xP|=Nd|xP|
Whichsideofthejunctionisdepletedmore?Aone-sidedjunctioniscalleda
N+Pjunction
or
P+NjunctionNPModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-84.2.1FieldandPotentialintheDepletionLayerOntheP-side,Arbitrarilychoosethevoltageatx=xP
asV=0.OntheN-side,NNPPModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-94.2.2Depletion-LayerWidthViscontinuousatx=
0IfNa>>Nd,asinaP+N
junction,WhataboutaN+Pjunction?where
0@=adNPNNxx||||PNModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-10EXAMPLE:AP+NjunctionhasNa=1020cm-3andNd
=1017cm-3.Whatisa)itsbuiltinpotential,b)Wdep,c)xN
,andd)xP?Solution:a)
b)c)d)ModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-114.3Reverse-BiasedPNJunction
Doesthedepletionlayerwidenorshrinkwithincreasingreversebias?+–V
NP
(b)reverse-biased
qVEcEcEfnEvq
bi+qVEfpEv
(a)V=0
EcEfEvEfEvq
biEcModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-124.4Capacitance-VoltageCharacteristics
Is
Cdep
agoodthing?
Howtominimizejunctioncapacitance?ReversebiasedPNjunctionisacapacitor.ModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-134.4Capacitance-VoltageCharacteristics
FromthisC-VdatacanNa
and
Nd
bedetermined?
ModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-14EXAMPLE:Iftheslopeofthelineinthepreviousslideis2x1023F-2V-1,theinterceptis0.84V,andAis1mm2,findthelighterandheavierdopingconcentrationsNlandNh
.
Solution:
IsthisanaccuratewaytodetermineNl
?Nh
?ModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-154.5JunctionBreakdownA
Zenerdiode
isdesignedtooperateinthebreakdownmode.
VIVB,breakdownPN
ARForwardCurrentSmallleakageCurrent
voltage
3.7V
R
ICABCDZenerdiodeModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-164.5.1PeakElectricField2/1|)|(2)0(ú?ùê?é+==rbispVqNfeEEbicritsBqNVfe-=22EN+PNa
NeutralRegion
0
xp
(a)increasing
reversebiasx
E
xp
(b)increasingreversebiasEpModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-174.5.2TunnelingBreakdown
Dominantifbothsidesofajunctionareveryheavilydoped.
V/cm
106?=critpEE
VIBreakdown
EmptyStatesFilledStates-EvEcModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-184.5.3AvalancheBreakdown
impactionization:anenergeticelectrongeneratingelectronandhole,whichcanalsocauseimpactionization.qNVcritsB22Ee=Impactionization+positivefeedback
avalanchebreakdownEcEfnEcEvEfporiginalelectronelectron-holepairgenerationModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-194.6ForwardBias–CarrierInjection
Minoritycarrierinjection
V=0I=0ForwardbiasedDriftanddiffusioncanceloutModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-204.6ForwardBias–Quasi-equilibriumBoundaryCondition
TheminoritycarrierdensitiesareraisedbyeqV/kTWhichsidegetsmorecarrierinjection?EcEfnEfpEvxEfnxNxPModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-214.6CarrierInjectionUnderForwardBias–Quasi-equilibriumBoundaryConditionkTVqaikTVqPeNnenn20)xP(==kTVqdikTVqNeNnepp20)(==xPModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-22EXAMPLE:CarrierInjectionAPNjunctionhasNa=1019cm-3andNd=1016cm-3.Theappliedvoltageis0.6V.Question:Whataretheminoritycarrierconcentrationsatthedepletion-regionedges?Solution:Question:Whataretheexcessminoritycarrierconcentrations?Solution: ModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-234.7CurrentContinuityEquationModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-244.7CurrentContinuityEquationMinoritydriftcurrentisnegligible;
Jp=–qDpdp/dx
LpandLnarethediffusionlengthsModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-254.8ForwardBiasedJunction--ExcessCarriersModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-264.8ExcessCarrierDistributionsModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-27EXAMPLE:CarrierDistributioninForward-biasedPNDiode
Sketchn'(x)ontheP-side.xN-sideP-side1013cm-3
2′1012n’(=p’)p′(=n’)ModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-28
HowdoesLncomparewithatypicaldevicesize?
Whatisp'(x)ontheP-side?EXAMPLE:CarrierDistributioninForward-biasedPNDiodeModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-294.9PNDiodeI-VCharacteristics
0
P-sideN-sideJtotalJpNJnPx
0
P-sideN-sideJtotal
JpNJnPJn=Jtotal
–JpJp=Jtotal
–JnModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-30ThePNJunctionasaTemperatureSensorWhatcausestheIVcurvestoshifttolowerVathigherT?ModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-314.9.1
ContributionsfromtheDepletionRegionSpace-ChargeRegion(SCR)currentUnderforwardbias,SCRcurrentisanextracurrentwithaslope120mV/decadeModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-324.10ChargeStorageWhatistherelationshipbetween
s
(charge-storagetime)
and
(carrierlifetime)?ModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-334.11Small-signalModeloftheDiodeWhatisGat300KandIDC
=1mA?DiffusionCapacitance:Whichislarger,diffusionordepletioncapacitance?CRVIqkTIeIkTqDCkTqV/)(/0==ModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-344.12SolarCellsSolarCellsisalsoknownas
photovoltaiccells.Convertssunlighttoelectricitywith10-30%conversionefficiency.1m2solarcellgenerateabout150Wpeakor25Wcontinuouspower.Lowcostandhighefficiencyareneededforwidedeployment.PartII:ApplicationtoOptoelectronicDevicesModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-354.12.1SolarCellBasicsV0.7V
–IscMaximumpower-outputSolarCellIVIDarkIV0Eq.(4.9.4)Eq.(4.12.1)
NP-ShortCircuitlightIsc+(a)EcEvDirect-GapandIndirect-GapSemiconductors
ModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-36Electronshavebothparticleandwaveproperties.AnelectronhasenergyEandwavevectork.indirect-gapsemiconductordirect-gapsemiconductor4.12.2
LightAbsorption
α(1/cm):absorptioncoefficient1/α
:lightpenetrationdepthModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-37Athinnerlayerofdirect-gapsemiconductorcanabsorbmostofsolarradiationthanindirect-gapsemiconductor.ButSi…4.12.3Short-CircuitCurrentandOpen-CircuitVoltage
ModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-38IflightshinesontheN-typesemiconductorandgeneratesholes(andelectrons)attherateofGs-1cm-3,Ifthesampleisuniform(noPNjunction),d2p’/dx2=0
p’=GLp2/Dp=GtpSolarCellShort-CircuitCurrent,IscModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-39AssumeverythinP+layerandcarriergenerationinNregiononly.xNP+Isc0xP'Lp0Gisreallynotuniform.Lpneedsbelargerthanthelightpenetrationdepthtocollectmostofthegeneratedcarriers.Open-CircuitVoltageModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-40TotalcurrentisISCplusthePVdiode(dark)current:Solvefortheopen-circuitvoltage(Voc)by
settingI=0HowtoraiseVoc?ModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-414.12.4OutputPowerTheoretically,thehighestefficiency(~24%)canbeobtainedwith1.9eV>Eg>1.2eV.LargerEgleadtotoolowIsc(lowlightabsorption);smallerEgleadstotoolowVoc.Tandemsolarcellsgets35%efficiencyusinglargeandsmallEgmaterialstailoredtotheshortandlongwavelengthsolarlight.
AparticularoperatingpointonthesolarcellI-Vcurvemaximizestheoutputpower(IV).Sisolarcellwith15-20%efficiencydominatesthemarketnowModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-42Lightemittingdiodes(LEDs)LEDsaremadeofcompoundsemiconductorssuchasInPandGaN.Lightisemittedwhenelectronandholeundergo
radiativerecombination.EcEvRadiativerecombination
Non-radiativerecombinationthroughtraps
4.13LightEmittingDiodesandSolid-StateLightingDirectandIndirectBandGapDirectbandgapExample:GaAsDirectrecombinationisefficientaskconservationissatisfied.IndirectbandgapExample:SiDirectrecombinationisrareaskconservationisnotsatisfiedTrapModernSemiconductorDevicesforIntegratedCircuits(C.Hu)ModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-444.13.1LEDMaterialsandStructureModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-454.13.1LEDMaterialsandStructure
redyellowblue
Wavelength(μm)ColorLatticeconstant(?)InAs0.363.44
6.05InN0.651.91infrared
3.45InP1.360.92
violet5.87GaAs1.420.875.66GaP2.260.555.46AlP3.390.515.45GaN2.450.373.19AlN6.200.20UV3.11Light-emittingdiodematerials
compoundsemiconductors
binarysemiconductors:-Ex:GaAs,efficientemitterternarysemiconductor:-Ex:GaAs1-xPx,tunable
Eg
(tovarythecolor)quaternarysemiconductors:-Ex:AlInGaP,tunableEgandlatticeconstant(forgrowinghighqualityepitaxialfilmsoninexpensivesubstrates)Eg(eV)RedYellowGreenBlueModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-46CommonLEDsSpectralrangeMaterialSystemSubstrateExampleApplicationsInfraredInGaAsPInPOpticalcommunicationInfrared-RedGaAsPGaAsIndicatorlamps.RemotecontrolRed-YellowAlInGaPGaAorGaPOpticalcommunication.High-brightnesstrafficsignallightsGreen-BlueInGaNGaNorsapphireHighbrightnesssignallights.VideobillboardsBlue-UVAlInGaNGaNorsapphireSolid-statelightingRed-BlueOrganicsemicon-ductorsglassDisplaysAlInGaP
QuantunWellModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-474.13.2Solid-StateLightingIncandescentlampCompactfluorescentlampTubefluorescentlampWhiteLEDTheoreticallimitatpeakofeyesensitivity(λ=555nm)Theoreticallimit(whitelight)176050-10090-?683~340luminosity(lumen,lm):ameasureofvisiblelightenergy normalizedtothesensitivityofthehumaneyeatdifferentwavelengths
Luminousefficacyoflampsinlumen/watt
Terms:luminositymeasuredinlumens.luminousefficacy,OrganicLightEmittingDiodes(OLED):haslowerefficacythannitrideoraluminidebasedcompoundsemiconductorLEDs.
ModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-484.14DiodeLasers(d)NetLightAbsorption(e)NetLightAmplificationStimulatedemission:emittedphotonhasidenticalfrequencyanddirectionalityasthestimulatingphoton;lightwaveisamplified.(b)SpontaneousEmission(c)StimulatedEmission(a)Absorption4.14.1LightAmplificationLightamplificationrequires
populationinversion:electronoccupationprobabilityislargerforhigherEstatesthanlowerEstates.ModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-494.14.1LightAmplificationinPNDiodePopulationinversionisachievedwhen
Populationinversion,qV>EgEquilibrium,V=0ModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-50R1,R2:reflectivitiesofthetwoendsG:lightamplificationfactor(gain)foraround-triptravelofthelightthroughthediodeLightintensitygrowsuntil,whenthelightintensityisjustlargeenoughtostimulatecarrierrecombinationsatthesameratethecarriersareinjectedbythediodecurrent.4.14.2OpticalFeedbackandLaserlightoutCleavedcrystalplaneP+N+Laserthresholdisreached(lightintensitygrowsbyfeedback)whenModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-514.14.2OpticalFeedbackandLaserDiode
DistributedBraggreflector(DBR)reflectslightwithmulti-layersofsemiconductors.Vertical-cavitysurface-emittinglaser(VCSEL)isshownontheleft.Quantum-welllaserhassmallerthresholdcurrentbecausefewercarriersareneededtoachievepopulationinversioninthesmallvolumeofthethinsmall-Egwell.ModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-524.14.3LaserApplicationsReddiodelasers:CD,DVDreader/writerBluediodelasers:Blu-rayDVD(higherstoragedensity)1.55mminfrareddiodelasers:
Fiber-opticcommunication
Photodiodes:ReversebiasedPNdiode.Detectsphoto-generatedcurrent(similartoIscofsolarcell)foropticalcommunication,DVDreader,etc.
Avalanchephotodiodes:
Photodiodesoperatingnearavalanchebreakdownamplifiesphotocurrentbyimpactionization.4.15PhotodiodesModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-53Twokindsofmetal-semiconductorcontacts:RectifyingSchottkydiodes:
metalonlightlydopedsiliconLow-resistanceohmiccontacts:metalonheavilydopedsiliconPartIII:Metal-SemiconductorJunctionSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-54fBn
IncreaseswithIncreasingMetalWorkFunction
Theoretically,
fBn=
yM
–cSi
yMcSi:WorkFunctionofmetal:ElectronAffinityofSi
qfBnEcEvEfE0qyMcSi
=4.05eVVacuumlevel,ModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-554.16SchottkyBarriersEnergyBandDiagramofSchottkyContact
Schottkybarrierheight,fB
,isafunctionofthemetalmaterial.
fBisthemostimportantparameter.ThesumofqfBnandqfBpisequaltoEg
.
MetalDepletion
layer
NeutralregionqfBnEcEcEfEfEvEvqfBpN-SiP-SiModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-56SchottkybarrierheightsforelectronsandholesfBn
increaseswithincreasingmetalworkfunctionfBn
+fBp
EgModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-57
Ahighdensityofenergystatesinthebandgapatthemetal-semiconductorinterfacepinsEftoanarrowrangeandfBn
istypically0.4to0.9V
Question:WhatisthetypicalrangeoffBp?FermiLevelPinning
qfBnEcEvEfE0
qyMcSi
=4.05eVVacuumlevel,+-ModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-58SchottkyContactsofMetalSilicideonSiSilicide-Siinterfacesaremorestablethanmetal-siliconinterfaces.AftermetalisdepositedonSi,anannealingstepisappliedtoformasilicide-Sicontact.Thetermmetal-siliconcontactincludesandalmostalwaysmeanssilicide-Sicontacts.Silicide:Asiliconandmetalcompound.Itisconductivesimilartoametal.fBnfBpModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-59UsingC-VDatatoDeterminefBQuestion:HowshouldweplottheCVdatatoextractfbi?EvEfEcqfbiqfBn
EvEcEfqfBnq(fbi+V)qVModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-60Once
fbiisknown,fB
canbedeterminedusingUsingCVDatatoDeterminefBV1/C2
-fbiEvEfEcqfbiqfBnModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-614.17ThermionicEmissionTheoryEfn-q(fB-
V)
qfB
qVMetalN-typeSiliconVEfmEvEcxvthxModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-624.18SchottkyDiodesVI
ReversebiasForwardbiasV=0ForwardbiasedReversebiasedModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-634.18SchottkyDiodesModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-644.19ApplicationsofSchottlyDiodes
I0ofaSchottkydiodeis103to108timeslargerthanaPNjunctiondiode,dependingonfB
.
AlargerI0meansasmallerforwarddropV.ASchottkydiodeisthepreferredrectifierinlowvoltage,highcurrentapplications.I
VPNjunctionSchottky
fBI
VPNjunctionSchottkydiode
fBdiodeModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-65SwitchingPowerSupplyACDCACACDCutilitypower110V/220V
PNJunction
rectifier
Hi-voltage
MOSFET
inverter
100kHzHi-voltage
Transformer
Schottky
rectifierLo-voltage50A1VfeedbacktomodulatethepulsewidthtokeepVout
=1VModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-66ThereisnominoritycarrierinjectionattheSchottkyjunction.Therefore,SchottkydiodescanoperateathigherfrequenciesthanPNjunctiondiodes.4.19ApplicationsofSchottkydiodesQuestion:WhatsetsthelowerlimitinaSchottkydiode’sforwarddrop?SynchronousRectifier:Foranevenlowerforwarddrop,replacethediodewithawide-WMOSFETwhichisnotboundbythetradeoffbetweendiodeVandleakagecurrent.ModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-674.20
QuantumMechanicalTunnelingTunnelingprobability:ModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-684.21OhmicContactsModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-694.21OhmicContactsTunnelingprobability:--
xSilicideN+SiEvEc
,EffBn--
xVEfmEvEc
,EffBn
–VModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-704.21OhmicContactsModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-714.22ChapterSummaryThepotentialbarrierincreasesby1Vifa1VreversebiasisappliedjunctioncapacitancedepletionwidthPartI:PNJunctionModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-724.22ChapterSummary
Underforwardbias,minoritycarriersareinjectedacrossthejucntion.
Thequasi-equilibriumboundaryconditionofminoritycarrierdensitiesis:
Mostoftheminoritycarriersareinjectedintothemorelightlydopedside.ModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-734.22ChapterSummary
Steady-statecontinuityequation:
Minoritycarriersdiffuseoutward
e–|x|/Lp
ande–|x|/Ln
Lp
and
Ln
arethediffusionlengthsModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-744.22ChapterSummaryChargestorage:
Diffusioncapacitance:Diodeconductance:ModernSemiconductorDevicesforIntegratedCircuits(C.Hu)Slide4-754.22ChapterSummaryPartII:OptoelectronicApplications~100umSior<1umdirect–gapsemiconductorcanabsorbmostofsolarphotonswithenergylargerthanEg.CarriersgeneratedwithindiffusionlengthfromthejunctioncanbecollectedandcontributetotheShortCircuitCurrentIsc.Theoretically,thehighestefficiency(~24%)can
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