銅鎳鈷硅合金帶箔材編制說(shuō)明

《銅鎳鈷硅合金帶箔材》行業(yè)標(biāo)準(zhǔn)編制說(shuō)明（討論稿）一、任務(wù)來(lái)源根據(jù)工信廳科函〔2022〕94號(hào)《工業(yè)和信息化部辦公廳關(guān)于印發(fā)2022年第一批行業(yè)標(biāo)準(zhǔn)制修訂和外文版項(xiàng)目計(jì)劃的通知》，其中行業(yè)標(biāo)準(zhǔn)（項(xiàng)目編號(hào)“2022-0045T-YS”）《銅鎳鈷硅合金帶箔材》由寧波興業(yè)盛泰集團(tuán)有限公司，寧波興業(yè)鑫泰新型電子材料有限公司，有研工程技術(shù)研究院有限公司起草，完成年限為2024年。二、工作簡(jiǎn)況1、立項(xiàng)目的和意義高強(qiáng)高導(dǎo)銅合金帶材具有高的強(qiáng)度、優(yōu)良的導(dǎo)電和導(dǎo)熱性能，是載人航天與探月工程、衛(wèi)星導(dǎo)航系統(tǒng)等國(guó)家重點(diǎn)工程、重點(diǎn)領(lǐng)域和新一代3C產(chǎn)品所必須和急需的關(guān)鍵基礎(chǔ)材料。銅鎳鈷硅合金是上述領(lǐng)域相關(guān)部件所必須的接插件、電力轉(zhuǎn)換等元器件的核心材料。據(jù)統(tǒng)計(jì)，2021年我國(guó)高性能銅鎳鈷硅銅合金帶材國(guó)內(nèi)需求量達(dá)到約10萬(wàn)噸，產(chǎn)值150億元以上，年增長(zhǎng)率20%以上，但該高端合金板帶材完全被日本、美國(guó)和德國(guó)的銅加工企業(yè)壟斷，完全依賴進(jìn)口，嚴(yán)重受制于人，不利于國(guó)家經(jīng)濟(jì)的發(fā)展和國(guó)防安全。加快銅鎳鈷硅合金標(biāo)準(zhǔn)建立，契合國(guó)家和地方科技發(fā)展規(guī)劃的要求，屬于國(guó)家重點(diǎn)領(lǐng)域發(fā)展的重大戰(zhàn)略需求，可顯著提高企業(yè)整體技術(shù)裝備水平及提升國(guó)內(nèi)外市場(chǎng)競(jìng)爭(zhēng)力的發(fā)展戰(zhàn)略，是滿足國(guó)家重大工程、加快企業(yè)轉(zhuǎn)型升級(jí)和提升產(chǎn)品國(guó)際競(jìng)爭(zhēng)力之急需。2、項(xiàng)目編制組成員根據(jù)任務(wù)落實(shí)會(huì)會(huì)議精神，本項(xiàng)目的編制組由寧波興業(yè)盛泰集團(tuán)有限公司負(fù)責(zé)起草,并且由相關(guān)單位參加起草，組織相關(guān)單位組建了《銅鎳鈷硅合金帶箔材》行業(yè)標(biāo)準(zhǔn)修訂起草小組。3、主編單位的技術(shù)基礎(chǔ)本標(biāo)準(zhǔn)的負(fù)責(zé)起草單位寧波興業(yè)盛泰集團(tuán)有限公司是中國(guó)銅板帶材十強(qiáng)企業(yè)（第一），擁有國(guó)家認(rèn)定企業(yè)技術(shù)中心、國(guó)家級(jí)博士后科研工作站、浙江省工程研究中心等。先后承擔(dān)國(guó)家“十三五”重點(diǎn)研發(fā)計(jì)劃、國(guó)家NQI重點(diǎn)研發(fā)計(jì)劃、火炬計(jì)劃等項(xiàng)目，迄今已獲得41項(xiàng)發(fā)明專利，主持、參與我國(guó)國(guó)家、行業(yè)標(biāo)準(zhǔn)制修訂工作30余項(xiàng)，引領(lǐng)我國(guó)有色合金新材料行業(yè)持續(xù)發(fā)展。寧波興業(yè)盛泰集團(tuán)有限公司致力于有色合金新材料的研發(fā)和生產(chǎn),服務(wù)于超大規(guī)模集成電路、5G/6G通訊、航空航天、高鐵、船舶、新能源汽車等30多個(gè)行業(yè)，打破了多項(xiàng)國(guó)外企業(yè)對(duì)高端合金領(lǐng)域的壟斷，解決了新材料“卡脖子”問題，助推我國(guó)產(chǎn)業(yè)升級(jí)。公司在有色合金新材料領(lǐng)域多種新材料的成功研發(fā)及產(chǎn)業(yè)化，為起草本行業(yè)標(biāo)準(zhǔn)提供了有力的技術(shù)支撐，具備了起草本行業(yè)標(biāo)準(zhǔn)的技術(shù)基礎(chǔ)。4主要工作過(guò)程接到標(biāo)準(zhǔn)起草任務(wù)后，寧波興業(yè)盛泰集團(tuán)有限公司立即成立了標(biāo)準(zhǔn)編制小組，首先整理收集本企業(yè)曾經(jīng)生產(chǎn)的產(chǎn)品的技術(shù)要求及產(chǎn)品使用現(xiàn)狀，為本標(biāo)準(zhǔn)全面、系統(tǒng)、有效的制定奠定了良好的基礎(chǔ)；同時(shí)編制小組會(huì)同市場(chǎng)開發(fā)和營(yíng)銷人員對(duì)銅鎳鈷硅合金帶箔材市場(chǎng)進(jìn)一步調(diào)研，多角度了解市場(chǎng)商不同客戶的需求以及產(chǎn)品未來(lái)發(fā)展趨勢(shì)，同時(shí)收集了主要生產(chǎn)廠商的生產(chǎn)水平和現(xiàn)狀，經(jīng)綜合研究、分析、整合調(diào)查的資料，對(duì)銅鎳鈷硅合金帶箔材的產(chǎn)品分類、技術(shù)要求、試驗(yàn)方法、檢驗(yàn)規(guī)則等進(jìn)行了反復(fù)試驗(yàn)、檢測(cè)、驗(yàn)證和確定。開始了本標(biāo)準(zhǔn)的起草工作，經(jīng)過(guò)編制小組多次內(nèi)部討論及廣泛征求意見，于2022年11月7日形成了本標(biāo)準(zhǔn)的《討論稿》。三、標(biāo)準(zhǔn)編制原則本標(biāo)準(zhǔn)起草單位自接受起草任務(wù)后，成立了本標(biāo)準(zhǔn)編制工作組負(fù)責(zé)收集生產(chǎn)統(tǒng)計(jì)、檢驗(yàn)數(shù)據(jù)、市場(chǎng)需求及客戶要求等信息。確定了《銅鎳鈷硅合金帶箔材》標(biāo)準(zhǔn)起草所遵循的基本原則和編制依據(jù)：1）查閱相關(guān)標(biāo)準(zhǔn)和國(guó)內(nèi)外客戶的相關(guān)技術(shù)要求；2）根據(jù)國(guó)內(nèi)銅鎳鈷硅合金帶箔材生產(chǎn)企業(yè)具體情況，力求做到標(biāo)準(zhǔn)的合理性與實(shí)用性；3）根據(jù)技術(shù)發(fā)展水平及測(cè)試數(shù)據(jù)確定技術(shù)指標(biāo)取值范圍；4）完全按照GB/T1.1和有色加工產(chǎn)品標(biāo)準(zhǔn)和國(guó)家標(biāo)準(zhǔn)編寫示例的要求進(jìn)行格式和結(jié)構(gòu)編寫。四、確定標(biāo)準(zhǔn)主要內(nèi)容的論據(jù)1標(biāo)準(zhǔn)題目與適用范圍本文件立項(xiàng)名稱為《銅鎳鈷硅合金帶箔材》。此標(biāo)準(zhǔn)名稱一方面規(guī)定了產(chǎn)品是銅合金箔帶材，另一方面也體現(xiàn)了產(chǎn)品主要合金元素為鎳鈷硅。2要求2.1產(chǎn)品分類產(chǎn)品分類是對(duì)銅鎳鈷硅合金帶箔材的牌號(hào)、代號(hào)、狀態(tài)、規(guī)格應(yīng)符合的規(guī)定，同時(shí)規(guī)定了產(chǎn)品標(biāo)記方法。相關(guān)情況分別說(shuō)明如下：（1）本標(biāo)準(zhǔn)根據(jù)我國(guó)銅鎳鈷硅合金帶箔材應(yīng)用的實(shí)際，參考了相關(guān)國(guó)家標(biāo)準(zhǔn)中的1個(gè)牌號(hào)：C70350。（2）狀態(tài)的確定，銅鎳鈷硅合金帶箔材標(biāo)準(zhǔn)對(duì)產(chǎn)品狀態(tài)標(biāo)示參照GB/T29094-2012標(biāo)準(zhǔn)，確定硬（TM04)、特硬（TM06）、彈性（TM08）三種狀態(tài)。（3）規(guī)格范圍：本標(biāo)準(zhǔn)根據(jù)銅鎳鈷硅合金帶箔材的要求，及實(shí)際生產(chǎn)控制水平和目前客戶的使用要求，規(guī)定公稱尺寸為厚度（0.08~0.5）*寬度（8~600）mm，都能滿足目前用戶的使用要求。（4）產(chǎn)品標(biāo)記方法：按照GB/T1.1-2009的規(guī)定，標(biāo)準(zhǔn)中分別給出了產(chǎn)品的典型標(biāo)記示例。2.2化學(xué)成分本標(biāo)準(zhǔn)中的牌號(hào)都是來(lái)自GB/T5231中的牌號(hào)，化學(xué)成分應(yīng)符合GB/T5231的規(guī)定。2.3尺寸及尺寸允許偏差對(duì)每一批產(chǎn)品，企業(yè)都要在出廠前對(duì)產(chǎn)品的外形尺寸進(jìn)行嚴(yán)格的抽樣檢測(cè)。本標(biāo)準(zhǔn)尺寸及尺寸允許偏差根據(jù)銅鎳鈷硅合金帶箔材的要求制定。2.3.1厚度帶箔材的厚度尺寸及其允許偏差見表1。表1帶箔材的厚度及允許偏差 單位為毫米厚度厚度允許偏差普通級(jí)較高級(jí)0.05-0.15±0.003±0.0025≥0.15-0.2±0.005±0.004≥0.2-0.3±0.006±0.005≥0.3-0.4±0.008±0.0075≥0.4-0.6±0.0125±0.010≥0.6-0.8±0.015±0.0125≥0.8-1.0±0.020±0.0152.3.2寬度帶箔材的寬度應(yīng)符合表2的規(guī)定。表2帶箔材的寬度及允許偏差單位為毫米寬度寬度及允許偏差5-8080-120120-400400-6100.05-0.50±0.05±0.075±0.1±0.15≥0.50-1.0±0.08±0.1±0.15±0.22.3.3側(cè)邊彎曲度帶箔材的側(cè)邊彎曲度應(yīng)符合表3的規(guī)定。表3帶材的側(cè)邊彎曲度單位為毫米寬度/mm側(cè)邊彎曲度允許偏差（mm/m）普通級(jí)高級(jí)厚度≥0.05-0.60厚度≥0.60-3.0厚度≥0.05-0.60厚度≥0.60-1.07.5-95634＞9-133.54.023＞13-253.03.51.52.5＞25-502.53.01.52＞50-1002.53.01.52＞100-600231.51.52.3.4毛刺本標(biāo)準(zhǔn)根據(jù)銅鎳鈷硅合金帶箔材的要求制定。表4帶箔材的毛刺要求單位為毫米厚度邊緣毛刺≤0.500.01＞0.50-1.00.022.3力學(xué)性能本標(biāo)準(zhǔn)根據(jù)銅鎳鈷硅合金帶箔材的要求制定。表5帶箔材的力學(xué)性能牌號(hào)狀態(tài)抗拉強(qiáng)度Rm/MPa斷后伸長(zhǎng)率A50mm％維氏硬度HVBSi2-0.8TM04770-900≥4220-280TM06840-970≥1240-300TM08≥900≥1≥2702.4彎曲性能本標(biāo)準(zhǔn)根據(jù)銅鎳鈷硅合金帶箔材的要求制定。表6帶箔材90°彎曲試驗(yàn)條件合金牌號(hào)狀態(tài)最大彎曲內(nèi)側(cè)半徑a厚度b：0.1mm~1mm垂直于軋制方向（GW）平行于軋制方向（BW）BSi2-0.8TM041×t1×tTM062×t2×tTM083.5×t4×t注1：t表示帶材厚度a0×t表示彎曲內(nèi)側(cè)半徑≤0.1mm。b厚度大于1mm的帶材，彎曲試驗(yàn)條件由供需雙方商定2.5抗應(yīng)力松弛應(yīng)力松弛率是恒量材料在常溫或高溫下，隨著時(shí)間的變化，保持應(yīng)力恒定的定量指標(biāo)。隨著端子連接器等電子元器件向著微型化、薄型化、高密度和高度集成化發(fā)展，在長(zhǎng)時(shí)間使用中產(chǎn)生的熱效應(yīng)不斷增加，部分元器件還可能在更高的溫度下長(zhǎng)時(shí)間使用，為了保持端子連接器彈片的嵌合力，這就要求材料具有優(yōu)良的抗應(yīng)力松弛性能。應(yīng)力松弛性能已成為未來(lái)高端端子連接器材料的重要性能指標(biāo)，目前部分下游企業(yè)已對(duì)材料提出了應(yīng)力松弛性能的要求。因此本標(biāo)準(zhǔn)中創(chuàng)新性的引入彎曲應(yīng)力松弛試驗(yàn)，符合未來(lái)高端連接器材料的使用需求，也體現(xiàn)出本標(biāo)準(zhǔn)的先進(jìn)性及前瞻性。目前生產(chǎn)企業(yè)通常采用彎曲應(yīng)力松弛試驗(yàn)方法測(cè)量材料的應(yīng)力松弛率，但企業(yè)及下游客戶對(duì)彎曲應(yīng)力松弛性能的檢測(cè)方法、試驗(yàn)裝置以及評(píng)價(jià)指標(biāo)均沒有一個(gè)統(tǒng)一的標(biāo)準(zhǔn)，因此本標(biāo)準(zhǔn)提出當(dāng)客戶有需求時(shí)，彎曲應(yīng)力松弛性能指標(biāo)以及試驗(yàn)方法由供需雙方協(xié)商決定。表7抗應(yīng)力松弛性能合金牌號(hào)狀態(tài)抗應(yīng)力松弛率%BSi2-0.8TM0470TM0670TM08552.6電性能當(dāng)需方要求帶箔材電性能時(shí)，電性能應(yīng)由供需雙方協(xié)商決定，帶箔材電性能的測(cè)試方法按YS/T478以及GB/T3930的規(guī)定進(jìn)行。表8電性能合金牌號(hào)20℃時(shí)導(dǎo)電率/%IACSBSi2-0.8≥402.7表面質(zhì)量本標(biāo)準(zhǔn)根據(jù)端子連接器用銅及銅合金帶箔材的要求制定。規(guī)定帶箔材的表面應(yīng)光滑、清潔，不允許有任何影響使用的缺陷。標(biāo)準(zhǔn)水平分析本標(biāo)準(zhǔn)合金牌號(hào)1個(gè)，等同采用ASTM牌號(hào)、國(guó)家標(biāo)準(zhǔn)1個(gè)；等同采用日標(biāo)的牌號(hào)1個(gè)。本標(biāo)準(zhǔn)是依據(jù)目前我國(guó)銅及銅合金加工的實(shí)際生產(chǎn)和使用情況制定的，基本與國(guó)外先進(jìn)標(biāo)準(zhǔn)保持一致，本標(biāo)準(zhǔn)達(dá)到國(guó)際先進(jìn)水平。四、標(biāo)準(zhǔn)主要內(nèi)容的確定依據(jù)4.1合金成分實(shí)測(cè)情況BSi2-0.8合金實(shí)測(cè)成分見下表。表9BSi2-0.8合金實(shí)測(cè)的成分統(tǒng)計(jì)數(shù)據(jù)表元素NiCoSiMnFeZnPbMg標(biāo)準(zhǔn)值1.0～2.51.0～2.00.5～1.2≤0.20≤0.20≤1.0≤0.05≤0.15實(shí)際值范圍1.41～1.90.95～1.530.5～0.70.01～0.190.007～0.1290.003～0.0820.0002～0.00390.001～0.071統(tǒng)計(jì)數(shù)（個(gè)）291291291291291291291291合格率（%）10097.261001001001001001004.2外形尺寸實(shí)測(cè)情況BSi2-0.8外形尺寸實(shí)測(cè)數(shù)據(jù)見附錄。4.3力學(xué)性能實(shí)測(cè)情況表10BSi2-0.8（TM04)合金抗拉強(qiáng)度數(shù)據(jù)表合金牌號(hào)狀態(tài)樣品數(shù)量（個(gè)）抗拉強(qiáng)度檢測(cè)結(jié)果范圍（MPa）BSi2-0.8TM04148770-876圖1BSi2-0.8（TM04)合金抗拉強(qiáng)度分布圖表11BSi2-0.8（TM06)合金抗拉強(qiáng)度數(shù)據(jù)表合金牌號(hào)狀態(tài)樣品數(shù)量（個(gè)）抗拉強(qiáng)度檢測(cè)結(jié)果范圍（MPa）BSi2-0.8TM06135840-901圖2BSi2-0.8（TM06)合金抗拉強(qiáng)度分布圖表12BSi2-0.8（TM04)合金斷后伸長(zhǎng)率數(shù)據(jù)表合金牌號(hào)狀態(tài)樣品數(shù)量（個(gè)）斷后伸長(zhǎng)率檢測(cè)結(jié)果范圍（%）BSi2-0.8TM041483.5~9圖3BSi2-0.8（TM04)合金斷后伸長(zhǎng)率分布圖表13BSi2-0.8（TM06)合金斷后伸長(zhǎng)率數(shù)據(jù)表合金牌號(hào)狀態(tài)樣品數(shù)量（個(gè)）斷后伸長(zhǎng)率檢測(cè)結(jié)果范圍（%）BSi2-0.8TM061351~12圖4BSi2-0.8（TM06)合金斷后伸長(zhǎng)率分布圖表14BSi2-0.8（TM04)合金維氏硬度數(shù)據(jù)表合金牌號(hào)狀態(tài)樣品數(shù)量（個(gè)）維氏硬度檢測(cè)結(jié)果范圍（HV）BSi2-0.8TM04148220~269圖5BSi2-0.8（TM04)合金維氏硬度分布圖表15BSi2-0.8（TM06)合金維氏硬度數(shù)據(jù)表合金牌號(hào)狀態(tài)樣品數(shù)量（個(gè)）維氏硬度檢測(cè)結(jié)果范圍（HV）BSi2-0.8TM06135243~280圖6BSi2-0.8（TM06)合金維氏硬度分布圖表16BSi2-0.8(TM08)合金實(shí)測(cè)的力學(xué)性能統(tǒng)計(jì)數(shù)據(jù)表狀態(tài)抗拉強(qiáng)度斷后伸長(zhǎng)率維氏硬度范圍/MPa數(shù)量合格率范圍/%數(shù)量合格率范圍/%HV數(shù)量合格率TM02921~9278100%1.5~3.08100%275~2848100%4.3電性能實(shí)測(cè)情況表17BSi2-0.8合金導(dǎo)電率數(shù)據(jù)表合金牌號(hào)狀態(tài)樣品數(shù)量（個(gè)）導(dǎo)電率檢測(cè)結(jié)果范圍（%IACS）BSi2-0.8TM04+TM064+TM0829144-53圖7BSi2-0.8合金導(dǎo)電率分布圖4.4其他指標(biāo)實(shí)測(cè)情況表面質(zhì)量均合格，彎曲性能和抗應(yīng)力松弛數(shù)據(jù)待補(bǔ)充。五、與現(xiàn)行相關(guān)法律、法規(guī)、規(guī)章及相關(guān)標(biāo)準(zhǔn)，特別是強(qiáng)制性標(biāo)準(zhǔn)的協(xié)調(diào)性與現(xiàn)行相關(guān)法律、法規(guī)、規(guī)章及相關(guān)強(qiáng)制推薦的標(biāo)準(zhǔn)沒有沖突。六、重大分歧意見的處理經(jīng)過(guò)和依據(jù)無(wú)。七、標(biāo)準(zhǔn)作為強(qiáng)制性或推薦性國(guó)家（或行業(yè)）標(biāo)準(zhǔn)的建議本標(biāo)準(zhǔn)建議不作為強(qiáng)制性標(biāo)準(zhǔn)，建議作為推薦性標(biāo)準(zhǔn)。八、貫徹標(biāo)準(zhǔn)的要求和措施建議本標(biāo)準(zhǔn)是以我國(guó)銅鎳鈷硅合金帶箔材的實(shí)際生產(chǎn)現(xiàn)狀為基礎(chǔ)，結(jié)合國(guó)內(nèi)、外訂貨合同要求，建議相關(guān)單位組織專項(xiàng)標(biāo)準(zhǔn)宣貫會(huì)進(jìn)行系統(tǒng)學(xué)習(xí)。本標(biāo)準(zhǔn)發(fā)布后，各企業(yè)應(yīng)積極宣傳和貫徹，并立即采用新標(biāo)準(zhǔn)訂貨，以保證產(chǎn)品質(zhì)量，滿足國(guó)內(nèi)、外市場(chǎng)及用戶的需要。九、廢止現(xiàn)行有關(guān)標(biāo)準(zhǔn)的建議無(wú)。十、其它應(yīng)予說(shuō)明的事項(xiàng)本標(biāo)準(zhǔn)根據(jù)目前國(guó)內(nèi)銅鎳鈷硅合金帶箔材的實(shí)際生產(chǎn)現(xiàn)狀和訂貨合同情況確定合金的牌號(hào)及成分、性能以及其它的要求。考慮隨著新材料的開發(fā)使用和生產(chǎn)裝備的更新，如果以后生產(chǎn)或訂貨合同中有其它合金或狀態(tài)需求可在下一版中進(jìn)行補(bǔ)充修訂。十一、預(yù)期效果通過(guò)標(biāo)準(zhǔn)的貫徹實(shí)施，將提高我國(guó)銅鎳鈷硅合金帶箔材規(guī)范并提高該類產(chǎn)品的生產(chǎn)控制水平。本標(biāo)準(zhǔn)結(jié)合我國(guó)國(guó)情，在國(guó)內(nèi)生產(chǎn)企業(yè)及國(guó)內(nèi)外用戶需求的基礎(chǔ)上，參照國(guó)內(nèi)外相關(guān)產(chǎn)品標(biāo)準(zhǔn)規(guī)范制定的，技術(shù)指標(biāo)先進(jìn)，具有普遍性、廣泛性、適用性、科學(xué)性和先進(jìn)性。本標(biāo)準(zhǔn)發(fā)布后，將規(guī)范我國(guó)銅鎳鈷硅合金帶箔材的性能和技術(shù)要求，提高產(chǎn)品在國(guó)內(nèi)、外市場(chǎng)上的競(jìng)爭(zhēng)力，給生產(chǎn)企業(yè)帶來(lái)較大的經(jīng)濟(jì)效益?！躲~鎳鈷硅合金帶箔材》行業(yè)標(biāo)準(zhǔn)編制組2022年11月7日附錄序號(hào)狀態(tài)厚度寬度抗拉延伸硬度屈服強(qiáng)度導(dǎo)電率%厚度公差寬度公差表面質(zhì)量1TM040.12286844425380046.70.0010.025合格2TM040.255258185.5258759530.0050.03合格3TM040.255158187.5258759530.0050.045合格4TM040.25787754.523075051.20.0050.025合格5TM040.2550781724175448.90.00250.03合格6TM040.3585777623174545.90.0050.05合格7TM040.255828153.5235789510.0050.035合格8TM040.25300771522075048.40.0050.025合格9TM040.25307724.524072251.10.0040.025合格10TM040.25317724.524072251.10.0040.03合格11TM040.25567771522075048.40.0050.05合格12TM040.33057925.524074745.80.0050.025合格13TM040.254307735.522973047.30.0050.04合格14TM040.25300778623275145.30.00050.025合格15TM040.2300800424476045.90.00350.025合格16TM040.2230810423479145.20.0010.0035合格17TM040.2200804424077146.80.0010.0035合格18TM040.25290781423876146.50.0020.0035合格19TM040.2300770623874245.20.00150.0035合格20TM040.2300770623874245.20.00150.0035合格21TM040.3326788623876345.70.0020.0035合格22TM040.23007914.524177445.60.0010合格23TM040.1515775423775047.50.0020.025合格24TM040.15300783424275247.50.0020.02合格25TM040.25280773424175545.80.00150合格26TM040.219.37914.524177445.60.0020.025合格27TM040.25240822524880244.20.00150合格28TM040.2300794424077145.20.0010合格29TM040.23380788524176746.70.0020.0035合格30TM040.825808622977648.80.0030.03合格31TM040.8200808622977648.80.0020合格32TM040.2300815424875845.20.0020.02合格33TM040.25300796623575546.40.00050.02合格34TM040.25300840425578546.60.0010.02合格35TM040.2523.5840425578546.60.0020.025合格36TM040.861812923876345.50.00150.015合格37TM040.3343822426079046.50.0010.03合格38TM040.25202836725977148.70.00050.02合格39TM040.22708324.525876344.40.0010.02合格40TM040.252808354.525977747.90.0010.02合格41TM040.2300783524175550.30.0010.03合格42TM040.251808395.525978745.60.00150.02合格43TM040.8300808622977648.80.0030.02合格44TM040.8600808622977648.80.0030.035合格45TM040.2300770523472948.10.0010.02合格46TM040.252008234.525175947.60.0020.03合格47TM040.623862425081645.40.00250.02合格48TM040.676862425081645.50.00250.02合格49TM040.623862425081645.40.00250.02合格50TM040.2300857425580244.40.00050.025合格51TM040.25160839424576444.20.0020.015合格52TM040.08300806423777644.40.00150.025合格53TM040.2280850526580146.70.00050.015合格54TM040.217850526580146.20.0020.025合格55TM040.3250842425378446.10.0020.025合格56TM040.2280850526580146.20.0020.025合格57TM040.2521.5820424477346.50.00250.03合格58TM040.22108463.525481245.90.0010.025合格59TM040.15280840426084044.80.0010.025合格60TM040.15400840426083044.80.00050.025合格61TM040.25270784425671746.10.0010.0035合格62TM040.252708423.525177244.90.0010.0035合格63TM040.2280820625875446.10.0020.02合格64TM040.2300814525975346.30.0020.03合格65TM040.253.58184.525975146.30.0010.02合格66TM040.253008146253754470.00050.03合格67TM040.25300821525575646.70.00050.02合格68TM040.25300818624576346.10.0010.015合格69TM040.15270816425577347.40.00150.025合格70TM040.15360839425376848.30.00050.03合格71TM040.151518374268798490.00050.025合格72TM040.1528.58374268798490.0010.025合格73TM040.25300804625573549.30.0010.03合格74TM040.2300826426876547.40.0010.025合格75TM040.06200869426682744.80.00050.025合格76TM040.22808393.525677444.70.00050.025合格77TM040.2250806425772546.10.0010.025合格78TM040.3300842425378446.10.0020.02合格79TM040.2300845425880046.10.00150.02合格80TM040.2300815425076346.70.0010.02合格81TM040.2293840424779446.20.00050.02合格82TM040.225817425576846.30.0020.02合格83TM040.25300816424677247.30.00050.02合格84TM040.230840424779446.20.0020.015合格85TM040.15300852426179244.50.00050.02合格86TM040.15270800424275346.20.0020.02合格87TM040.2300850425980246.40.00050.03合格88TM040.3250842425378446.10.0020.025合格89TM040.2315840424978347.50.00150.03合格90TM040.06230832426578346.10.00050.025合格91TM040.06200792424675345.90.0010.025合格92TM040.25300823425478746.80.00050.025合格93TM040.3310816625175347.40.00150.025合格94TM040.25300811624776947.10.0020.025合格95TM040.12300853423580246.20.00050.03合格96TM040.2270821625077047.90.0010.03合格97TM040.253.5850526580146.20.0020.015合格98TM040.25300827424978047.40.00050.025合格99TM040.2280812525276846.20.00050.025合格100TM040.2300816424679646.60.0010.025合格101TM040.12300876426084945.20.00050.025合格102TM040.063008503.524782647.40.00050.025合格103TM040.08100806423777644.40.00150.015合格104TM040.32207965251759460.0010.0035合格105TM040.1527833425581047.40.00150.02合格106TM040.15300840625580447.40.00050.02合格107TM040.25300807425475547.90.0010.0035合格108TM040.25300807425475347.90.00050.0035合格109TM040.15300808425776948.40.00050.02合格110TM040.25300820425478246.70.00050.0035合格111TM040.2300844526280446.70.0010.0035合格112TM040.2200844526280446.70.0010.0035合格113TM040.25280831425379846.80.00050.03合格114TM040.25260810524776746.30.00050.0035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