氟化鈉化學(xué)品安全技術(shù)說明書

1、氟化鈉化學(xué)品安全技術(shù)說明書說明書目錄第一部分化學(xué)品名稱第九部分理化特性第二部分成分/組成信息第十部分穩(wěn)定性和反應(yīng)活性第三部分危險(xiǎn)性概述第十一部分毒理學(xué)資料第四部分急救措施第十二部分生態(tài)學(xué)資料第五部分消防措施第十三部分廢棄處置第六部分泄漏應(yīng)急處理第十四部分運(yùn)輸信息第七部分操作處置與儲(chǔ)存第十五部分法規(guī)信息第八部分接觸控制/個(gè)體防護(hù)第十六部分其他信息第一部分:化學(xué)品名稱化學(xué)品中文名稱:氟化鈉化學(xué)品英文名稱:sodiumfluoride中文名稱2:英文名稱2:技術(shù)說明書編碼:760CASNo.:7681-49-4分子式:NaF分子量:42.00第二部分:成分/組成信息有害物成分含量CASNo.氟化鈉?

2、99.0,7681-49-4than?5mm;elevationdeviationwaslessthan?5mmworksurfaceheightdifferenceisnotmorethan3mmontheoneendtotheotherend;wrongtoothatthejointislessthan1mm.Siderailmounting:siderailinstallationtakeeachsiderailontwopoints.Duringtheinstallationprocess,usetensionertoadjustthesiderail.Siderailholetopc

3、enterwithinthescopeoftheworkislessthan+2-1mm,scopeofworkata4-to-2;wrongtoothlessthan1mmatthejointworksurfaceflatness2mmlateralcurvatureRADIUSislessthan?5mmsealingplatesurfacedistortionislessthan1mm.Reinforcementprocessofadjustmentiscompleted,inordertopreventtankdeformationordisplacement,weldedtanksi

4、deofthedoor,thenweldedreinforcingside,laplengthisnotlessthan100mm.Doorinstallation:thelinteltheinstallationfocusesonfamilyCentersillplanedistancehislessthan?3mm;worksurfaceflatnessoflessthan2mm;combinationofsurfacedislocationislessthan0.5mmsurfacedistortionislessthan1.5mm.Modewiththesiderail.Gridslo

5、tbi-directionalgateleafonacarliftandlowergrillebladeadjustmentiscompletedwithpinconnection,thentryconnectingrod.Afteryouchecktheaccessoriescompletethefastening,hangingoutthebottomopeningandclosingtestinstillwaterasawhole.8.2.3tainterandhingeinstallationSetup:Pivotfixedbearinginstallation?orbitstitch

6、ing,alignment?armsplicing,installationconnectedwiththeheadstock?weldingdoorleafsideconnectingplateswelded,watersealinstallation?clean,andwipeoff.8.2.3.1hingeinstallationand第三部分:危險(xiǎn)性概述危險(xiǎn)性類別:侵入途徑:健康危害:急性中毒:多為誤服所致。服后立即出現(xiàn)劇烈惡心、嘔吐、腹痛、腹瀉。重者休克、呼吸困難、紫紺。如不及時(shí)搶救可致死亡。部分患者出現(xiàn)尊麻疹，吞咽肌麻痹，手足抽搐或四肢肌肉痙攣。短期內(nèi)吸入大量本品粉塵，引起呼吸道刺

7、激癥狀，并伴有頭昏、頭痛、無力及消化道癥狀。慢性影響長(zhǎng)期較高濃度吸入可引起氟骨癥?？芍缕ぱ祝卣叱霈F(xiàn)潰瘍或大皰。環(huán)境危害：燃爆危險(xiǎn)：本品不燃，高毒，具刺激性，嚴(yán)重?fù)p害粘膜、上呼吸道、眼睛和皮膚。第四部分：急救措施皮膚接觸：脫去污染的衣著，用肥皂水和清水徹底沖洗皮膚。眼睛接觸：提起眼瞼，用流動(dòng)清水或生理鹽水沖洗。就醫(yī)。吸入：迅速脫離現(xiàn)場(chǎng)至空氣新鮮處。保持呼吸道通暢。如呼吸困難，給輸氧。如呼吸停止，立即進(jìn)行人工呼吸。就醫(yī)。食入：飲足量溫水，催吐。洗胃。就醫(yī)。第五部分：消防措施危險(xiǎn)特性：與酸類反應(yīng)放出有腐蝕性、刺激性更強(qiáng)的氫氟酸，能腐蝕玻璃。有害燃燒產(chǎn)物：氟化氫。滅火方法：用大量水滅火。用霧狀水驅(qū)散

8、煙霧與刺激性氣體。第六部分：泄漏應(yīng)急處理應(yīng)急處理：隔離泄漏污染區(qū)，限制出入。建議應(yīng)急處理人員戴防塵面具（全面罩），穿防毒服。不要直接接觸泄漏物。小量泄漏：避免揚(yáng)塵，用潔凈的鏟子收集于干燥、潔凈、有蓋的容器中。大量泄漏：用塑料布、帆布覆蓋。然后收集回收或運(yùn)至廢物處理場(chǎng)所處置。第七部分:操作處置與儲(chǔ)存than?5mm;elevationdeviationwaslessthan?5mmworksurfaceheightdifferenceisnotmorethan3mmontheoneendtotheotherend;wrongtoothatthejointislessthan1mm.Siderai

9、lmounting:siderailinstallationtakeeachsiderailontwopoints.Duringtheinstallationprocess,usetensionertoadjustthesiderail.Siderailholetopcenterwithinthescopeoftheworkislessthan+2-1mm,scopeofworkata4-to-2;wrongtoothlessthan1mmatthejointworksurfaceflatness2mmlateralcurvatureRADIUSislessthan?5mmsealingpla

10、tesurfacedistortionislessthan1mm.Reinforcementprocessofadjustmentiscompleted,inordertopreventtankdeformationordisplacement,weldedtanksideofthedoor,thenweldedreinforcingside,laplengthisnotlessthan100mm.Doorinstallation:thelinteltheinstallationfocusesonfamilyCentersillplanedistancehislessthan?3mm;work

11、surfaceflatnessoflessthan2mm;combinationofsurfacedislocationislessthan0.5mmsurfacedistortionislessthan1.5mm.Modewiththesiderail.Gridslotbi-directionalgateleafonacarliftandlowergrillebladeadjustmentiscompletedwithpinconnection,thentryconnectingrod.Afteryouchecktheaccessoriescompletethefastening,hangi

12、ngoutthebottomopeningandclosingtestinstillwaterasawhole.8.2.3tainterandhingeinstallationSetup:Pivotfixedbearinginstallation?orbitstitching,alignment?armsplicing,installationconnectedwiththeheadstock?weldingdoorleafsideconnectingplateswelded,watersealinstallation?clean,andwipeoff.8.2.3.1hingeinstalla

13、tionand氟化鈉化學(xué)品安全技術(shù)說明書操作注意事項(xiàng):密閉操作，局部排風(fēng)。操作人員必須經(jīng)過專門培訓(xùn)，嚴(yán)格遵守操作規(guī)程。建議操作人員佩戴自吸過濾式防塵口罩，戴化學(xué)安全防護(hù)眼鏡，穿透氣型防毒服，戴乳膠手套。避免產(chǎn)生粉塵。避免與酸類接觸。搬運(yùn)時(shí)要輕裝輕卸，防止包裝及容器損壞。配備泄漏應(yīng)急處理設(shè)備。倒空的容器可能殘留有害物。儲(chǔ)存注意事項(xiàng):儲(chǔ)存于陰涼、干燥、通風(fēng)良好的庫(kù)房。庫(kù)溫不超過30?，相對(duì)濕度不超過80,。包裝密封。應(yīng)與酸類、食用化學(xué)品分開存放，切忌混儲(chǔ)。儲(chǔ)區(qū)應(yīng)備有合適的材料收容泄漏物。應(yīng)嚴(yán)格執(zhí)行極毒物品“五雙”管理制度。第八部分:接觸控制/個(gè)體防護(hù)職業(yè)接觸限值中國(guó)MAC(mg/m3):1F前蘇聯(lián)

14、MAC(mg/m3):1/0.2FTLVTN:OSHA2.5mgF/m3;ACGIH2.5mgF/m3TLVWN:未制定標(biāo)準(zhǔn)監(jiān)測(cè)方法:離子選擇性電極法;氟試劑,鑭鹽比色法工程控制:密閉操作，局部排風(fēng)。提供安全淋浴和洗眼設(shè)備。呼吸系統(tǒng)防護(hù):可能接觸其粉塵時(shí)，應(yīng)該佩戴自吸過濾式防塵口罩。緊急事態(tài)搶救或撤離時(shí)，建議佩戴自給式呼吸器。眼睛防護(hù):戴化學(xué)安全防護(hù)眼鏡。身體防護(hù):穿透氣型防毒服。手防護(hù):戴乳膠手套。其他防護(hù):工作現(xiàn)場(chǎng)禁止吸煙、進(jìn)食和飲水。工作完畢，淋浴更衣。工作服不準(zhǔn)帶至非作業(yè)場(chǎng)所。單獨(dú)存放被毒物污染的衣服，洗后備用。保持良好的衛(wèi)生習(xí)慣。第九部分:理化特性主要成分:含量:工業(yè)級(jí)一級(jí)?99.0

15、,;二級(jí)?84,。外觀與性狀:白色粉末或結(jié)晶，無臭。pH:熔點(diǎn)(?):993沸點(diǎn)(?):1700than?5mm;elevationdeviationwaslessthan?5mmworksurfaceheightdifferenceisnotmorethan3mmontheoneendtotheotherend;wrongtoothatthejointislessthan1mm.Siderailmounting:siderailinstallationtakeeachsiderailontwopoints.Duringtheinstallationprocess,usetensionerto

16、adjustthesiderail.Siderailholetopcenterwithinthescopeoftheworkislessthan+2-1mm,scopeofworkata4-to-2;wrongtoothlessthan1mmatthejointworksurfaceflatness2mmlateralcurvatureRADIUSislessthan?5mmsealingplatesurfacedistortionislessthan1mm.Reinforcementprocessofadjustmentiscompleted,inordertopreventtankdefo

17、rmationordisplacement,weldedtanksideofthedoor,thenweldedreinforcingside,laplengthisnotlessthan100mm.Doorinstallation:thelinteltheinstallationfocusesonfamilyCentersillplanedistancehislessthan?3mm;worksurfaceflatnessoflessthan2mm;combinationofsurfacedislocationislessthan0.5mmsurfacedistortionislesstha

18、n1.5mm.Modewiththesiderail.Gridslotbi-directionalgateleafonacarliftandlowergrillebladeadjustmentiscompletedwithpinconnection,thentryconnectingrod.Afteryouchecktheaccessoriescompletethefastening,hangingoutthebottomopeningandclosingtestinstillwaterasawhole.8.2.3tainterandhingeinstallationSetup:Pivotfi

19、xedbearinginstallation?orbitstitching,alignment?armsplicing,installationconnectedwiththeheadstock?weldingdoorleafsideconnectingplateswelded,watersealinstallation?clean,andwipeoff.8.2.3.1hingeinstallationand相對(duì)密度(水=1):2.56相對(duì)蒸氣密度(空氣=1):無資料飽和蒸氣壓(kPa):0.13(1077?)燃燒熱(kJ/mol):無意義臨界溫度(?):無資料臨界壓力(MPa):無資料辛醇/

20、水分配系數(shù)的對(duì)數(shù)值:無資料閃點(diǎn)(?):無意義引燃溫度(?):無意義爆炸上限%(V/V):無意義爆炸下限%(V/V):無意義溶解性:溶于水，微溶于醇。主要用途:用作殺蟲劑、木材防腐劑。其它理化性質(zhì):第十部分:穩(wěn)定性和反應(yīng)活性穩(wěn)定性:禁配物:強(qiáng)酸。避免接觸的條件:潮濕空氣。聚合危害:分解產(chǎn)物:第十一部分:毒理學(xué)資料急性毒性:LD50:52mg/kg（大鼠經(jīng)口）;57mg/kg（小鼠經(jīng)口）LC50:無資料亞急性和慢性毒性:than?5mm;elevationdeviationwaslessthan?5mmworksurfaceheightdifferenceisnotmorethan3mmonthe

21、oneendtotheotherend;wrongtoothatthejointislessthan1mm.Siderailmounting:siderailinstallationtakeeachsiderailontwopoints.Duringtheinstallationprocess,usetensionertoadjustthesiderail.Siderailholetopcenterwithinthescopeoftheworkislessthan+2-1mm,scopeofworkata4-to-2;wrongtoothlessthan1mmatthejointworksur

22、faceflatness2mmlateralcurvatureRADIUSislessthan?5mmsealingplatesurfacedistortionislessthan1mm.Reinforcementprocessofadjustmentiscompleted,inordertopreventtankdeformationordisplacement,weldedtanksideofthedoor,thenweldedreinforcingside,laplengthisnotlessthan100mm.Doorinstallation:thelinteltheinstallat

23、ionfocusesonfamilyCentersillplanedistancehislessthan?3mm;worksurfaceflatnessoflessthan2mm;combinationofsurfacedislocationislessthan0.5mmsurfacedistortionislessthan1.5mm.Modewiththesiderail.Gridslotbi-directionalgateleafonacarliftandlowergrillebladeadjustmentiscompletedwithpinconnection,thentryconnec

24、tingrod.Afteryouchecktheaccessoriescompletethefastening,hangingoutthebottomopeningandclosingtestinstillwaterasawhole.8.2.3tainterandhingeinstallationSetup:Pivotfixedbearinginstallation?orbitstitching,alignment?armsplicing,installationconnectedwiththeheadstock?weldingdoorleafsideconnectingplateswelde

25、d,watersealinstallation?clean,andwipeoff.8.2.3.1hingeinstallationand氟化鈉化學(xué)品安全技術(shù)說明書刺激性:家兔經(jīng)眼:20mg/24小時(shí)，中度刺激。致敏性:致突變性:致畸性:致癌性:第十二部分:生態(tài)學(xué)資料生態(tài)毒理毒性:生物降解性:非生物降解性:生物富集或生物積累性:其它有害作用:無資料。第十三部分:廢棄處置廢棄物性質(zhì):廢棄處置方法:根據(jù)國(guó)家和地方有關(guān)法規(guī)的要求處置?；蚺c廠商或制造商聯(lián)系，確定處置方法。廢棄注意事項(xiàng):第十四部分:運(yùn)輸信息危險(xiǎn)貨物編號(hào):61513UN編號(hào)：1690包裝標(biāo)志:包裝類別:O53包裝方法:塑料袋或二層牛皮紙袋外

26、纖維板桶、膠合板桶、硬紙板桶;塑料袋外塑料桶（固體）;塑料桶（液體）;兩層塑料袋或一層塑料袋外麻袋、塑料編織袋、乳膠布袋;塑料袋外復(fù)合塑料編織袋（聚丙烯三合一袋、聚乙烯三合一袋、聚丙烯二合一袋、聚乙烯二合一袋）;塑料袋或二層牛皮紙袋外普通木箱;螺紋口玻璃瓶、鐵蓋壓口玻璃瓶、塑料瓶或金屬桶（罐）外普通木箱;螺紋口玻璃瓶、塑料瓶或鍍錫薄鋼板桶（罐）外滿底板花格箱、纖維板箱或膠合板箱。than?5mm;elevationdeviationwaslessthan?5mmworksurfaceheightdifferenceisnotmorethan3mmontheoneendtotheotherend

27、;wrongtoothatthejointislessthan1mm.Siderailmounting:siderailinstallationtakeeachsiderailontwopoints.Duringtheinstallationprocess,usetensionertoadjustthesiderail.Siderailholetopcenterwithinthescopeoftheworkislessthan+2-1mm,scopeofworkata4-to-2;wrongtoothlessthan1mmatthejointworksurfaceflatness2mmlate

28、ralcurvatureRADIUSislessthan?5mmsealingplatesurfacedistortionislessthan1mm.Reinforcementprocessofadjustmentiscompleted,inordertopreventtankdeformationordisplacement,weldedtanksideofthedoor,thenweldedreinforcingside,laplengthisnotlessthan100mm.Doorinstallation:thelinteltheinstallationfocusesonfamilyC

29、entersillplanedistancehislessthan?3mm;worksurfaceflatnessoflessthan2mm;combinationofsurfacedislocationislessthan0.5mmsurfacedistortionislessthan1.5mm.Modewiththesiderail.Gridslotbi-directionalgateleafonacarliftandlowergrillebladeadjustmentiscompletedwithpinconnection,thentryconnectingrod.Afteryouche

30、cktheaccessoriescompletethefastening,hangingoutthebottomopeningandclosingtestinstillwaterasawhole.8.2.3tainterandhingeinstallationSetup:Pivotfixedbearinginstallation?orbitstitching,alignment?armsplicing,installationconnectedwiththeheadstock?weldingdoorleafsideconnectingplateswelded,watersealinstalla

31、tion?clean,andwipeoff.8.2.3.1hingeinstallationand運(yùn)輸注意事項(xiàng):鐵路運(yùn)輸時(shí)應(yīng)嚴(yán)格按照鐵道部危險(xiǎn)貨物運(yùn)輸規(guī)則中的危險(xiǎn)貨物配裝表進(jìn)行配裝。運(yùn)輸前應(yīng)先檢查包裝容器是否完整、密封，運(yùn)輸過程中要確保容器不泄漏、不倒塌、不墜落、不損壞。嚴(yán)禁與酸類、氧化劑、食品及食品添加劑混運(yùn)。運(yùn)輸時(shí)運(yùn)輸車輛應(yīng)配備泄漏應(yīng)急處理設(shè)備。運(yùn)輸途中應(yīng)防曝曬、雨淋，防高溫。第十五部分:法規(guī)信息法規(guī)信息化學(xué)危險(xiǎn)物品安全管理?xiàng)l例（1987年2月17日國(guó)務(wù)院發(fā)布），化學(xué)危險(xiǎn)物品安全管理?xiàng)l例實(shí)施細(xì)則（化勞發(fā)1992677號(hào)），工作場(chǎng)所安全使用化學(xué)品規(guī)定（1996勞部發(fā)423號(hào)）等法規(guī)，針對(duì)化學(xué)

32、危險(xiǎn)品的安全使用、生產(chǎn)、儲(chǔ)存、運(yùn)輸、裝卸等方面均作了相應(yīng)規(guī)定;常用危險(xiǎn)化學(xué)品的分類及標(biāo)志(GB13690-92)將該物質(zhì)劃為第6.1類毒害品;車間空氣中氟化物衛(wèi)生標(biāo)準(zhǔn)(GB16228-1996)，規(guī)定了車間空氣中該物質(zhì)的最高容許濃度及檢測(cè)方法。第十六部分:其他信息than?5mm;elevationdeviationwaslessthan?5mmworksurfaceheightdifferenceisnotmorethan3mmontheoneendtotheotherend;wrongtoothatthejointislessthan1mm.Siderailmounting:siderailinstallationtakeeachsiderailontwopoints.Duringtheinstallationprocess,usetensionertoadjustthesiderail.Siderailh