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1、The English language version is the original and the reference in case of dispute.Chemical substances whose use within the Volvo Group shall be limitedVolvos grey listOrientationThis issue differs from issue 1 in that:- a text regarding legal requirements has been added in section 1 Scope and field
2、of application- two new phthalates have been added under Plasticizers in table 1- the limits for metallic lead and lead compounds have been added- reference to EU directive for nickel release has been added- the risk of reproductive hazard has been added for dibutyl phthalate- in the footnote for he
3、xavalent chromium, the reference to STD 5732,104 has been replaced by a text stating the limit for the free hexavalent chromium- the substances in the tables have been sorted according to English alphabetical order.Two associated standards are STD 100-0002 “Chemical substance which must not be used
4、within the Volvo Group Volvos black list” and STD 100-0004 “Substitutes for hazardous chemical substances Volvos white list”.1 Scope and field of applicationAccording to a decision by the Volvo Group management, restrictions have been introduced with respect to the use of certain chemical substances
5、. This standard lists those chemical substances, which should not be used in Volvos production processes or found in unreacted form in Volvos products. The Volvo Groups Environmental Council initiates the updating of the standard.Please note that these lists are only Volvo standards and compli
6、ance with these lists does not mean that legal requirements concerning hazardous chemical substance in different countries are fulfilled.Products containing chemical substances including in this standard shall be kept under surveillance and active work shall be performed to find less hazardous alter
7、natives to be introduced as soon as this is technically and economically possilbe.英文版為原始版本,當(dāng)對(duì)本文解釋有爭(zhēng)議時(shí)以英文版為準(zhǔn)。Volvo集團(tuán)內(nèi)部限制使用的化學(xué)物質(zhì)Volvo灰色清單介紹此版本和第一版的不同之處是:在第一節(jié)適用范圍中增加了有關(guān)法律要求方面的內(nèi)容。- 在列表增塑劑類中增加了兩種鄰苯二甲酸酯。-在列表金屬類中增加了金屬鉛和鉛的化合物。-根據(jù)歐洲環(huán)境標(biāo)準(zhǔn)的要求增加了對(duì)鎳的使用限制。-在鄰苯二甲酸二丁酯的危害項(xiàng)中增加了生殖危害。-在關(guān)于六價(jià)鉻的腳注中,原來要求參考標(biāo)準(zhǔn)STD 5732,104的內(nèi)容被
8、有關(guān)自由價(jià)鉻限制標(biāo)準(zhǔn)的內(nèi)容所取代。-列表中的物質(zhì)按英文頭字母順序重新排列了。與此標(biāo)準(zhǔn)有關(guān)的兩個(gè)標(biāo)準(zhǔn)是STD 100-0002“Volvo 集團(tuán)內(nèi)部禁止使用的化學(xué)物質(zhì)-Volvo 黑色清單”和STD 100-0004“危險(xiǎn)化學(xué)物質(zhì)的替代品-Volvo白色清單”。1 適用范圍依據(jù)Volvo集團(tuán)管理層的決定,某些化學(xué)物質(zhì)的使用是受到限制的。此標(biāo)準(zhǔn)列出了在Volvo公司生產(chǎn)過程中不應(yīng)該使用的化學(xué)物質(zhì),在未處理前,它們也不允許存在于Volvo的產(chǎn)品中。Volvo集團(tuán)的環(huán)境委員會(huì)負(fù)責(zé)該標(biāo)準(zhǔn)的升級(jí)。請(qǐng)注意該清單僅僅是Volvo公司的標(biāo)準(zhǔn),滿足該標(biāo)準(zhǔn)的要求并不意味就能滿足各國(guó)當(dāng)?shù)赜嘘P(guān)危險(xiǎn)化
9、學(xué)品的法律限制。含有一種或多種清單列出的化學(xué)物質(zhì)的產(chǎn)品必須處于嚴(yán)格的監(jiān)督之下。同時(shí),只要技術(shù)和經(jīng)濟(jì)條件上一有可能,就需要采取有效措施尋找危害性更低的替代品。Befor new products containing one or more of the chemical substances listed in this standard putting into use, an assessment shall always be made regarding the possible use of less hazardous products.The restriction refer
10、to each deliberate use of the chemical substances specified in the standard at concentrations exceeding 0.1 per cent by mass. Specific limits noted in the list apply to some substances. However, the restriction does not apply in those cases a chemical substance occurs in the form of impurities in a
11、specific product, that is, non-desired occurrence in very low concentrations, or when it is handled in small quantities by trained staff at laboratories.Exceptions may also be made for chemical substances used in processes controlled by legal requirements or safety regulations where it is not possib
12、le for Volvo exclusively to limit the use of the substance in question. In situations where exceptions have to be made, special precautionary measures shall be taken to prevent injurious effects on human or the environment. The respective Volvo company shall decide upon any exceptions.Reference to t
13、his standard can be made in design prerequisites (DPR and is made in “Requirement for suppliers and contractors Environment”. For an example of reference to this standard, see section 3 Reference in documentation.在含有清單中所列的一種或幾種化學(xué)物質(zhì)的新產(chǎn)品投入使用之前,必須做一個(gè)評(píng)審以保證盡可能少的使用有危害的物質(zhì)。列表給出了每一種化學(xué)物質(zhì)限制使用的具體場(chǎng)合,在大批量的生產(chǎn)過程中,灰
14、色清單上的化學(xué)物質(zhì)濃度不允許超過0.1%。其中一些物質(zhì)注明了特殊的限制。然而,特殊產(chǎn)品中低濃度非希望的化學(xué)生成雜質(zhì)并不包括在清單禁止之列;在試驗(yàn)室中由專業(yè)人員控制的少量化學(xué)品也不在清單禁止之列。在Volvo公司沒有必要單獨(dú)禁止有爭(zhēng)議的化學(xué)物質(zhì)使用的情況下,如過程控制符合法律要求和安全規(guī)章,清單物質(zhì)的限制使用允許有例外,前提是采取特別的預(yù)防措施防止對(duì)人或環(huán)境產(chǎn)生危害。Volvo各公司可以自己決定是否援引例外條例。在有關(guān)設(shè)計(jì)前提條件(DPR的標(biāo)準(zhǔn)和文件“對(duì)供應(yīng)商和承包方的要求-環(huán)境部分”中可能要求參考本標(biāo)準(zhǔn)。在第三節(jié)演示了一個(gè)在文件中要求參考本標(biāo)準(zhǔn)的例子。2 List of substances
15、物質(zhì)清單Table 1EGroup分組Substance name化學(xué)物質(zhì)名CAS no. 1KEMI listed 10Example of type or area of use典型使用場(chǎng)合Risk 2危害Acids酸類Hydrofluoric acid氫氟酸7664-39-3OPickling, etching酸洗,蝕刻TAdditives添加劑Diphenylamine 3二苯胺122-39-4OLubricants潤(rùn)滑劑E, TSodium nitrite亞硝酸鈉7632-00-0-Anti-rust agent防銹劑C, TBiocides (No concentration li
16、mits生物殺滅劑Chlorocresol(meta-對(duì)氯代間甲酚59-50-7OLubricants, paints潤(rùn)滑劑,油漆E, AChlorocresol(ortho-4-氯-2-甲基苯酚1570-64-5-Lubricants, paints潤(rùn)滑劑,油漆E(probablyChloromethyl isothiazolinone5-氯-2-甲基-異噻唑啉-3-酮Methyl isothiazolinone2-甲基-4-異噻唑啉-3-酮Kathon CG凱松(為上兩種物質(zhì)的混合物26172-55-42682-20-455965-84-9OOOAqueous solution工業(yè)循環(huán)水處
17、理劑AOrganotin Comp. (trialkyl三烷基錫類化合物SeveralO, RCooling water冷卻水EThiram (TMTD雙硫胺甲酰137-26-8OA, EComplex mixtures復(fù)雜混合物Coal tar煤焦油8007-45-265996-91-0O, RDistillation product, filler蒸餾產(chǎn)品,填充物C, EColophony (rosin (Applies to>1%松香 (應(yīng)用超過1%)8050-09-78052-1-0673138-82-6OOOAdhesives, paints, cutting fluids粘合
18、劑,涂料,切削液ACreosote木榴油8001-58-9O, RDistillation product, filler蒸餾產(chǎn)品,填充物C, EFlame retardants阻燃劑Brominated (not PBB + PBDE溴化物 (不包括PBB和PBDE)SeveralOTextiles, plastics織物,塑料E(probably有可能Triphenyl phosphate磷酸三苯脂115-86-6RAlso as antioxidant也用作抗氧化劑EHardeners硬化劑2,4-Toluene diisocyanate甲苯-2,4二異氰酸酯584-84-9OPUR f
19、oams, adhesivesPUR發(fā)泡劑,粘合劑A(asthma哮喘2,6-Toluene diisocyanate甲苯-2,6二異氰酸酯91-08-7OPUR foams, adhesivesPUR發(fā)泡劑,粘合劑A(asthma哮喘TGIC呔嗶克(異氰脲酸三縮水甘油酯)2451-62-9OPowder paints粉末涂料T (mutagen誘變劑HCFC compounds 4氫氯氟烴類化合物HCFC 141b二氯氟乙烷1717-00-6OCooling agent冷媒OHCFC 142b一氯二氟乙烷75-68-3OCooling agent冷媒OHCFC 22二氟氯甲烷75-45-6O
20、Cooling agent冷媒OMetals金屬Arsenic + compounds砷及砷的化合物SeveralO, Rwood preservative木材防腐N, C, ECadmium in batteries 5電池中的鎘SeveralO, RAccumulators蓄電池C, EChromium (6+ compound 6六價(jià)鉻化合物SeveralO, RSurface treatment表面處理A, C, ELead alloys 7鉛合金SeveralO, RAlloy合金N, ELead + compound 8鉛及其化合物SeveralO, RPigment in pai
21、nts涂料中的顏料N, ENickle 9鎳7440-02-0O, RSurface treatment表面處理AStrontium chromate鉻酸鍶7789-06-2O, RPingment顏料CZinc chromate鉻酸鋅13530-65-9-Pingment顏料CPlasticizers增塑劑Butyl benzyl phthalate鄰苯二甲酸丁芐酯85-68-7-Adhesives, paints粘合劑,涂料EDibutyl phthalate鄰苯二甲酸二丁酯84-74-2OAdhesives, paints粘合劑,涂料E, RDi (2-ethylhexylphthala
22、teDEHP鄰苯二甲酸二-(2-乙基已基)酯117-81-7RSealants, plastics密封劑,塑料RDi(methoxyethylphthalate鄰苯二甲酸二-(2-甲基乙基)酯117-82-8Radhesives, plastics粘合劑,塑料RDimethyl phthalate鄰苯二甲酸二甲酯131-11-3-Hardeners, paintsTSolvents溶劑Chloroform氯仿67-66-3RSolvent溶劑C, R1,2-Dichloroethane1,2-二氯乙烷107-06-2O, RAdditive for fuels燃油添加劑Cn-Hexane正已烷
23、110-54-3-Solvent溶劑NLimonene (Applies to> 1%檸檬油精(應(yīng)用超過1%)138-86-35989-27-5-OSolvent溶劑A, E2-Methoxy-1-propanol(Applies to > 0.5%2-甲基丙醇(應(yīng)用超過0.5%)1589-47-5-Solvent溶劑RTrichloroethylene三氯乙烯79-01-6-Solvent溶劑CSurface-active agents表面活性劑DHTDMAC61789-80-8OSoftener柔軟劑EDSDMAC雙十八烷基二甲基氯化銨107-64-2O, RRinsing a
24、gent 水處理凝絮劑EDTDMAC68783-78-8OVehicle care products車用保養(yǎng)產(chǎn)品1 CAS no.=Chemical Abstract Service registry number. Internationally applied scientific index identifying chemical substances.CAS no.=化學(xué)制品摘要服務(wù)登錄碼,簡(jiǎn)稱 CAS登錄碼 ,為國(guó)際通用的用來認(rèn)定化學(xué)物質(zhì)的科學(xué)編碼。2)A = Allergy, C = Cancer, T = Toxic, E = Environmen
25、tally hazardous, N = Neurotoxic, O = Ozone depletion, R = Reproductive hazards.A = 過敏 , C = 癌癥, T = 有毒, E = 危害環(huán)境, N = 毒害神經(jīng), O = 損耗臭氧層 , R=危害生物生殖功能3)Nitrite can form carcinogenic nitrosamines if amines are present.亞硝酸鹽如果和胺類物質(zhì)接觸有可能形成致癌的亞硝酸胺。4)HCFC used as blowing agent in foam plastics (PUR or as solv
26、ent is covered by the black list, STD 100-0002.HCFC used as cooling agent is covered by the grey list, STD 100-0003.當(dāng)HCFC用作泡沫塑料的發(fā)泡劑或溶劑時(shí),它被黑色清單覆蓋。當(dāng)HCFC用作冷卻介質(zhì)時(shí),它被灰色清單覆蓋。5)The use of cadmium in batteries is covered by the grey list, STD 100-0003, and other application by the black list, STD 100-0002,當(dāng)鎘
27、用在電池中時(shí),它被灰色清單覆蓋;鎘的其他應(yīng)用被黑色清單覆蓋。6)For each individual batch of surface treated parts, the mean value of free hexavalent chromium must not exceed 0.3µg/cm2 when tested in accordance with STD 5713,102.用Volvo標(biāo)準(zhǔn)STD 5713,102的方法測(cè)試,對(duì)每一批表面處理的零件,自由六價(jià)鉻含量的平均值不得超過0.3µg/cm2。7)Concentration limits in acco
28、rdance with the EU ELV directive are, for example, for steel 0.35%, for aluminum 0.4% and for copper 0.4%.鉛在合金中含量限制值與歐盟的ELV (End-of-life Vehicles指導(dǎo)一致。例如,在鋼中為0.35%,在鋁合金中為0.4%,在銅合金中為copper 0.4%。8)The grey lists general limit of 0.1 per cent by mass applies to metallic lead if the component is not exempted in Annex 2 of the EU
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