2024起動用鉛鋰蓄電池技術(shù)要求

范 符 觀 量 25℃常溫起動能力 0℃低溫起動能力 -18℃最大起動能力 電 觀 性 量 25℃常溫起動能力 0℃低溫起動能力 -18℃最大起動能力 志 裝 輸 存 附 A（資料性）《起動用鉛鋰蓄電池技術(shù)要求》團(tuán)體標(biāo)準(zhǔn)英文 本文件適用于額定電壓為12V的各種汽車、摩托車、拖拉機(jī)、摩托艇、工程車、船舶及其他內(nèi)燃機(jī)GB/T5008.1—20131GB/T5008.2—20132GB/T23638—2009IEC60095.1—2006起動用鉛酸蓄電池1QC/T1094—2018GB/T5008—2013、GB/T23638—2009、IEC60095—2006、QC/T1094—2018起動用鉛鋰蓄電池leadacid-Li-ionbatteryforstarting,lighting,and（Ah（AhIca5min（A（AI10：10（AC10/10。 性能（TZ），部分型號性能不確定可省略不寫； 圖

圖2圖3圖3（續(xù)表110hr外形尺寸（參考值 7.14、7.15試驗(yàn)時，不同容量的蓄電池對應(yīng)的25℃常溫起動電流、0℃低溫起動電流、-18℃最大起表210hr250-18 25 0按7.9試驗(yàn)時，放電5s時蓄電池端電壓應(yīng)不低于8.4V，放電30s時蓄電池端電壓應(yīng)不低于7.2V。 -18 按7.12試驗(yàn)時，存放60天的電池的015s 按7.15試驗(yàn)時，蓄電池的025s 10.5 3h內(nèi)蓄電池電壓變化不大于0.05V/h 蓄電池完全充電后，在溫度25±23I10（A）電流連續(xù)充電2h。檢查有無漏液，驗(yàn)中檢測蓄電池溫度變化，當(dāng)蓄電池溫度下降至比峰值低10 1h~5hI10（A）10.5V±0.05Vt（h）。????=??10×t[1?0.01(??? Ce——10小時率實(shí)際容量，單位為安時（Ah）；I10——10小時率放電電流，單位為安培（A）；t——放電持續(xù)時間，單位為小時（h）； 251h~5h25℃±25h2253s5s10 0℃5s30s -181h~5h18℃±1℃的低溫箱或低溫室20h1min218℃最大起動功率進(jìn)行恒功5s5s 25℃±5℃I05h。I0按式（2）0±120h~25h1min14.8V±0.1V5 25℃±260 25512h 25±214.8V±0.1V1h5I10（A）3036h14.8V±0.1V1h5I10（A）1h215s，測記蓄電池7.2.212h1h~5h15s”的驗(yàn)證；若進(jìn)行驗(yàn)證時的放電 25℃±524h，然后緊固到15N·m~25N·m。30Hz~35Hz29.4m/s22h0±120h1min20℃低溫起動電流進(jìn)行恒流放電至蓄電7.2Vt（s）。 表3---1125℃10℃113161316161 表425℃0-180-18 5~402mGuangdongEnergyResearchGuangdongEnergyResearch

附錄

TechnicalrequirementsofLeadacid-Li-ionBatteriesforStarting,Lighting,andIgnition2023-4-15 Normative Termsand Product Productmodel Batterydimensions Batterystructure Batterydimensions Appearance polarity Safetycharacteristics Capacity Startingabilityat25℃ Startingabilityat0℃ Maximumstartingabilityat-18℃ Chargingacceptance Chargeretention Electrolyteholdingability Cyclicdurability resistance Measuringinstrument BatteriesCharged Overalldimensionsandweight Appearance Polarity Safetytest Capacity Startingabilityat25℃ Startingabilityat0℃ Maximumstartingabilityat-18℃ Chargingacceptance Chargeretention Electrolyteholdingability Cyclicdurability resistance Inspection Inspectionclassification Samplingrules FactoryinspectionandRoutineinspection inspection Judgmentrules Marking,packaging,transportationand Marking Packaging Transportation Storage ThisdocumentisdraftedaccordingtoGB/T1.1—2020《GuidelinesforStandardizationPart1:StructureandDraftingRulesofStandardizationDocuments》.ThisdocumentisproposedbyGuangDongKaiJiePowerSupplyThisdocumentisissuedbyGuangdongEnergyResearchSocietyandisundercentralizedPleasenotethatthecontentsofthisdocumentmayinvolvepatents.Theissuingagencyofthisdocumentdoesnotassumetheresponsibilityofidentifyingthepatent.Documentdraftingunit：GuangDongKaiJiePowerSupplyCo.,Ltd,GuangZhouKaiJiePowerIndustrialCo.,Ltd,GuangzhouInstituteofEnergyConversion,CAS,GuangZhouMinTongTradingCo.,Ltd,GuangDongAssociationofCircularEconomyandResourcesComprehensiveUtilization.Documentdrafter:RonghuaChen,RuiyuanChen,DexiWang,JianxunSun,KaijunDong,WeimingLuo,HaifengGuan,ZhenhuaShao,DongjiWu,XiaotangSu,SihuiZeng.TechnicalrequirementsofLeadacid-Li-ionBatteriesforStarting,Lighting,andIgnitionThisdocumentspecifiesthetechnicalrequirements,testmethods,inspectionrules,marking,packaging,transportation,andstorageofLeadacid-Li-ionbatteriesforSLI(starting,lighting,andignition).Thisdocumentisapplicabletoleadacid-Li-ionbatteriesforSLIofvariousautomobiles,motorcycles,tractors,motorboats,engineeringvehicles,ships,andotherinternalcombustionengineswitharatedvoltageof12V.NormativeThefollowingdocumentsarereferredtointhetextinsuchawaythatsomeoralloftheircontentconstituterequirementsofthisdocument.Fordatedreferences,onlythedatedversionsapplytothisdocument.Forundatedreferences,thelatestversion(includingallamendments)appliestothisdocument.GB/T5008.1—2013LeadacidstartingbatteriesPart1TechnicalconditionsandtestGB/T5008.2—2013LeadacidstartingbatteriesPart2Productspecifications,terminaldimensions,andGB/T23638—2009LeadacidbatteriesforIEC60095.1—2006LeadacidstartingbatteriesPart1GeneralrequirementsandtestmethodsQC/T1094—2018GeneralTechnicalConditionsforLithium-IonBatteriesforMotorcycleTermsandThetermsanddefinitionsgiveninGB/T5008—2013,GB/T23638—2009,IEC60095—2006,QC/T1094—2018andthefollowingapplytothisdocument.Leadacid-Li-ionbatteryforstarting,lighting,andLeadacid-Li-ionbatteryisacombinationofoneormorelead-acidbatterymonomersconnectedwithoneormorelithium-ionbatterymonomers,whichisthepowersupplyforstarting,ignition,andlightingofautomobiles,motorcycles,tractors,motorboats,engineeringvehicles,ships,andotherinternalcombustionengines.ThefollowingsymbolsapplytothisCe:Actualcapacityat10hourdischargerate,unit:ampere-hoursC10:Ratedcapacityat10hourdischargerate,unit:ampere-hoursIca:Chargecurrentofchargingacceptancetestwhenchargingfor5min,unit:ampereI0:Dischargecurrentofchargingacceptancetest,unit:ampere(A),value:Ce/10.I10:Dischargecurrentat10hourdischargerate,unit:ampere(A),value:C10/10.Product ProductProductmodelconsistsoffiveparts,theschematicdiagramofproductmodelisshowninFigure——ThefirstpartisthecodeforsealedLeadacid-Li-ionbatteries(representedby——Thesecondpartisthecodeforperformanceofbattery,includinggeneralperformance(representedby"T"),high-performance(representedby"TX"or"TR"),andultra-high-performance(representedby"TZ"),somemodelswithuncertainperformancecanbeomitted;——ThethirdpartisthecodeforcapacityofcorrespondingLeadacidbattery(representedby——Thefourthpartisthecodefordifferentoveralldimensionsofbatterieswiththesamecapacity(representedbyA,B,C...),whenthereisonlyoneexternaldimensionforthesamecapacity,thispartcanbeomitted;——Thefifthpartisthecodeforterminalpolaritydirection,leftnegativeandrightpositive(representedby"L"or"3"),leftpositiveandrightnegative(representedby"R"or"4")，thispartcanbeomitted. ThecodeforterminalpolaritydirectionThecodefordifferenceoveralldimensionsThecodeforcapacityofcorrespondinglead-acidThecodeforperformanceofThecodeforsealedLeadacid-Li-ionFigure1Schematicdiagramofproduct BatteryDimensionsofoverallstructureandexplanationofsymbolsareshowninFigure2andFigureUnit:Thesymbolsusedtodenotethevariousdimensionsareasl——LengthofLeadacid-Li-ionbattery;b——WidthofLeadacid-Li-ionbattery;h——HeightofLeadacid-Li-ionbattery;H——TotalheightofLeadacid-Li-ionbattery.Note:ThisfigureshowsLeadacid-Li-ionbatterywithfourFigure2Dimensionsofoverallstructure（FourUnit:Figure3Dimensionsofoverallstructure（TwoThesymbolsusedtodenotethevariousdimensionsareasl——LengthofLeadacid-Li-ionbattery;b——WidthofLeadacid-Li-ionbattery;h——HeightofLeadacid-Li-ionbattery;H——TotalheightofLeadacid-Li-ionbattery.Note:ThisfigureshowsLeadacid-Li-ionbatterywithtwoFigure3Dimensionsofoverallstructure（TwoProductmodelandthecorrespondingbatterydimensionsareshowninTableTable1ProductmodelandbatteryOverallNote:SpecialspecificationsandmodelscanbedeterminedbybothpartiesthroughTechnical BatteryThebatteryshallbecomposedofleadacidbatteryandLi-ionbatteryinparallel.Theleadacidbatteryiscomposedofbatteryslot,positivepole,negativepole,separator,electrolyte,batterycover,cover,andsafetyvalve.TheLi-ionbatteryiscomposedofpositivepole,negativepole,separator,electrolyte,aluminumplasticfilm,andcircuitprotectionplate.Thetwotypesofbatteriesareconnectedinparallelwithconnectorssuchascopperterminalsandwires. BatteryTheoveralldimensionsofthebatteryshallcomplywithTable1orbedeterminedthroughnegotiationbetweenthesupplierandthebuyer. Thesurfaceofthebatteryshallbeuniformincolor,freeofcracks,scratches,andobviousdeformation,withclearmarkings. Terminal SafetyOverchargeTestaccordingto7.6.1,thebatteryshallbefreeofleakageandShortcircuitTestaccordingto7.6.2,thebatteryshallbefreeoffireand Testaccordingto7.7,inthefirstthreetests,theactualcapacityCeshallnotbelowerthan95%oftheratedcapacityC10atleastonce,whichisconsideredqualified.Testaccordingto7.8,7.9,7.10,7.14,7.15,batterycapacity,startingcurrentat25℃,startingcurrentat0℃,maximumstartingpowerat-18℃,andcyclicstartingcurrentareshowninTable2.Table2TestParametersofStartingcurrentat25℃currentat0℃Maximumstartingpowerat-18℃CyclicstartingNote:Specialperformanceindicatorscanbedeterminedbybothpartiesthrough Startingabilityat25Testaccordingto7.8，attheendofthelastdischarge,theterminalvoltageshallnotbelowerthan7.2V,theappearanceshallbefreeofdeformationandliquidleakage. Startingabilityat0Testaccordingto7.8，theterminalvoltageshallnotbelowerthan8.4Vwhendischargingfor5s,thebatteryterminalvoltageshallnotbelowerthan7.2Vwhendischargingfor30s.Thebatteryterminalvoltageshallmeetthespecifiedrequirementsduringthefirstthreetests. Maximumstartingabilityat-18Testaccordingto7.10,whendischargingfor5s,theterminalvoltageshallnotbelowerthan6V.Thebatteryterminalvoltageshallmeetthespecifiedrequirementsduringthefirstthreetests. ChargingTestaccordingto7.11,theratioofchargingcurrentIcatoI0shallnotbelessthan ChargeTestaccordingto7.12,thestartingdischargetimeat0℃ofthebatterystoredfor60daysshallnotbelessthan15s. ElectrolyteholdingTestaccordingto7.13，thereshallbenoelectrolyteleakageonthebattery CyclicTestaccordingto7.14，thebatteryshallbeabletowithstandatleast10cycledurabilitytest VibrationTestaccordingto7.15，thestartingdischargetimeat0℃ofthebatteryshallnotbelessthan25Test MeasuringThemeasuringrangeoftheinstrumentusedshallchangewiththemeasuredvoltageorcurrentvalue,andthereadingofthepointerinstrumentshallbewithinthelastthirdofthemeasuringrange.TheaccuracyofthevoltmeterusedforvoltagemeasurementshallnotbelowerthanclassTheaccuracyoftheammeterusedformeasuringcurrentshallnotbelowerthanclassThethermometerformeasuringtemperatureshallhaveanappropriaterange,itsdivisionvalueshallnotbegreaterthan1℃,andthecalibrationaccuracyshallnotbelessthan0.5℃.Theinstrumentformeasuringtimeshallbedividedbyhour,minuteandsecond,andshallhaveanaccuracyofatleast±1%.Thegraduationvalueofthemeasuringtoolformeasuringtheoveralldimensionsofthebatteryshallnotbegreaterthan1mm.Thedensitometerusedtomeasurethedensityofelectrolyteshallhaveanappropriaterange,andeachgraduationvalueshallnotbegreaterthan0.005g/cm3.Theweighinginstrumentforweighingthebatteryshallhaveanaccuracyofmorethan±Theinstrumentformeasuringpressureshallbeapressuregaugewithanaccuracyofnotlessthan BatteriesThebatteryischargedto14.8V±0.1VwithI10(A),andthencontinuetochargewith0.5I10(A).Whenthebatteryvoltagefluctuationislessthan0.05V/hfor3hconsecutively,thebatteryisfullcharge.Thebatteryischargedwithconstant-voltageof14.8V±0.1Vandlimitary-currentofI10(A).Whenthecurrentstabilizeswithin0.2I10(A)for3h,thebatteryisfullcharge. OveralldimensionsandUsemeasuringtoolsandweighingapparatustomeasuretheoveralldimensionsandweightofthe Visuallyinspecttheappearanceofthe Checkthepolarityofthestoragebatterywithavoltmeteroran SafetyAfterthebatteryisfullycharged,itshallbecontinuouslychargedwith3I10(A)for2hat25℃±2℃.Checkwhetherthereisliquidleakageandwhethertheappearanceisnormal.ShortcircuitAfterthebatteryisfullycharged,underthetemperatureof25℃±2℃,thepositiveandnegativepolesareshort-circuitedwithawirewithresistancenotexceeding100mΩ,checkingthetemperaturechangeofthebattery.Thetemperaturedropsto10℃belowthepeak,testcompleted.Duringthetest,thebatteryshallbefreefromfireandexplosion. Duringthetest,thebatteryareallintheenvironmentof20℃-3010.5V±0.05V,andrecordthedischargedurationtCeiscalculatedaccordingtoFormula????=??10×t[1?0.01(??? IntheCe—Actualcapacityat10hourdischargerate,unit:ampere-hoursI10—Dischargecurrentat10hourdischargerate,unit:amperet—Dischargeduration,unit:hourT—Testambienttemperature,unit:Afterthetest,thestoragebatteryshallbechargedtothefullychargedstate Startingabilityat25Within1hto5hafterthebatteryisfullycharged,keepitinanaturalenvironmentwithatemperatureof25℃±2℃for5h，thendischargeinthedischargemodeof“constant-currentdischargefor3s,stopfor5s，continuouscyclefor10times”withstartingcurrentat25℃inTable2,andmeasuretheterminalvoltageattheendofdischarge.Afterthetest,thebatteryshallbefullychargedafteritrecoverstotheambient Startingabilityat0Within1hto5hafterthebatteryisfullycharged,putthebatteryintoalow-temperatureboxorroomwithatemperatureof0℃±1℃foratleast20h.Within1minafterthebatteryistakenoutoflow-temperatureboxorroom,constantcurrentdischargewithstartingcurrentat0℃inTable2for30s,andmeasuretheterminalvoltageat5sand30s.Afterthetest,thebatteryshallbefullychargedafteritrecoverstotheambient Maximumstartingabilityat-18Within1hto5hafterthebatteryisfullycharged,putthebatteryintoalow-temperatureboxorroomwithatemperatureof-18℃±1℃foratleast20h.Within1minafterthebatteryistakenoutoflow-temperatureboxorroom,constant-powerdischargewithmaximumstartingpowerat-18℃inTable2for5s,andmeasuretheterminalvoltageat5s.Afterthetest,thebatteryshallbefullychargedafteritrecoverstotheambient ChargingThefullychargedbatteryisdischargedwithI10(A)for5hat25℃±5℃.I0iscalculatedaccordingtoformula(2):IntheI0—Dischargecurrentofchargingacceptancetest,unit:ampereCe—Actualcapacityat10hourdischargerate,unit:ampere-hoursAfterdischarge,immediatelyputthebatteryintoalow-temperatureboxorroomwithatemperatureof0℃±1℃for20h-25h.Within1minafterthebatteryistakenoutoflow-temperatureboxorroom,chargewithconstant-voltageof14.8V±0.1V,andmeasureIca(A)whenchargingfor5min.CalculatetheratioofchargingcurrentIcato ChargeWipethefullychargedbatterysurface,opencircuitstandingfor60daysinanaturalenvironmentwithatemperatureof25℃±2℃.Thenstartingabilityat0℃ofthebatteryshallbetestedaccordingto7.9withoutsupplementarycharge,recorddischargetime(s)whentheterminalvoltagedropsto7.2V. ElectrolyteholdingAfterthebatteryisfullycharged,immediatelywipethebatterysurfacedry,andthenplaceitupsidedownonapieceofblottingpaperat25℃±5℃for12h.Visuallyobservewhethertherearetracesofelectrolyteontheblotting CyclicDuringthetest,thebatteryareallintheenvironmentof25℃±2Thefullychargedbatteryshallbedischargedinthedischargemodeof“constant-currentdischargefor3s,stopfor5s,continuouscyclefor10times”withcyclicstartingcurrentinTable2,andthenchargewithconstant-voltageof14.8V±0.1Vfor1h.Themaximumcurrentshallnotexceed5I10(A).Soastoformacycle.Afterthebatteryhasbeencycledfor30consecutivetimes,opencircuitstandingfor36days,thenchargewithconstant-voltageof14.8V±0.1Vfor1h,themaximumcurrentshallnotexceed5I10(A),standfor1hafterrecharging,thenconstant-currentdischargewithcyclicstartingcurrentinTable2for15s,measuretheterminalvoltageattheendofdischarge.Theaboveoperationsconstitutethetestofacycledurabilitytestunit.Whenthebatteryisconstant-currentdischargedfor15s,iftheterminalvoltageisnotlowerthan7.2Vattheendofdischarge,itshallbeacycledurabilitytestunit，thenfullychargethebatteryaccordingtotheconstant-voltagecurrent-limitingchargingmethodin7.2.2，after12hoffullcharging,conductthetestofthenextcycledurabilitytestunitaccording7.14.2.Iftheterminalvoltageislowerthan7.2Vattheendofdischarge,theverificationof“constant-currentdischarge15s”shallbeconductedwithin1h-5hafterthebatteryisfullychargedaccordingtotheconstant-voltagecurrent-limitingchargingmethodin7.2.2.Duringtheverificationof"constant-currentdischargefor15s"，iftheterminalvoltageisnotlowerthan7.2Vattheendofdischarge,itshallbeacycledurabilitytestunit，thenfullychargethebatteryaccordingtotheconstant-voltagecurrent-limitingchargingmethodin7.2.2，after12hoffullcharging,conductthetestofthenextcycledurabilitytestunitaccording7.14.2.Iftheterminalvoltageisstilllowerthan7.2Vwhenperformingvalidation,thecyclelifetestisended,andthiscycleunitisnotincludedinthenumberofcycledurabilitytestunits.Afterthetest,calculatethetotalnumberofqualifiedcycledurabilitytestunitsofthe VibrationAfterfullychargingthebatterythathaspassedthecapacitytest,storeitinanenvironmentwithatemperatureof25℃±5℃for24h,thenfastenittothevibrationtestbench.Useaspecialfour-frameclamptopressevenlyontheupperedgeofthebattery.Fourcornersarefixedevenlyonthevibrationtablethroughbolts.Tightentheboltstoatorqueof15N·m-25N·m.Thestoragebatteryshallwithstandaverticalvibrationwithafrequencyof30Hz-35Hzandanaccelerationof29.4m/s2for2h.Afterthevibrationtest,putthestoragebatteryintoalow-temperatureroomorboxwithatemperatureof0℃±1℃foratleast20hwithoutsupplementarycharging.Within1minafterremovalfromroomorbox,dischargeatconstantcurrentwithstartingcurrentat0℃inTable2untilthebatteryterminalvoltageis7.2V，recordthedischargetime（s）.Inspection InspectionTheinspectionincludesFactoryinspection,Routineinspections,andType SamplingRepresentativeproductscanbeselectedfortype FactoryinspectionandRoutineFactoryinspectionitemsandRoutineinspectionitemsmustbeinspectedfordeliveredproducts.InspectionitemsandinspectionsamplequantityareshowninTable3.Table3FactoryInspectionandRoutineInspectionTestBattery--Table3FactoryInspectionandRoutineInspectionInspectionTest-Safety1forOnceaOnceaStartingabilityat25OnceaStartingabilityat0OnceaMaximumstartingat-18OnceaCharging1forOnceeverythreeChargeOnceeverysixElectrolyteholdingOnceeverythreeCyclicOnceeverysixVibrationOnceeverysix TypeIncaseofanyofthefollowingcircumstances,samplingshallbecarriedoutfortypeinspection,andthetypeinspectionmustbethequalifiedproducts.TrialproducednewTheproductstructure,processformula,orrawmaterialsarePeriodicsamplinginspectionofproductsproducedinThetestofgovernmentTypeinspectionitemsandalltestTypeinspectionitemsandalltestproceduresareshowninTableT