獸藥殘留監(jiān)控計(jì)劃 附件4 殘留限量標(biāo)準(zhǔn)

附件4,,,,

2019年度動(dòng)物及動(dòng)物產(chǎn)品獸藥殘留檢測(cè)方法及殘留限量,,,,

化合物Compound,動(dòng)物/組織Species/Matrix,"推薦檢測(cè)方法

RecommendedMethods","檢測(cè)限(或定量限)

DetectionorQuantificationLimit

(μg/kgorμg/L）",殘留限量MRL（μg/kg）

氟喹諾酮類Fluoroquinolones,雞/蛋Chichen/Egg,液相色譜質(zhì)譜法LC-MS-MS（GB/T21312-2007)高效液相色譜法HPLC（781號(hào)公告-6-2006）,環(huán)丙沙星Ciprofloxacin10,不得檢出ND

,,,恩諾沙星Enrofloxacin10,

,,,洛美沙星Lomefloxacin0.5,

,,,氧氟沙星Ofloxacin0.5,

,,,諾氟沙星Norfloxacin1.0,

,,,培氟沙星Pefloxacin1.0,

,,,噁喹酸Oxolinicacid0.5,50

磺胺喹噁啉Sulfaquinoxaline,雞/蛋Chichen/Egg,高效液相色譜法HPLC（1025號(hào)公告-15-2008）,磺胺喹噁啉Sulfaquinoxaline20,不得檢出ND

,,,,,

金剛烷胺Amantadine,雞/蛋Chichen/Egg,動(dòng)物性食品中金剛烷胺殘留量的測(cè)定液相色譜-串聯(lián)質(zhì)譜法（見附錄1）,金剛烷胺Amantadine1,不得檢出ND

,,,,,

氯羥吡啶Clopidol,雞/蛋Chichen/Egg,高效液相色譜法HPLC（GB/T20362-2006),氯羥吡啶Clopidol20,不得檢出ND

,,,,,

四環(huán)素類Tetracyclines,雞/蛋Chichen/Egg,動(dòng)物性食品中四環(huán)素類藥物殘留量的測(cè)定液相色譜法（見附錄2）,四環(huán)素tetracycline20,200

,,,土霉素Oxytetracycline20,

,,,金霉素Chlortetracycline20,

,,,多西環(huán)素Doxycycline20,不得檢出ND

磺胺類Sulphonamides,雞/肝Chicken/Liver,高效液相色譜法HPLC（農(nóng)牧發(fā)[2001]38號(hào)）高效液相色譜法HPLC（GB29694-2013）液相色譜質(zhì)譜法LC-MS-MS（1025號(hào)公告-23-2008）,磺胺二甲基嘧啶Sulfamethazine0.5-20,100

,,,磺胺間二甲氧嘧啶Sulfadimethoxine0.5-20,

,,,磺胺嘧啶Sulfadiazine0.5-20,

,,,磺胺喹噁啉Sulfaquinoxaline0.5-20,

磺胺類Sulphonamides,雞/肝Chicken/Liver,高效液相色譜法HPLC（農(nóng)牧發(fā)[2001]38號(hào)）高效液相色譜法HPLC（GB29694-2013）液相色譜質(zhì)譜法LC-MS-MS（1025號(hào)公告-23-2008）,磺胺間甲氧嘧啶Sulfamonomethoxine0.5-20,100

,,,磺胺甲氧嗪Sulfamethoxypyridazine0.5-20,

,,,磺胺甲噁唑Sulfamethoxazole0.5-20,

,,,磺胺醋酰Sulfacetamide0.5-12,

,,,磺胺吡啶Sulfapyridine0.5-12,

,,,磺胺甲基嘧啶Sulfamerazine0.5-12,

,,,磺胺噁唑Sulfamoxol0.5-12,

,,,磺胺異噁唑Sulfisoxazole0.5-12,

,,,苯甲酰磺胺Sulfabenzamide0.5-12,

,,,磺胺氯噠嗪Sulfachloropyridazine0.5-12,

,,,磺胺苯吡唑Sulfaphenazole0.5-12,

,,,磺胺甲噻二唑Sulfamethizole0.5,

,,,磺胺鄰二甲氧嘧啶Sulfadoxine0.5,

,,,磺胺噻唑sulfathiazole0.5,

硝基咪唑類Nitiomidazoles,雞/肝Chicken/Liver,動(dòng)物源食品中甲硝唑、地美硝唑及其代謝物殘留檢測(cè)液相色譜-串聯(lián)質(zhì)譜法（見附錄3）,甲硝唑Metronidazole0.5,不得檢出ND

,,,羥基甲硝唑Metronidazole-OH0.5,

,,,地美硝唑Dimetridazole0.5,

,,,羥基地美硝唑Dimetridazole-OH0.5,

地克珠利Diclazuril,雞/肉Chicken/Muscle,高效液相色譜法HPLC（GB29701-2013）,地克珠利Diclazuril50,500

,,,,,

氟苯尼考及其代謝物FlorfenicolanditsMetabolites,雞/肉Chicken/Muscle,動(dòng)物性食品中氟苯尼考及其代謝物多殘留的測(cè)定液相色譜-串聯(lián)質(zhì)譜法（見附錄4）,氟苯尼考胺Florfenicolamine3,100

,,,,,

,,,,,

氟喹諾酮類Fluoroquinolones,雞/肉Chichen/Muscle,高效液相色譜法HPLC（1025號(hào)公告-14-2008）,達(dá)氟沙星Danofloxacin20,200

,,,恩諾沙星Enrofloxacin20,100

,,,環(huán)丙沙星Ciprofloxacin20,

磺胺類Sulphonamides,雞/肉Chichen/Muscle,高效液相色譜法HPLC（農(nóng)牧發(fā)[2001]38號(hào)）高效液相色譜法HPLC（GB29694-2013）液相色譜質(zhì)譜法LC-MS-MS（1025號(hào)公告-23-2008）,磺胺二甲基嘧啶Sulfamethazine0.5-20,100

,,,磺胺間二甲氧嘧啶Sulfadimethoxine0.5-20,

,,,磺胺嘧啶Sulfadiazine0.5-20,

,,,磺胺喹噁啉Sulfaquinoxaline0.5-20,

,,,磺胺間甲氧嘧啶Sulfamonomethoxine0.5-20,100

,,,磺胺甲氧嗪Sulfamethoxypyridazine0.5-20,

,,,磺胺甲噁唑Sulfamethoxazole0.5-20,

,,,磺胺醋酰Sulfacetamide0.5-5,

,,,磺胺吡啶Sulfapyridine0.5-5,

,,,磺胺甲基嘧啶Sulfamerazine0.5-5,

,,,磺胺噁唑Sulfamoxol0.5-5,

,,,磺胺異噁唑Sulfisoxazole0.5-5,

,,,苯甲?；前稴ulfabenzamide0.5-5,

,,,磺胺氯噠嗪Sulfachloropyridazine0.5-5,

,,,磺胺苯吡唑Sulfaphenazole0.5-5,

,,,磺胺甲噻二唑Sulfamethizole0.5,

,,,磺胺鄰二甲氧嘧啶Sulfadoxine0.5,

,,,磺胺噻唑Sulfathiazole0.5,

金剛烷胺Amantadine,雞/肉Chicken/Muscle,動(dòng)物性食品中金剛烷胺殘留量的測(cè)定液相色譜-串聯(lián)質(zhì)譜法（見附錄1）,金剛烷胺Amantadine1,不得檢出ND

,,,,,

氯霉素Chloramphenicol,雞/肉Chicken/Muscle,氣相色譜法GC（1025號(hào)公告-21-2008）氣相色譜質(zhì)譜法GC-MS（781號(hào)公告-1-2006）液相色譜質(zhì)譜法HPLC-MS-MS（781號(hào)公告-2-2006）,氯霉素Chloramphenicol0.3,不得檢出ND

,,,,,

,,,,,

尼卡巴嗪殘留標(biāo)示物MarkerResiduesofNicarbazin,雞/肉Chicken/Muscle,高效液相色譜法HPLC(GB29691-2013)液相色譜質(zhì)譜法HPLC-MS-MS(GB29690-2013,二硝基苯脲DNC20,200

,,,,,

四環(huán)素類Tetracyclines,雞/肉Chicken/Muscle,液相色譜質(zhì)譜法LC-MS-MS（1025號(hào)公告-12-2008）,四環(huán)素tetracycline5,100

,,,土霉素Oxytetracycline5,

,,,金霉素Chlortetracycline5,

泰樂菌素Tylosin,雞/肉Chichen/Muscle,高效液相色譜法HPLC（958號(hào)公告-5-2007）,泰樂菌素Tylosin20,200

,,,,,

替米考星Tilmicosin,雞/肉Chicken/Muscle,高效液相色譜法HPLC（1025號(hào)公告-10-2008）,替米考星Tilmicosin10,75

,,,,,

硝基呋喃類代謝物NitrofuranMetabolites（AOZ、AMOZ、AHD、SEM）,雞/肉Chicken/Muscle,液相色譜質(zhì)譜法LC-MS-MS（781號(hào)公告-4-2006）,氨基唑烷酮AOZ0.25,不得檢出ND

,,,甲基嗎啉氨基唑烷酮AMOZ0.25,

,,,氨基乙內(nèi)酰脲AHD0.25,

,,,氨基脲SEM0.25,

β-內(nèi)酰胺類β-lactams,牛/奶Cow/Milk,動(dòng)物性食品中β-內(nèi)酰胺類藥物多殘留檢測(cè)超高效液相色譜-串聯(lián)質(zhì)譜法（見附錄5）,青霉素GBenzylpenicillin：1,4

,,,阿莫西林Amoxicillin：1,10

,,,氨芐西林Ampicillin：1,10

,,,苯唑西林Oxacillin：1,30

,,,氯唑西林Cloxacillin：1,30

,,,頭孢喹肟Cefquinome：1,20

,,,頭孢氨芐Cefalexin：1,100

阿維菌素類Avermectins,牛/奶Cow/Milk,高效液相色譜法HPLC（GB29696-2013）,阿維菌素Abamectin：1,"不得檢出

ND"

,,,多拉菌素Doramectin：1,

,,,伊維菌素Ivermectin：1,10

氟喹諾酮類Fluoroquinolones,牛/奶Cow/Milk,液相色譜質(zhì)譜法LC-MS-MS（GB/T21312-2007)高效液相色譜法HPLC（GB29692-2013）,恩諾沙星Enrofloxacin：25,100

,,,環(huán)丙沙星Ciprofloxacin：25,

,,,達(dá)氟沙星Danofloxacin：7.5,30

,,,氟甲喹Flumequine：12.5,50

,,,洛美沙星Lomefloxacin0.5,不得檢出ND

,,,氧氟沙星Ofloxacin0.5,

,,,諾氟沙星Norfloxacin1.0,

,,,培氟沙星Pefloxacin1.0,

磺胺類Sulphonamides,牛/奶Cow/Milk,液相色譜質(zhì)譜法LC-MS-MS（781號(hào)公告-12-2006）,磺胺二甲嘧啶Sulfadimidine0.2,100

,,,磺胺嘧啶Sulfadiazine2.0,

,,,磺胺吡啶Sulfapyridine2.0,

,,,磺胺甲基嘧啶Sulfamerazine2.0,

,,,磺胺二甲異嘧啶Sulfisomidine1.0,

,,,磺胺甲氧嘧啶Sulfameter3.0,

,,,磺胺甲基異噁唑Sulfamethoxazole4.0,

,,,磺胺異噁唑Sulfisoxazole5.0,

,,,磺胺二甲氧基嘧啶Sulfadimethoxine2.0,

四環(huán)素類Tetracyclines,牛/奶Cow/Milk,牛奶中四環(huán)素類藥物殘留檢測(cè)超高效液相色譜-串聯(lián)質(zhì)譜法（見附錄6）,四環(huán)素tetracycline5,100

,,,土霉素Oxytetracycline5,

,,,金霉素Chlortetracycline5,

,,,多西環(huán)素Doxycycline5,不得檢出ND

阿苯達(dá)唑及其主要代謝物AlbendazoleanditsmainMetabolites,牛/肉Cattle/Muscle,高效液相色譜法HPLC（958號(hào)公告-9-2007）,阿苯達(dá)唑Albendazole5,100

,,,阿苯達(dá)唑砜Albendazolesulfone5,

,,,阿苯達(dá)唑亞砜Albendazolesulfoxide5,

阿維菌素類Avermectins,牛/肉Cattle/Muscle,高效液相色譜法HPLC（1025號(hào)公告-5-2008）,多拉菌素Doramectin:1.5,10

,,,伊維菌素Ivermectin:1.5,10

克侖特羅Clenbuterol,牛/肉Cattle/Muscle,氣相色譜質(zhì)譜法GC-MS（958號(hào)公告-8-2007）,克侖特羅Clenbuterol0.5,不得檢出ND

,,,,,

同化激素AnabolicSexHormones,牛/肉Cattle/Muscle,液相色譜質(zhì)譜法LC-MS-MS（1031號(hào)公告-1-2008）,司坦唑醇Stanozolol0.3,不得檢出ND

,,,甲基睪酮Methyltestosterone0.3,

,,,群勃龍Trenbolone0.4,

,,,丙酸睪酮Testosteronepropinate0.4,

,,,苯丙酸諾龍NadrolonePhenylpropionate0.4,

頭孢噻呋Ceftiofur,牛/肉Cattle/Muscle,高效液相色譜法HPLC（1025號(hào)公告-13-2008）,頭孢噻呋Ceftiofur100(定量限),1000

,,,,,

磺胺類Sulphonamides,羊/肉Ovine/Muscle,液相色譜質(zhì)譜法HPLC-MS-MS(GB/T20759-2006),磺胺醋酰Sulfacetamide5.0,100

,,,磺胺甲噻二唑Sulfamethizole2.5,

,,,磺胺二甲異噁唑Sulfisoxazole5.0,

,,,磺胺氯噠嗪Sulfachloropyridazine5.0,

,,,磺胺嘧啶Sulfadiazine5.0,

,,,磺胺甲基異噁唑Sulfamethoxazole5.0,

,,,磺胺噻唑sulfathiazole10,

,,,磺胺-6-甲氧嘧啶Sulfamonomethoxine5.0,

,,,磺胺甲基嘧啶Sulfamerazine5.0,

,,,磺胺鄰二甲氧嘧啶Sulfadoxine5.0,

,,,磺胺吡啶Sulfapyridine5.0,

,,,磺胺對(duì)甲氧嘧啶Sulfameter20,

,,,磺胺甲氧噠嗪Sulfamethoxypyridazine10,

,,,磺胺二甲基嘧啶Sulfamethazine20,

,,,磺胺苯吡唑Sulfaphenazole40,

,,,磺胺間二甲氧嘧啶Sulfadimethoxine10,

克侖特羅Clenbuterol,羊/肉Ovine/Muscle,氣相色譜質(zhì)譜法GC-MS；高效液相色譜法HPLC（GB/T5009.192-2003）,克侖特羅Clenbuterol0.5,不得檢出ND

,,,,,

卡巴氧和喹乙醇?xì)埩魳?biāo)示物MarkerResiduesofCarbadoxandOlaquindox,豬/肝Pig/Liver,高效液相色譜法HPLC（781號(hào)公告-3-2006）液相色譜質(zhì)譜法HPLC-MS-MS(GB-T20746-2006）,喹噁啉-2-羧酸QCA10(定量限）,"不得檢出

ND"

,,,3-甲基喹噁啉-2-羧酸MQCA10（定量限）,50

,,,,,

硝基咪唑類Nitiomidazoles,豬/肉Pig/Muscle,動(dòng)物源食品中甲硝唑、地美硝唑及其代謝物殘留檢測(cè)液相色譜-串聯(lián)質(zhì)譜法（見附錄3）,甲硝唑Metronidazole0.5,不得檢出ND

,,,羥基甲硝唑Metronidazole-OH0.5,

,,,地美硝唑Dimetridazole0.5,

,,,羥基地美硝唑Dimetridazole-OH0.5,

地塞米松Dexamethasone,豬/肉Pig/Muscle,液相色譜質(zhì)譜法LC-MS-MS（1031號(hào)公告-2-2008）液相色譜質(zhì)譜法LC-MS-MS（GB-T21981-2008）,地塞米松Dexamethasone0.5（定量限）,0.75

,,,,,

氟苯尼考及其代謝物FlorfenicolanditsMetabolites,豬/肉Pig/Muscle,動(dòng)物性食品中氟苯尼考及其代謝物多殘留測(cè)定液相色譜-串聯(lián)質(zhì)譜法（見附錄4）,氟苯尼考胺Florfenicolamine3,300

,,,,,

,,,,,

氟喹諾酮類Fluoroquinolones,豬/肉Pig/Muscle,液相色譜質(zhì)譜法LC-MS-MS（GB/T21312-2007)高效液相色譜法HPLC（1025號(hào)公告-14-2008）,達(dá)氟沙星Danofloxacin20,100

,Pig/Muscle,,恩諾沙星Enrofloxacin20,100

,,,環(huán)丙沙星Ciprofloxacin20,

,,,洛美沙星Lomefloxacin1.0,"不得檢出

ND"

,,,氧氟沙星Ofloxacin1.0,

,,,諾氟沙星Norfloxacin2.0,

,,,培氟沙星Pefloxacin2.0,

,,,噁喹酸Oxolinicacid1.0,100

,,,氟甲喹Flumequine1.0,500

磺胺類Sulphonamides,豬/肉Pig/Muscle,高效液相色譜法HPLC（GB29694-2013）液相色譜質(zhì)譜法LC-MS-MS（1025號(hào)公告-23-2008）,磺胺二甲基嘧啶Sulfamethazine0.5-5,100

,,,磺胺間二甲氧嘧啶Sulfadimethoxine0.5-5,

,,,磺胺間甲氧嘧啶Sulfamonomethoxine0.5-5,

,,,磺胺甲氧嗪Sulfamethoxypyridazine0.5-5,

,,,磺胺甲噁唑Sulfamethoxazole0.5-5,

,,,磺胺醋酰Sulfacetamide0.5-5,

,,,磺胺吡啶Sulfapyridine0.5-5,

,,,磺胺甲基嘧啶Sulfamerazine0.5-5,

,,,磺胺噁唑Sulfamoxol0.5-5,

,,,磺胺異噁唑Sulfisoxazole0.5-5,

,,,苯甲?；前稴ulfabenzamide0.5-5,100

,,,磺胺氯噠嗪Sulfachloropyridazine0.5-5,

,,,磺胺苯吡唑Sulfaphenazole0.5-5,

,,,磺胺嘧啶Sulfadiazine0.5,

,,,磺胺喹噁啉Sulfaquinoxaline0.5,

磺胺類Sulphonamides,豬/肉Pig/Muscle,高效液相色譜法HPLC（GB29694-2013）液相色譜質(zhì)譜法LC-MS-MS（1025號(hào)公告-23-2008）,磺胺甲噻二唑Sulfamethizole0.5,100

,,,磺胺鄰二甲氧嘧啶Sulfadoxine0.5,

,,,磺胺噻唑Sulfathiazole0.5,

金剛烷胺Amantadine,豬/肉Pig/Muscle,動(dòng)物性食品中金剛烷胺殘留量的測(cè)定液相色譜-串聯(lián)質(zhì)譜法（見附錄1）,金剛烷胺Amantadine1,不得檢出ND

,,,,,

四環(huán)素類Tetracyclines,豬/肉Pig/Muscle,液相色譜質(zhì)譜法LC-MS-MS（1025號(hào)公告-12-2008）,四環(huán)素tetracycline5,100

,,,土霉素Oxytetracycline5,

,,,金霉素Chlortetracycline5,

"四環(huán)素類、磺胺類和氟喹諾酮類Tetracyclines,SulphonamidesandFluoroquinolones",豬/肉Pig/Muscle,動(dòng)物性食品中四環(huán)素類、磺胺類和氟喹諾酮類藥物多殘留的測(cè)定液相色譜-串聯(lián)質(zhì)譜法（見附錄7）,四環(huán)素tetracycline2,100

,,,土霉素Oxytetracycline2,

,,,金霉素Chlortetracycline2,

,,,多西環(huán)素Doxycycline2,100

,,,乙?；前稴ulfacetamide2,100

,,,磺胺吡啶Sulfapyridine2,

,,,