主要學(xué)術(shù)思想和學(xué)術(shù)成績(jī)

主要學(xué)術(shù)思想和學(xué)術(shù)成績(jī)催化劑是催化反應(yīng)工藝技術(shù)的核心。催化反應(yīng)是一個(gè)表/界面過(guò)程，但在反應(yīng)器宏尺度下往往受限于催化劑床層內(nèi)的流動(dòng)與傳遞過(guò)程的制約，導(dǎo)致催化劑活性和選擇性甚至催化劑穩(wěn)定性受到負(fù)面影響。結(jié)構(gòu)催化劑與反應(yīng)器技術(shù)（StructuredCatalystsandReactors,SCRs）已被廣泛證實(shí)能顯著優(yōu)化固體催化劑床層的流體力學(xué)行為和提高催化劑床層內(nèi)部的熱/質(zhì)傳遞性能，因而在多相催化領(lǐng)域的研究受到越來(lái)越多的關(guān)注，成為當(dāng)前催化與反應(yīng)工程交叉領(lǐng)域的熱點(diǎn)和國(guó)際前沿。然而，目前多數(shù)研究主要限于涂層技術(shù)的規(guī)則2D空隙蜂窩陶瓷和微通道SCR的研究。雖然相關(guān)SCR技術(shù)已普遍用于汽車(chē)尾氣催化凈化，也在蒽醌加氫、費(fèi)-托合成、氣相丙烯雙氧水環(huán)氧化等過(guò)程中實(shí)現(xiàn)了工業(yè)應(yīng)用示范，但是涂層技術(shù)成本高、實(shí)施難度大、對(duì)金屬Foam等新型非規(guī)則結(jié)構(gòu)基體的技術(shù)普適性差。要強(qiáng)調(diào)的是，具有三維（3D）非規(guī)則空隙結(jié)構(gòu)的Foam/Fiber基體，在消除徑向擴(kuò)散限制、強(qiáng)化渦流混合傳質(zhì)、規(guī)?；苽涞确矫骘@示出微通道難以企及的優(yōu)勢(shì)，但高效的Foam/Fiber基體3D骨架表面催化功能化的研究尚屬空白。我們提出了金屬Foam/Fiber基體“非涂層”原位催化功能化的“自上而下（Top-Down）”逆向設(shè)計(jì)策略，原創(chuàng)性地構(gòu)建了濕式化學(xué)刻蝕、原電池反應(yīng)置換活化、分子篩原位生長(zhǎng)、介孔Al2O3同源氧化衍生等的結(jié)構(gòu)催化劑制備新方法和新技術(shù)，突破了“涂層技術(shù)”通適性差的局限性，將結(jié)構(gòu)催化劑從規(guī)則2D空隙蜂窩和微通道結(jié)構(gòu)拓展到了非規(guī)則3D空隙金屬Foam/Fiber等結(jié)構(gòu)，形成了特色鮮明的反應(yīng)器（Top，流動(dòng)與傳遞）-催化劑（Down，表界面反應(yīng)）高效耦合一體化設(shè)計(jì)新方向，實(shí)現(xiàn)了反應(yīng)器（Top）內(nèi)流動(dòng)和熱/質(zhì)傳遞與表界面（Down）催化反應(yīng)的協(xié)同耦合，進(jìn)而可提高催化劑的利用效率、提升穩(wěn)態(tài)反應(yīng)速率和選擇性、減緩催化劑失活，尤其為眾多C1能源化工反應(yīng)過(guò)程存在的傳質(zhì)/傳熱限制等問(wèn)題的解決以及為滿(mǎn)足環(huán)境催化（VOC催化燃燒）和“模塊”化工廠等對(duì)高通量、低壓降等的特殊要求提供了新的技術(shù)途徑。在煤/生物質(zhì)基合成天然氣（SNG）、甲醇制丙烯（MTP）、DMO加氫合成EG、VOCs/CH4催化燃燒、氣相醇選擇氧化、甲烷干重整、催化精餾等多個(gè)過(guò)程的應(yīng)用中得到有力驗(yàn)證。例如，借助原電池置換反應(yīng)一步實(shí)現(xiàn)了整裝式Au(Ag)/Ni(Cu)-fiber催化劑制備，用于強(qiáng)放熱氣相醇氧化實(shí)現(xiàn)了低溫高活性與強(qiáng)化傳熱的統(tǒng)一；揭示了Au/Ni-fiber上Ni2O3-Au+活性位結(jié)構(gòu)以其協(xié)同作用關(guān)系。研制了纖維結(jié)構(gòu)化Ni/CeAlO3-Al2O3復(fù)合催化劑，用于強(qiáng)吸熱CH4/CO2重整實(shí)現(xiàn)了熱力學(xué)（高導(dǎo)熱消除冷點(diǎn)）和動(dòng)力學(xué)兩方面抑制積碳的統(tǒng)一；揭示了CeAlO3的動(dòng)力學(xué)抑制積碳的本質(zhì)。無(wú)需對(duì)ZSM-5分子篩進(jìn)行任何化學(xué)修飾和晶粒尺寸控制，僅對(duì)其進(jìn)行微結(jié)構(gòu)化設(shè)計(jì)合成了整裝Metal-fiber@ZSM-5核殼結(jié)構(gòu)催化劑，即大幅提高了ZSM-5分子篩在MTP反應(yīng)過(guò)程中的穩(wěn)定性和丙烯選擇性；本質(zhì)上，ZSM-5分子篩的結(jié)構(gòu)化設(shè)計(jì)促進(jìn)了MTH過(guò)程“碳烴池”機(jī)理中烯烴循環(huán)路徑同時(shí)明顯抑制了芳烴循環(huán)路徑。借助一步濕法化學(xué)刻蝕方法，開(kāi)發(fā)了傳熱效率高、催化性能好的整裝結(jié)構(gòu)化Ni-foam@Ni-MOx(MOx:Al,Ce,Mg等的一元或多元混合氧化物)甲烷化催化劑，實(shí)現(xiàn)了優(yōu)異的甲烷化催化性能與良好導(dǎo)熱性的統(tǒng)一，為發(fā)展無(wú)循環(huán)、高通量、快速移熱結(jié)構(gòu)化甲烷化合成天然氣（SNG）催化反應(yīng)器工藝提供了核心技術(shù)基礎(chǔ)；與世界500強(qiáng)的香港中華煤氣集團(tuán)合作，成功實(shí)現(xiàn)了整裝結(jié)構(gòu)甲烷化催化劑的工業(yè)試制，基于該催化劑的無(wú)循環(huán)一次性通過(guò)SNG新工藝技術(shù)的工業(yè)化應(yīng)用也在實(shí)施中。最近，遵循“逆向設(shè)計(jì)（Top-Down）”的研發(fā)思路，通過(guò)一步原電池置換法、可控氧化外延生長(zhǎng)法和同源生長(zhǎng)等方法，分別設(shè)計(jì)研制了低溫活性高、選擇性好、穩(wěn)定性好和可大通量低壓降操作、床層幾何構(gòu)型靈活設(shè)計(jì)的系列專(zhuān)利催化劑，如：煤層氣催化脫氧Ni-Foam@NiPd(alloy,<1%Pd)催化劑、DMO加氫制乙二醇Ni-foam@NiM-alloy催化劑、Ni-foam@NiO-NbOx乙烷氧化脫氫制乙烯催化劑、CO與亞硝酸甲酯反應(yīng)合成DMO/DMC低Pd（<0.3wt%）Pd/AlOOH/Al-matrix催化劑、Pd@SiO2/Al2O3/Al-matrix(<0.5%Pd)甲烷/VOCs催化燃燒脫除催化劑等。主持國(guó)家自然科學(xué)基金委‘十五’“能源發(fā)展中的若干關(guān)鍵科學(xué)問(wèn)題”重大項(xiàng)目課題1項(xiàng)（20590366）、國(guó)家基金委面上項(xiàng)目6項(xiàng)（20573036，20973063，21076083，21273075，21473057，21773069）、科技部“973”項(xiàng)目課題1項(xiàng)（2011CB201403）、科技部“863”“氫能源”專(zhuān)項(xiàng)課題1項(xiàng)（2007AA05Z101）、教育部“高等院校博士點(diǎn)專(zhuān)項(xiàng)基金”（20090076110006）項(xiàng)目1項(xiàng)、上海市科委重大項(xiàng)目子課題1項(xiàng)（05DJ14002）和重點(diǎn)基礎(chǔ)研究項(xiàng)目1項(xiàng)（18JC1412100），以及企業(yè)（香港中華煤氣集團(tuán)、上海浦景化工、中石化上海工程公司等）委托額合作開(kāi)發(fā)項(xiàng)目多項(xiàng)。發(fā)表論文200余篇，申請(qǐng)發(fā)明專(zhuān)利40余件（其中PCT專(zhuān)利3件），獲得中國(guó)發(fā)明專(zhuān)利授權(quán)30余件、美國(guó)專(zhuān)利授權(quán)2件。近年來(lái)，在Sci.Adv.、iScience、J.

Catal.、AIChE

J.、ACSCatal.、Chem.Commun.、Green

Chem.、ACSAppl.Mater.Interfaces、ChemSusChem、ACSSustainableChem.Eng.、Lab

Chip、J.Mater.Chem.、Int.J.HydrogenEnergy、J.

Power

Sources、Appl.

Catal.

A/B、Catal.

Today

、Nanoscale、Catal.Sci.Technol.等國(guó)內(nèi)外高水平學(xué)術(shù)刊物公開(kāi)發(fā)表論文100余篇。指導(dǎo)畢業(yè)的趙國(guó)鋒博士、陳偉碩士、高立達(dá)碩士和王翔宇碩士分別榮獲2016年度、2014年度和2011年度“上海市研究生優(yōu)秀成果”。技術(shù)合作開(kāi)發(fā)與轉(zhuǎn)化進(jìn)展情況2013年以來(lái)，與世界500強(qiáng)的香港中華煤氣集團(tuán)合作，大力開(kāi)展基于微結(jié)構(gòu)化設(shè)計(jì)的C1能源與化工關(guān)鍵催化劑技術(shù)的研究開(kāi)發(fā)。合成氣甲烷化技術(shù)可用以消除煤炭在一次性能源利用中的嚴(yán)重污染問(wèn)題、實(shí)現(xiàn)煤炭清潔利用，同時(shí)也是生物質(zhì)能源化利用的可行途徑。該反應(yīng)是一個(gè)強(qiáng)放熱過(guò)程，不僅反應(yīng)熱效應(yīng)十分強(qiáng)烈而且現(xiàn)有催化劑存在明顯傳質(zhì)限制，如何實(shí)現(xiàn)催化劑催化性能與強(qiáng)化傳質(zhì)/傳熱的統(tǒng)一，實(shí)現(xiàn)低能耗、低投資無(wú)循環(huán)的一次性通過(guò)反應(yīng)工藝操作，還面臨巨大的挑戰(zhàn)。以具有強(qiáng)化熱/質(zhì)傳遞和優(yōu)化流體結(jié)構(gòu)功能的孔結(jié)構(gòu)工程化的金屬Ni-Foam為基體，合理利用結(jié)構(gòu)金屬基體自身的化學(xué)活潑性特點(diǎn)，發(fā)展了一步濕法化學(xué)刻蝕制備自支撐Ni-Al2O3催化劑的新方法，開(kāi)發(fā)了傳熱效率高、催化性能好的結(jié)構(gòu)化Ni-Al2O3/Ni-foam甲烷化催化劑并成功工業(yè)化制備，實(shí)現(xiàn)了優(yōu)異的甲烷化催化性能與良好導(dǎo)熱性的統(tǒng)一，為發(fā)展無(wú)循環(huán)、高通量、快速移熱結(jié)構(gòu)化甲烷化合成天然氣（SNG）催化反應(yīng)器工藝提供了核心技術(shù)。目前，編制完成了首套生物質(zhì)基合成氣無(wú)循環(huán)甲烷化工藝包，已具備商業(yè)化實(shí)施條件。另外，遵循“逆向設(shè)計(jì)（Top-Down）”的催化劑-反應(yīng)器一體化設(shè)計(jì)的研發(fā)思路，還研發(fā)了草酸二酯加氫酯制乙二醇或乙醇酸酯結(jié)構(gòu)化催化劑、甲烷二氧化碳干氣重整結(jié)構(gòu)化催化劑以及SS-fiber@ZSM-5核殼結(jié)構(gòu)MTP催化劑和甲烷氧化偶聯(lián)催化劑。其中，草酸二酯加氫結(jié)構(gòu)化催化劑200mL裝量的放大穩(wěn)定性測(cè)試中，已完成連續(xù)穩(wěn)定運(yùn)行2500小時(shí)的穩(wěn)定性測(cè)試，已具有應(yīng)用轉(zhuǎn)化的良好前景；在與港華煤氣前期合作研究的基礎(chǔ)上，甲烷干氣重整結(jié)構(gòu)催化劑的放大試制和單管中試測(cè)試工作也大力推進(jìn)中。通過(guò)技術(shù)轉(zhuǎn)讓給香港中華煤氣集團(tuán)的CO與亞硝酸甲酯反應(yīng)合成DMO/DMC低Pd（<0.3wt%）Pd/AlOOH/Al-matrix專(zhuān)利催化劑的中試試驗(yàn)也在順利開(kāi)展中。最近，我們以Mn2O3-Na2WO4/SiO2為基礎(chǔ)催化劑，基于MnTiO3輔助[Mn3+?Mn2+]低溫循環(huán)活化O2驅(qū)動(dòng)低溫OCM的科學(xué)認(rèn)識(shí)，形成了具有知識(shí)產(chǎn)權(quán)的低溫OCM催化劑。相關(guān)成果《TiO2摻雜Mn2O3-Na2WO4/SiO2催化劑上MnTiO3驅(qū)動(dòng)低溫甲烷氧化偶聯(lián)制烯烴》于2017年6月9日發(fā)表于國(guó)際著名學(xué)術(shù)出版集團(tuán)Science旗下2015年新創(chuàng)子刊《ScienceAdvances》（2017,e1603180）。目前已申請(qǐng)3項(xiàng)發(fā)明專(zhuān)利（CN

104759291;WO

2015101345;201710146190.1）。在此基礎(chǔ)上，正在與中石化上海工程公司合作開(kāi)展低溫OCM熱模試驗(yàn)，通過(guò)進(jìn)行創(chuàng)新催化劑的百公斤級(jí)試制，實(shí)現(xiàn)滿(mǎn)足新催化劑反應(yīng)工藝要求的反應(yīng)器工程化設(shè)計(jì)，完成基于創(chuàng)新催化劑和反應(yīng)工藝條件下的安全工藝流程優(yōu)化，來(lái)達(dá)到具備開(kāi)展全過(guò)程中試試驗(yàn)所需的技術(shù)基礎(chǔ)。發(fā)表著作路勇，鞏金龍等編著.《結(jié)構(gòu)催化劑與反應(yīng)器》.

化學(xué)工業(yè)出版社.

2020.GuofengZhao,YeLiu,and

YongLu*.Fromnano-tomacro-engineeringofnanocompositesandapplicationsinheterogeneouscatalysis.

In:AdvancesinNanostructuredComposites.Vol.2:ApplicationsofNanocoposites.

M.Aliofkhazraei(ed.).

CRCPress,Taylor&FrancisGroup,2017,Chapter5.路勇，趙國(guó)鋒.

結(jié)構(gòu)催化劑與反應(yīng)器：新結(jié)構(gòu)、新策略和新進(jìn)展.

《催化反應(yīng)工程》，閻子峰，陳誦英等主編.

科學(xué)出版社.2017.

第7章.朱吉?dú)J，路勇.規(guī)整結(jié)構(gòu)催化劑及反應(yīng)器.《化工過(guò)程強(qiáng)化方法與技術(shù)》，劉有智等編著.

化學(xué)工業(yè)出版社.

2017.

第24章.代表性論文2020JianZhu,WeidongSun,SongWang,GuofengZhao,YeLiu,YongLu*.ANi-foam-structuredMoNi4-MoOxnanocompositecatalystforhydrogenationofdimethyloxalatetoethanol.Chem.Commun.,2020,56,806-809.SongWang,GuofengZhao,YeLiu,andYongLu*.High-PerformancePd@ZnO-CuO/Brass-FiberCatalystforSelectiveHydrogenationofAcetylene:EffectofCalcination-AssistedEndogenousGrowthofZnO-CuOCompositeonBrass-fiber.J.Catal.,2020,382,295-304.GuofengZhao,XiaxiaPan,YeLiu,andYongLu*.Thin-feltPd-MgO-Al2O3/Al-FiberCatalystwithHighResistancetoWater-VaporPoisoningforCatalyticCombustionofMethane.J.Catal.,2020,384,122-135.JianZhu,GuofengZhao*,WeidongSun,SongWang,YeLiu,andYongLu*.Gas-phasehydrogenationofdimethyloxalatetoethanol:SuperiorFeNi3-FeOx/Ni-foamcatalystderivedfromNiFe2O4-NiO/Ni-foam.Appl.Catal.B,2020,118873.JiaDing,ZhiqiangZhang,ChaoMeng,GuofengZhao,*YeLiu,andYongLu*.Fromnano-tomacro-engineeringofZSM-11ontothin-feltstainless-steel-fiber:Steam-assistedcrystallizationsynthesisandmethanol-to-propyleneperformance.Catal.Today,2020,347,10-17.2019JiaDing,YingshuaiJia,PengjingChen,GuofengZhao,*YeLiu,andYongLu*.Thin-felthollow-B-ZSM-5/SS-fibercatalystformethanol-to-propylenereaction:Towardremarkablestabilityimprovementfromdiffusionenhancement.Chem.Eng.J.,2019,361,588-598.Longgang,Tao,GuofengZhao,*PengjingChen,ZhiqiangZhang,YeLiu,YongLu*.High-performanceCo-MnOxcompositeoxidecatalyststructuredontoAl-fiberfeltforhigh-throughputO3decomposition.ChemCatChem,2019,11,1131-1142.PengjingChen,LongangTao,JianZhu,GuofengZhao,*YeLiu,andYongLu*.Morphology-controllablehexagonal-phaseindiumoxideinsitustructuredontoathin-feltAl2O3/Al-fiberforhydrogenationofCO2tomethanol.EnergyTechnol.,2019,7,1800747/1-1800747/10.PengjingChen,GuofengZhao*,XuerongShi*,JianZhu,JiaDing,YongLu*.Nano-intermetallicInNi3C0.5compounddiscoveredasasuperiorcatalystforCO2reutilization.iScience,2019,17,315-324.YingshuaiJia,ChunzhengWang,JiaDing,GuofengZhao,YeLiu,andYongLu*.Carbon-decorated-Pd(Pd@C)nanocatalystsstructuredonAl-fiberthinfeltforcarbonylationofmethylnitritetoDMC.Catal.Commun.,2019,126,1-4.ChunzhengWang,YingshuaiJia,ZhiqiangZhang,GuofengZhao*,YeLiu,andYongLu*.RoleofPdCxspeciesinPd@PdCx/AlOOH/Al-fibercatalystfortheCOoxidativecouplingtodimethyloxalate.Appl.Surf.Sci.,2019,478,840-845.LonggangTao,ZhiqiangZhang,PengjingChen,GuofengZhao*,YeLiu,andYongLu*.Thin-feltAl-fiber-structuredPd-Co-MnOx/Al2O3catalystwithhighmoistureresistanceforhigh-throughputO3decomposition.Appl.Surf.Sci.,2019,481,802-810.ZhiqiangZhang,GuofengZhao*,WeidongSun,YeLiu,andYongLu*.Oxidativedehydrogenationofethane:SuperiorNb2O5-NiO/Ni-foamcatalysttailoredbytuningmorphologyofNiO-precursorsgrownonaNi-foam.iScience,2019,20,90-99.GuofengZhao*,RuijuanChai,ZhiqiangZhang,WeidongSun,YeLiu,andYongLu*.High-performancemonolithicNi-CeAlO3/Al2O3/FeCrAl-fiberCatalystforCatalyticOxy-MethaneReformingtoSyngas.Fuel,2019,258,116102/1-11.SongWang,GuofengZhao,YeLiu,andYongLu*.High-PerformancePd/AlOOH/Al-fiber(ppmPd)forHemi-HydrogenationofAcetylene:PositiveEffectofHydroxyl-EnrichedCatalystSurface.Ind.Eng.Chem.Res.,2019,58,16431-16441.ZhiqiangZhang,GuofengZhao*,WeidongSun,YeLiu,andYongLu*.High-performanceNi-foam-structuredNb2O5-NiOcompositecatalystfortheoxidativedehydrogenationofethanetoethylene:EffectsofNb2O5loadingandcalcinationtemperature.Micropor.Mesopor.Mater.,2019,288,109609/1-9.JiaDing,LizhuoWang,ZhiqiangZhang,ShufangZhao,YongLu*,andJunHuang*Athin-feltmicrofibrous-structuredZSM-11/SS-fibercatalystfordehydrationofglyceroltoacrolein.ACSSustainableChem.Eng.,2019,7,16225-16232.JianZhu,GuofengZhao*,TongZhu,WeidongSun,YongLu*.Top-downevolutionaryengineeringofnanoporousNi3PontoaNi-foam:Asuperiorcatalystforgas-phasehydrogenationofdimethyloxalatetomethylglycolate.ACSAppl.Mater.Interfaces,2019,11,37635-37643.2018趙國(guó)鋒,張智強(qiáng),朱堅(jiān),柴瑞娟,丁嘉,劉曄,路勇.結(jié)構(gòu)催化劑與反應(yīng)器：新結(jié)構(gòu)、新策略和新進(jìn)展.化工進(jìn)展,2018，38(4):1287-1304.JiaDing,YingshuaiJia,PengjingChen,GuofengZhao,YeLiu,andYongLu*.Microfibrous-structuredhollow-ZSM-5/SS-fibercatalystwithmesoporositydevelopmentdependentlifetimeimprovementforMTPreaction.Micro.Meso.Mater.,261(2018)1-8.ZhiqiangZhang,JiaDing,RuijuanChai,GuofengZhao,YeLiu,andYongLu*.Oxidativedehydrogenationofethanetoethylene:ApromisingCeO2-ZrO2-modifiedNiO-Al2O3/Ni-foamcatalysts.Appl.Catal.A,550(2018)151-159.TaoDeng,YakunLi,GuofengZhao*,YeLiu,andYongLu*.Catalyticdistillationforesterificationofaceticacidwithethanol:developmentofnovelSS-fiber@HZSM-5catalyticpackingsandexperimentaloptimizationviaresponsesurfacemethodology.J.Chem.Technol.Biotechnol.,93(2018)827–841.JiaDing,PengjingChen,GuofengZhao*,YeLiu,andYongLu*High-performancethin-feltSS-fiber@HZSM-5catalystssynthesizedviaseed-assistedvaporphasetransportformethanol-to-propylenereaction:Effectsofcrystalsize,mesoporosityandaluminumuniformity.J.Catal.,360(2018)40-50.LonggangTao,GuofengZhao,*SongyuFan,PengjingChen,ZhiqiangZhang,YeLiu,andYongLu*.Thin-feltmicrofibrous-structuredAu-α-Fe2O3/ns-γ-Al2O3/Al-fibercatalystforhigh-throughputCOoxidation.Appl.Catal.A556(2018)180-190.PengjingChen,ChunzhengWang,LupengHan,GuofengZhao*,YeLiu,andYongLu*.MonolithicNi5Ga3/SiO2/Al2O3/Al-fibercatalystwithenhancedheattransferforCO2hydrogenationtomethanolatambientpressure.Appl.Catal.A562(2018)234-240.PengweiWang,XinZhang,GuofengZhao,*YeLiu,andYongLu*.Oxidativecouplingofmethane:MOx-modified(M:Ti,Mg,Ga,Zr)Mn2O3-Na2WO4/SiO2catalystsandMOx-modificationeffect.Chin.J.Catal.,2018,39,1395–1402.TaoDeng,GuofengZhao,*YeLiu,andYongLu*.Catalyticdistillationforone-stepcyclohexylacetateproductionandcyclohexene-cyclohexaneseparationviaesterificationofcyclohexenewithaceticacidovermicrofibrous-structuredNafion-SiO2/SS-fiberpackings.Chem.Eng.Process.:ProcessIntensification,2018,131,215-226.ZhiqiangZhang,GuofengZhao*,RuijuanChai,JianZhu,YeLiuandYongLu*.Low-temperature,highlyselective,highlystableNb2O5-NiO/Ni-foamcatalystfortheoxidativedehydrogenationofethane.Catal.Sci.Technol.,2018,8,4383-4389.2017PengweiWang,GuofengZhao*,YuWang,andYongLu*.MnTiO3-drivenlow-temperatureoxidativecouplingofmethaneoverTiO2-dopedMn2O3-Na2WO4/SiO2catalyst.Sci.Adv.2017,3:e1603180.GuofengZhao,SongyuFan,YeLiu,andYongLu*.Reaction-InducedSelf-AssemblyofCoO@Cu2ONanocompositesIn-SituontoSiC-FoamforGas-PhaseOxidationofBioethanoltoAcetaldehyde.ChemSusChem,10(2017)1380-1384.ChunzhengWang,PengjingChen,YakunLi,GuofengZhao,YeLiu,andYongLu*.Microfibrous-StructuredPd/AlOOH/Al-FiberforCOCouplingtoDimethylOxalate:EffectofMorphologyofAlOOHEndogenouslyGrownonAl-Fiber.ACSAppl.Mater.Interfaces,9(2017)9795-9804.JiaDing,PengjingChen,ZhiqiangZhang,LupengHan,GuofengZhao,YeLiu,andYongLu*.Microfibrous-structuredSS-fiber@meso-HZSM-5catalystformethanol-to-propylenereaction:Steam-assistedcrystallizationsynthesisandinsightintomesoporocity-dependentstabilityenhancement.ACSSustainableChem.Eng.,

5(2017)

1840-1853.RuijuanChai,SongyuFan,ZhiqiangZhang,PengjingChen,YakunLi,QiaofeiZhang,GuofengZhao,YeLiu,andYongLu*.Free-StandingNiO-MgO-Al2O3NanosheetsDerivedfromLayeredDoubleHydroxidesGrownontoFeCrAl-fiberasStructuredCatalystsforDryReformingofMethane.ACSSustainableChem.Eng.,5(2017)4517-4522.JiaDing,TaoDeng,PengjingChen,GuofengZhao,YeLiu,andYongLu*.Vapor-phasetransportsynthesisofmicrofibrous-structuredSS-fiber@ZSM-5catalystwithdramaticselectivityandstabilityimprovementformethanol-to-propylene.Catal.Sci.Technol.,7(2017)2087-2100.RuijuanChai,YakunLi,QiaofeiZhang,SongyuFan,ZhiqiangZhang,PengjingChen,GuofengZhao,YeLiu,andYongLu*.Foam-structuredNiO-MgO-Al2O3nanocompositesderivedfromNiMgAl-LDHsin-situgrownontoNi-foam:Apromisingcatalystforhigh-throughputcatalyticoxy-methanereforming.ChemCatChem,9(2017)268-272.PengweiWang,GuofengZhao*,YeLiu,andYongLu*.TiO2-dopedMn2O3-Na2WO4/SiO2catalystforoxidativecouplingofmethane:solutioncombustionsynthesisandMnTiO3-dependentlow-temperatureactivityimprovement.Appl.Catal.A,544(2017)77-83.ZhiqiangZhang,LupengHan,RuijuanChai,QiaofeiZhang,YakunLi,GuofengZhao,YeLiu,andYongLu*.MicrostructuredCeO2-NiO-Al2O3/Ni-foamcatalystforoxidativedehydrogenationofethanetoethylene.Catal.Commun.,88(2017)90-93.YanfeiChen,LupengHan,JianZhu,PengjingChen,GuofengZhao*,YeLiu,andYongLu*.Ag-CunanocompositecatalystgalvanicallydepositedontoaNi-foamforgas-phasedimethyloxalatehydrogenationtomethylglycolate.Catal.Commun.,96(2017)58-62.JiaDing,PengjingChen,JianZhu,GuofengZhao,YeLiu,andYongLu*.Synthesis

of

microfibrous-structured

SS-fiber@beta

composite

by

a

seed-assisteddry-gel

conversion

method.Micro.Meso.Mater.,250(2017)1-8.RuijuanChai,ZhiqiangZhang,PengjingChen,GuofengZhao*,YeLiu,andYongLu*.Ni-foam-structuredNiO-MOx-Al2O3(M=CeorMg)nanocompositecatalystforhighthroughputcatalyticpartialoxidationofmethanetosyngas.Micro.Meso.Mater.,253(2017)123-128.RuijuanChai,PengjingChen,ZhiqiangZhang,GuofengZhao,YeLiu,andYongLu*.Thin-feltNiO-Al2O3/FeCrAl-fibercatalystforhigh-throughputcatalyticoxy-methanereformingtosyngas.Catal.Commun.,101(2017)48-50.RuijuanChai,ZhiqiangZhang,PengjingChen,GuofengZhao*,YeLiu,andYongLu*.FromNano-toMacro-engineeringofLDHs-derivedNanosheetCatalystsforHarshReactions.Int.J.HydrogenEnergy,42(2017)27094-27099.RuijuanChai,GuofengZhao*,ZhiqiangZhang,PengjingChen,YeLiu,andYongLu*.HighSintering-/Coke-ResistanceNi@SiO2/Al2O3/FeCrAl-fiberCatalystforDryReformingofMethane:One-Step“MacrotoNano”O(jiān)rganizationviaCross-LinkingMolecules.Catal.Sci.Technol.,7(2017)5500-5504.2016GuofengZhao,YeLiu,andYongLu*.Foam/fiber-structuredcatalysts:Non-dip-coatingfabricationstrategyandapplicationsinheterogeneouscatalysis.Sci.Bull.,61(2016)745-748.ChunzhengWang,PengjingChen,YakunLi,GuofengZhao,YeLiu,andYongLu*.InsituDRIFTSstudyofCOcouplingtodimethyloxalateoverstructuredAl-fiber@ns-AlOOH@Pdcatalyst.J.Catal.,344(2016)173-183.LupengHan,GuofengZhao*,YanfeiChen,JianZhu,PengjingChen,YeLiu,andYongLu*.Cu-fiber-structuredLa2O3-PdAu(alloy)-Cunanocompositecatalystforgas-phasedimethyloxalatehydrogenationtoethyleneglycol.Catal.Sci.Technol.,6(2016)7024-7028.QiaofeiZhang,GuofengZhao,*ZhiqiangZhang,LupengHan,SongyuFan,RuijuanChai,YeLiu,JunHuang,andYongLu*.Fromnano-tomacro-engineeringofoxide-encapsulated-nanoparticlesforharshreaction:One-steporganizationviacross-linkingmolecules.Chem.Commun.52(2016)11927-11930.QiaofeiZhang,Xin-PingWu,YakunLi,RuijuanChai,GuofengZhao*,ChunzhengWang,Xue-QingGong,*YeLiu,andYongLu*.High-performancePdNinano-alloycatalystin-situstructuredonNi-foamforcoalbedmethanedeoxygenation:ExperimentalandDFTstudies.ACSCatal.6(2016)6236?6245.JiaDing,ZhiqiangZhang,LupengHan,ChunzhengWang,PengjingChen,GuofengZhao*,YeLiu,andYongLu*.Self-supportedSS-fiber@meso-HZSM-5core-shellcatalystviacaramel-assistantsynthesistowardprolongedlifetimeformethanol-to-propylenereaction.RSCAdv.,6(2016)48387-48395.TaoDeng,YakunLi,GuofengZhao*,YeLiuandYongLu*.Catalyticdistillationforethylacetatesynthesisusingmicrofibrous-structuredNafion-SiO2/SS-fibersolidacidpackings.React.Chem.Eng.,1(2016)409-417.ChunzhengWang,LupengHan,GuofengZhao,YeLiu,YongLu*.High-performance,lowPd-loadingmicrofibrous-structuredAl-fiber@ns-AlOOH@PdcatalystforCOcouplingtodimethyloxalate.J.Catal.,337(2016)145-156.QiaofeiZhang,YakunLi,RuijuanChai,GuofengZhao,*YeLiu,andYongLu*.Low-temperatureactive,highlyoscillation-resistantPdNi(alloy)/Ni-foamcatalystwithenhancedheattransferforcoalbedmethanedeoxygenationviacatalyticcombustion.Appl.Catal.B:Environ.,187(2016)148-158.GuofengZhao,SongyuFan,LonggangTao,RuijuanChai,QiaofeiZhang,YeLiu,andYongLu*.Microfibrous-structuredbinary-oxides-nanocompositewithboostedhighly-activeinterfaceforgas-phaseselectiveoxidationofalcohols.ChemCatChem,8(2016)

313-317.LupengHan,LiZhang,GuofengZhao,*QiaofeiZhang,RuijuanChai,YeLiuandYongLu*.Cu-fiber-structuredternaryPd-Au-CuOxcatalyst:Galvanicexchangereactionpreparationandcatalyticperformanceforgas-phasehydrogenationofdimethyloxalatetoethyleneglycol.ChemCatChem,8(2016)1065-1073.YakunLi,QiaofeiZhang,RuijuanChai,GuofengZhao,FahaiCao,YeLiu,andYongLu*.Metal-foam-structuredNi-Al2O3catalysts:Wetchemicaletchingpreparationandsyngasmethanationperformance.Appl.Catal.A,510(2016)216-226.MingWen,JiaDing,ChunzhengWang,YakunLi,GuofengZhao,YeLiu,andYongLu*.High-performanceSS-fiber@HZSM-5core-shellcatalystformethanol-to-propylene:Akineticandmodelingstudy.Micro.Meso.Mater.,221(2016)187-196.LupengHan,ChunzhengWang,GuofengZhao*,YeLiu,YongLu*.Thin-sheetmicrofibrous-structuredFeKMn/meso-Al2O3/Al-fibercatalystsforFischer-Tropschtoolefins.AIChEJ.,62(3)(2016)

742-752.RuijuanChai,YakunLi,QiaofeiZhang,GuofengZhao*,YeLiu,andYongLu*.Free-standingNiO-MgOnanosheetsin-situcontrollablycompositedonNi-foamasmonolithiccatalystforcatalyticoxy-methanereforming.Mater.Lett.,171(2016)248-251.LupengHan,ChunzhengWang,JiaDing,GuofengZhao*,YeLiu,andYongLu*.Microfibrous-structuredAl-fiber@ns-Al2O3core-shellcompositefunctionalizedbyFe-Mn-Kviasurfaceimpregnationcombustion:as-burntcatalystsforsynthesisoflightolefinsfromsyngas.RSCAdv.,6(2016)

9743-9752.2015QiaofeiZhang,Xin-PingWu,GuofengZhao,YakunLi,ChunzhengWang,YeLiu,Xue-QingGong,

YongLu*.High-performancePdNialloyin-situstructuredonmonolithicmetal-foamforcoalbedmethanedeoxygenationviacatalyticcombustion.Chem.Commun.,51(2015)12613-12616.GuofengZhao,XinpingWu,RuijuanChai,QiaofeiZhang,XueqingGong,JunHuang,YongLu*.Tailoringhighlyactiveandstablenano-catalysts:fromgold-nano-particlesonbulk-metal-oxidestoitsinversenano-metal-oxidesonlarge-gold-particles.Chem.Commun.,51(2015)5975.LiZhang,LupengHan,GuofengZhao,RuijuanChai,QiaofeiZhang,YeLiu,YongLu*.StructuredPd-Au/Cu-fibercatalystforgas-phasehydrogenolysisofdimethyloxalatetoethyleneglycol.Chem.Commun.,51(2015)10547-10549.ChunzhengWang,LupengHan,QiaofeiZhang,YakunLi,GuofengZhao,YeLiu,YongLu*.Endogenousgrowthof2DAlOOHnanosheetson3DAl-fibernetworkviasteam-onlyoxidation.GreenChem.,17(2015)3762-3765.YakunLi,QiaofeiZhang,RuijuanChai,GuofengZhao,FahaiCao,YeLiu,YongLu*.High-performanceNi-Ce-Al2O3/Ni-foamcatalystwithenhancedheattransferforsubstitutenaturalgasproductionviasyngasmethanation.ChemCatChem,7(2015)1427-1431.YakunLi,QiaofeiZhang,RuijuanChai,GuofengZhao,FahaiCao,YeLiu,YongLu*.CO2methanation:high-performancecatalystwithenhancedheattransferobtainedbymodifiedwetchemicaletchingofNi-foam.AIChEJ.,61(2015)4323–4331.MingWen,XiangyuWang,LupengHan,JiaDing,YingSun,YeLiu,YongLu*.Monolithicmetal-fiber@HZSM-5core-shellcatalystsformethanol-to-propylene.Micro.Meso.Mater.,206(2015)8-16.MingjueYu,Yi-AnZhu,YongLu,GangshengTong,KakeZhu,XingguiZhou.ThepromotingroleofAginNi-?CeO2catalyzedCH4-?CO2dryreformingreaction.Appl.Catal.B165(2015)43.JiaDing,LupengHan,MingWen,GuofengZhao,YeLiu,andYongLu*.Microfibrous-structuredAl-fiber@HZSM-5core-shellcatalystsformethanol-to-propylenereaction.Catal.Commun.,72(2015)156-160.RuijuanChai,YakunLi,QiaofeiZhang,GuofengZhao*,YeLiu,YongLu*.MonolithicNi-MOx/Ni-foam(M=Al,ZrorY)catalystswithenhancedheat/masstransferforenergy-efficientcatalyticoxy-methanereforming.Catal.Commun.,70(2015)1-5.JianJiang,ChaoYang,ZhongjiangLu,JiaDing,TaoLi,YongLu,FahaiCao.CharacterizationandapplicationofaPt?/ZSM-?5?/SSMFcatalystforhydrocrackingofparaffinwax.Catal.Commun.60

(2015)1.2014QiaofeiZhang,YakunLi,LiZhang,LiChen,YeLiu,YongLu*.Thin-sheetmicrofibrous-structurednanoporous-gold/Al-fibercatalystsforoxidativecouplingofmethanoltomethylformate.J.Catal.317(2014)54-61.XiangyuWang,MingWen,ChunzhengWang,JiaDing,YingSun,YeLiu,YongLu*.Microstructuredfiber@HZSM-5core-shellcatalystswithdramaticselectivityandstabilityimprovementforthemethanol-to-propyleneprocess.Chem.Commun.50(2014)6343-6345.QiaofeiZhang,YakunLi,LiZhang,LiChen,YeLiu,YongLu*.Structurednanoporous-gold/Al-fiber:galvanicdepositionpreparationandreactivityfortheoxidativecouplingofmethanoltomethylformate.GreenChem.16(2014)2992-2996.GuofengZhao,YakunLi,QiaofeiZhang,FahaiChao,YongLu*.Galvanticdepositionofsilveron80um-Cu-fiberforgas-phaseoxidationofalcohols.AIChEJ.60(2014)1045-1053.2013GuofengZhao,HuanyunHu,ZhengJiang,ShuoZhang,YongLu*.NiO-dopedAu/Ti-powder:Acatalystwithdramaticimprovementinactivityforgas-phaseoxidationofalcohols.Appl.Catal.A467(2013)171-177.GuofengZhao,MiaomiaoDeng,YifengJiang,HuanyunHu,JunHuang,YongLu*.MicrostructuredAu/Ni-fibercatalyst:Galvanicreactionpreparationandcatalyticperformanceforlow-temperaturegas-phasealcoholoxidation.J.Catal.301(2013)46-53.GuofengZhao,JunHuang,ZhengJiang,ShuoZhang,LiChen,YongLu*.MicrostructuredAu/Ni-fibercatalystforlow-temperaturegas-phasealcoholoxidation:EvidenceofNi2O3-Au+hybridactivesites.Appl.Catal.B:Environ.140-141(2013)249-257.WeiChen,GuofengZhao,QingsongXue,LiChen,YongLu*.Highcarbon-resistanceNi/CeAlO3-Al2O3catalystforCH4/CO2reforming.Appl.Catal.B:Environ.136-137(2013)260-268.GuofengZhao,HuanyunHu,WeiChen,ZhengJiang,ShuoZhang,JunHuang,YongLu*.Ni2O3-Au+hybridactivesitesonNiOx@Auensemblesforlow-temperaturegas-phaseoxidationofalcohols.Catal.Sci.Technol.3(2013)404-408.XinnanLu,GuofengZhao,YongLu*.PropyleneepoxidationwithO2andH2:ahighperformanceAu/TS-1catalystpreparedviaadeposition–precipitationmethodusingurea.Catal.Sci.Technol.3(2013)2906-2909.2012YuzhuFang,FangtingJiang,HongLiu,XiaomingWu,YongLu*.Standing-freeNi-microfibrous-supportedcarbonnanotubeaerogels(CNAGs)hybridelectrodesin3Dforhigh-performancesupercapacitors.RSCAdv.,2(2012)6562.WeiChen,WenqianSheng,GuofengZhao,FahaiCao,QingsongXue,LiChen,YongLu*.MicrofibrousentrapmentofNi/Al2O3fordryreformingofmethane:Ademonstrationonenhancementofcarbonresistanceandconversion.RSCAdv.2(2012)3651.WeiChen,WenqianSheng,FahaiCao,YongLu*.MicrofibrousentrapmentofNi/Al2O3fordryreformingofmethane:Heat/masstransferenhancementtowardscarbonresistanceandconversionpromotion.IntJHydrogenEnergy37(2012)18021-18030.YuanLi,YuzhuFang,HongLiu,XiaomingWu,YongLu*.Free-standing3Dpolyaniline-CNTs/Ni-fiberhybridelectrodesforhigh-performancesupercapacitors.Nanoscale4(2012)2867-2869.YinTang,G.Chen,YongLu.EfficientaldolcondensationbyusingmodifiedCaOassolid-basecatalysts.Res.Chem.Intermediates38(3-5)(2012)937.2011YinTang,M.Meng,J.\o"Showauthordetails"Zhang,YongLu.EfficientpreparationofbiodieselfromrapeseedoilovermodifiedCaO.Appl.Energy88(8)(2011)2735.GuofengZhao,HuanyunHu,MiaomiaoDeng,YongLu*.MicrostructuredAu/Ni-fibercatalystforlow-temperaturegas-phaseselectiveoxidationofalcohols.ChemCommun,47(2011)9642-9644.GuofengZhao,MinLing,HuanyunHu,MiaomiaoDeng,QingsongXue,YongLu*.AnexcellentAu/meso--Al2O3catalystforaerobicselectiveoxidationofalcohols.GreenChem3(2011)3088-3092.MinLin,GuofengZhao,WeiChen,MiaomiaoWang,QingsongXue,YongLu*.Microfibrous

structured

catalytic

packings

for

miniature

methanol

fuel

processor:

Methanol

steam

reforming

and

CO

preferential

oxidation.IntJHydrogenEnergy36(2011)12833-12842.GuofengZhao,HuanyunHu,MiaomiaoDeng,MinLing,YongLu*.Au/Cu-fibercatalystwithenhancedlow-temperatureactivityandheattransferforgas-phaseoxidationofalcohols.GreenChem13(2011)55-58.GuofengZhao,HuanyunHu,MiaomiaoDeng,MinLing,YongLu*.GalvanicdepositionofAuonpaper-likeCu-fiberforhigh-efficiencylow-temperaturegas-phaseoxidationofalcohols.ChemCatChem3(2011)1629-1636.2010MiaomiaoDeng?GuofengZhao?QingsongXue?LiChen?andYongLu*.Microfibrous-structuredsilvercatalystforlow-temperaturegas-phaseselectiveoxidationofbenzylalcohol.Appl.Catal.B99(2010)222-228.JipingMao?MiaomiaoDeng?LiChen?YeLiu?YongLu*.Novelmicrofibrous-strucutredsilvercatalystforhighefficiencygas-phaseoxidationofalcohols.AIChEJ.56(2010)1545-1556.JinZhang,Guofeng\o"Showauthordetails"Zhao,Z.Popovi?,YongLu,YeLiu.Pd-porphyrinfunctionalizedionicliquid-modifiedmesoporousSBA-15:Anefficientandrecyclablecatalystforsolvent-freeHeckreaction.MaterialsResearchBulletin45(11)(2010)1648.LuLiu,L.\o"Showauthordetails"Wei,YongLu,JunliangZhang.One-pottandemcatalysis:Aconciseroutetofusedbicyclicscaffoldsfromacyclicβ-ketoestersandalkynylaldehydes.Chem.-AEur.J.16(39)(1010)11813.YinTang,Li\o"Showauthordetails"Chen,Miaomiao\o"Showauthordetails"Wang,Jianfeng\o"Showauthordetails"Li,YongLu*.MicrofibrousentrappedZnO-CaO/Al2O3forhighefficiencyhydrogenproductionviamethanolsteamreforming.Particuology8(3)(2010)225.凌敏，趙國(guó)鋒，曹