化學(xué)品安全及安全技術(shù)說(shuō)明書(shū)

化學(xué)品安全及安全技術(shù)說(shuō)明書(shū)ChemicalSafety&MaterialSafetyDataSheet(MSDS)1法規(guī)要求Regulatoryrequirements化學(xué)品及其危害Introductionofchemicalsandthehazard安全標(biāo)志Safetysign運(yùn)輸標(biāo)簽Transportlabel化學(xué)品安全技術(shù)說(shuō)明書(shū)MaterialSafetyDataSheet(MSDS)化學(xué)品的安全使用、處置和運(yùn)輸Thesafetyofusage,disposalandtransportofchemicals培訓(xùn)內(nèi)容

Trainingschedule2通過(guò)此次培訓(xùn)，對(duì)一些法規(guī)要求及化學(xué)品的基本知識(shí)有所了解，并能夠閱讀化學(xué)品安全技術(shù)說(shuō)明書(shū)。Toincreasetheknowledgeoftheregulationrequirementsandthechemicals,becapabletoreadMSDSbythistraining.培訓(xùn)目的

Trainingobjective3我國(guó)的主要化學(xué)品管理法規(guī)及標(biāo)準(zhǔn)

MainregulationsandstandardsofchemicalsmanagementinChina中華人民共和國(guó)安全生產(chǎn)法SafeProductionLawofthePeople’sRepublicofChina危險(xiǎn)化學(xué)品安全管理?xiàng)l例RegulationoncontroloverDGchemicals工作場(chǎng)所安全使用化學(xué)品規(guī)定（170公約）Regulationonsafelyusingchemicalsinworkingarea（170pact）《常用危險(xiǎn)化學(xué)品的分類(lèi)及標(biāo)志》（GB13690-1992）Theclassificationandsignofdangerouschemicalsincommonuse《危險(xiǎn)貨物分類(lèi)和品名編號(hào)》（GB6944-2005）Theclassificationandnumberofdangerousgoods《危險(xiǎn)貨物品名表》（GB12268-1990）Thenamelistofdangerousgoods《化學(xué)品安全標(biāo)簽編寫(xiě)規(guī)定》（GB15258-1999）

Regulationonsafetylabel《化學(xué)品安全技術(shù)說(shuō)明書(shū)編寫(xiě)規(guī)定》（GB16483-2000）

RegulationonmakingMSDS國(guó)內(nèi)相關(guān)法規(guī)及標(biāo)準(zhǔn)

Relatedregulation4指各種化學(xué)元素、由元素組成的化合物及其混合物，無(wú)論是天然的或是人造的。Meansallkindsofchemicalelement,compoundswhichconstitutedwithelementandcompoundsmixture,whethernaturalormanmade.什么是化學(xué)品？Whatarechemicals?5固體：在室溫下以固態(tài)形式存在的物質(zhì)。如金屬，塑料Solids–thematerialsexistasasolidformunderthenormalroomtemperature.e.g.metals,plastics液體：在室溫下以液態(tài)形式存在的物質(zhì)。如稀釋劑Liquids–thematerialsexistasaliquidformunderthenormalroomtemperature.e.g.thinners氣體：在室溫下以氣態(tài)形式存在的物質(zhì)。如一氧化碳Gases–thematerialsexistasagasformunderthenormalroomtemperature.e.g.carbonmonoxide蒸氣：液體由于溫度、壓力的改變形成空氣中的微小液滴，正常狀態(tài)下為液體。Vapours–theliquidformstinyliquiddropsintheairbecauseofthechangeoftemperatureandpressure,itwillbeliquidinnormalcondition.e.g.solvents煙：固體由于溫度、壓力的改變形成空氣中的細(xì)小的固體顆粒。Smoke–thesolidformstinysolidparticleintheairbecauseofthechangeoftemperatureandpressure.塵：室溫下空氣中的細(xì)小固體顆粒。Dust–thetinysolidparticleintheairunderthenormalroomtemperature.存在形式

Existenceforms6化學(xué)品中具有易燃、易爆、有毒、有害及有腐蝕特性，會(huì)對(duì)人員、設(shè)施、環(huán)境造成傷害或損害的化學(xué)品屬危險(xiǎn)化學(xué)品。Thechemicalswhichhavethecharactersofflammability,explosive,toxic,harmfulandcorrosive,andwillcausehurtordamagetoperson,equipmentsandenvironmentaredangerouschemicals.危險(xiǎn)化學(xué)品(一)Hazardouschemicals7《常用危險(xiǎn)化學(xué)品的分類(lèi)及標(biāo)志》（GB13690-1992）

“Theclassificationandsignofdangerousgoodsincommonuse”第1類(lèi)：爆炸品

class1:explosive第2類(lèi)：壓縮氣體和液化氣體

class2:compressedgasandliquefiedgas第3類(lèi)：易燃液體

class3:flammableliquid第4類(lèi)：易燃固體、自燃物品和遇濕易燃物品

class4:flammablesolid,substanceliabletospontaneouscombustionandsubstancesflammablewhenwet第5類(lèi)：氧化劑和過(guò)氧化物

class5:oxidizingsubstancesandperoxide第6類(lèi)：有毒品

class6:toxic第7類(lèi)：放射性物品

class7:radioactivesubstance第8類(lèi)：腐蝕品

class8:corrosive危險(xiǎn)化學(xué)品(二)Hazardouschemicals8BYC所用到的危險(xiǎn)化學(xué)品

ExamplesinBYC產(chǎn)品：finishedproducts苯benzene甲苯toluene甲酸formicacid丙酸propionicacid一甲胺monomethylamine二甲胺dimethylamine三甲胺trimethylamine丙烯酸acrylicacid丙烯酸甲酯methylacrylate丙烯酸乙酯ethylacrylate丙烯酸丁酯butylacrylate……原料：rawmaterials硫酸sulfuricacid氫氧化鈉causticsoda氨（氨水、液氨）ammonia(ammoniawatersolution,ammonialiquid)……危險(xiǎn)化學(xué)品(三)Hazardouschemicals9一些化學(xué)品單獨(dú)儲(chǔ)存可能是安全的,但是如果和其他化學(xué)品接觸時(shí)會(huì)變成危險(xiǎn)品。Severalchemicalsareprobablysafewhenstorageseparately,howevertheywillbehazardouswhencontactwithotherchemicals.化學(xué)品的危害有：Thehazardofchemicalsare可燃flammable有毒toxic可爆explosive腐蝕caustic環(huán)境environmental……化學(xué)品的危害Thehazardofchemicals10你的肺部：如果你吸入煙,霧,灰塵

Yourlung:ifyouinhalesmoke,fuganddust你的皮膚：液體或粉料接觸或?yàn)R到皮膚上或眼睛里

Yourskin:contactliquidsorpowder,spilltoskinandeyes你的口：如果你接觸化學(xué)品后吃東西

Yourmouth:ifyoueatsomethingaftercontactingchemicals意外吞入：化學(xué)品

Swallowaccidentally:chemicals化學(xué)品進(jìn)入人體的途徑

Routesofentryintobody11使用化學(xué)品必須遵守的第一條規(guī)則是…“知道你在和什么化學(xué)品打交道,并且知道如何保護(hù)自己和別人”Thefirstruleofusingchemicalsmustbeobservedis:Youmustknowwhichchemicalsyouareworkingon,andhowtoprotectyourselfandothers?安全使用化學(xué)品？Howtousechemicalssafety?12安全標(biāo)志safetysign運(yùn)輸標(biāo)簽transportlabel化學(xué)品安全技術(shù)說(shuō)明書(shū)materialsafetydatasheet（MSDS)……如何得到相關(guān)信息？Wheretogetinformation?13《安全標(biāo)志》“safetysign”(GB2894-1996）《安全標(biāo)志使用導(dǎo)則》“theusageguidelineofsafetysigns”(GB16179-1996）

BYCPortal:01-010-00-0-0-00-021Safetysigns安全標(biāo)志在哪里？Wherearesafetysigns?公司/裝置的入口處theentranceofcompany/plant工作區(qū)域workingarea裝有化學(xué)品的管道、容器上thepipelineandcontainerwithchemicals……安全標(biāo)志

Safetysign14禁止標(biāo)志Prohibitionsign禁止堆放

Donotobstruct警告標(biāo)志W(wǎng)arningsign當(dāng)心腐蝕Caution,corrosion必須戴防護(hù)手套Mustwearprotectiveprotectiongloves強(qiáng)制性標(biāo)志Mandatorysign應(yīng)急信息標(biāo)志Emergencyinformationsign可動(dòng)火區(qū)Flareupregion安全標(biāo)志舉例

Examplesofsafetysign(1)15危險(xiǎn)化學(xué)品標(biāo)志Dangerouschemicalssign極其易燃性EXTREMELYFLAMMABLE極其易燃性Extremelyflammable擊碎板面

Breaktoobtainaccess消防安全標(biāo)志Firesafetysigns環(huán)保標(biāo)志Environmentprotectsigns廢氣排放口

Outletofwastegas當(dāng)心危險(xiǎn)固體廢物

Cautionhazardouswastesolid安全標(biāo)志舉例

Examplesofsafetysign(2)16禁止用水滅火Nowatertoputoutthefire禁止飲用Donotdrink禁止通行Authorizedpersonalonly禁止放易燃物Nolayinginflammablething禁止標(biāo)志

Prohibitionsign17當(dāng)心中毒Caution,toxichazard當(dāng)心火災(zāi)－易燃物質(zhì)Dangeroffire-Highlyflammablematerials

當(dāng)心爆炸－爆炸性物質(zhì)Dangerofexplosion-Explosivematerials當(dāng)心火災(zāi)－氧化物Dangeroffire-oxidizingmaterials警告標(biāo)志

Warningsign18必須戴安全帽和防護(hù)眼鏡Mustwearsafetyhelmetandprotectivegoggles必須戴護(hù)耳器Mustwearearprotector必須戴眼部和臉部防護(hù)用品Mustweareyeandfaceprotection必須加鎖Mustbelocked必須戴防毒面具M(jìn)ustweargasdefencemask強(qiáng)制性標(biāo)志

Mandatorysign19避險(xiǎn)處Haven可動(dòng)火區(qū)Flareupregion眼部清洗處Eyewashstation噴淋安全裝置Safetyshowerstation應(yīng)急信息標(biāo)志

Emergencyinformationsign20生物影響B(tài)IOHAZARDOUS對(duì)環(huán)境造成危險(xiǎn)DANGEROUSFORTHEENVIRONMENT有害HARMFUL刺激性IRRITANT腐蝕性CORROSIVE毒性TOXIC毒性很強(qiáng)VERYTOXIC放射性RADIOACHIC高度易燃性HIGHLYFLAMMABLE極其易燃性EXTREMELYFLAMMABLE氧化性O(shè)XIDIZING爆炸性EXPLOSIVES危險(xiǎn)化學(xué)品標(biāo)志

Dangerouschemicalssign21舉例Example22《化學(xué)品安全標(biāo)簽編寫(xiě)規(guī)定》(GB15258-1999）“Theregulationofmakingchemicalssafetylabel”(GB15258-1999）化學(xué)品安全標(biāo)簽包括物質(zhì)名稱(chēng)、危險(xiǎn)性標(biāo)志、編號(hào)、警示詞、危險(xiǎn)性概述、安全措施、滅火方法、生產(chǎn)廠(chǎng)家、地址、電話(huà)、應(yīng)急咨詢(xún)電話(huà)、提示參閱MSDS等內(nèi)容Thechemicalssafetylabelcontains:thenameofsubstance,hazardsign,number,alarmwords,hazardidentification,safetymeasures,fire-fightingmethod,productcompanyinformation(address,phonenumber,emergencyconsultationnumber),remindingofseeingMSDS……運(yùn)輸標(biāo)簽

Transportlabel23

揚(yáng)子巴斯夫化工有限責(zé)任公司BASF-YPCCompanyLimited

純度/

pure：

凈重/

weight：

批號(hào)/

batchNo.：N-butanol正丁醇C4H10O注

意Notice易燃、有毒、具刺激性Flammable,Harmful,Irritating

安全措施/SafetyMeasures防止與堿類(lèi)及堿化物料接近/Protectagainstalkaliesandalkalizingsubstances.防止靜電–遠(yuǎn)離火源-近處應(yīng)準(zhǔn)備滅火器/Preventelectrostaticcharge-sourcesofignitionshouldbekeptwellclear–fireextinguishersshouldbekepthandy.密閉包裝，并存于陰涼及干燥處/Keepcontainertightlyclosedinacool，dry.自燃濕度>300℃/Autoignitiontemperature>300℃.

滅火/FireFightingMeasure水噴霧,干滅火介質(zhì),耐醇性泡沫,二氧化碳/waterspray,dryextinguishingmedia,alcohol-resistantfoam,carbondioxide請(qǐng)向生產(chǎn)銷(xiāo)售企業(yè)索取安全技術(shù)說(shuō)明書(shū)PleaseaskforMSDSfrommanufactureordistributors揚(yáng)子巴斯夫化工有限責(zé)任公司CC出品ProductbyCCPLANT,BYCCo.Ltd郵編Zip-code：210048南京市六合區(qū)大廠(chǎng)鎮(zhèn)/DaChang,LuHe,Nanjingmunicipal電話(huà)Tel：025－×××××××UNNo.1120CNNo.33552應(yīng)急電話(huà)：Emergencycall24常用危險(xiǎn)化學(xué)品標(biāo)志-主標(biāo)志Mainsign25常用危險(xiǎn)化學(xué)品標(biāo)志-副標(biāo)志Subsidiarysign26《化學(xué)品安全技術(shù)說(shuō)明書(shū)編寫(xiě)規(guī)定》（GB16483-2000）“RegulationonmakingMSDS”

化學(xué)品使用者獲取有關(guān)化學(xué)品危害訊息和安全措施的來(lái)源Thesourceofhazardinformationandsafetyprecautionsofachemicalproductforusers化學(xué)品供應(yīng)商向用戶(hù)傳達(dá)必要的化學(xué)品危害信息的工具Thetoolforthechemicalsuppliertotransferessentialhazardinformationofachemicalproducttotherecipient提供緊急響應(yīng)的信息Provideemergencyresponseinformation管理工作場(chǎng)所中化學(xué)品的參考資料Thereferenceformanagementofhazardouschemicalsinworkplace操作工的安全培訓(xùn)Trainingprogramofworkerprotection安全措施Safetymeasures安全操作規(guī)程化學(xué)品安全技術(shù)說(shuō)明書(shū)（MSDS）27MSDS1.化學(xué)品及企業(yè)標(biāo)識(shí)Substance/preparationandcompanyidentification2.成份組成信息Composition/informationoningredients3.危險(xiǎn)性概述Hazardidentification4.急救措施Firstaidmeasures5.消防措施Fire-fightingmeasures6.泄漏應(yīng)急處理Accidentalreleasemeasures7.操作處置與儲(chǔ)存Handlingandstorage8.控制接觸/個(gè)體防護(hù)Exposecontrolandpersonalprotection9.理化特性Physicalandchemicalproperties10.穩(wěn)定性和反應(yīng)活性Stabilityandreactivity11..毒理學(xué)資料Toxicologicalinformation12.生態(tài)學(xué)資料Ecologicalinformation13.廢棄處置Disposalconsiderations14.運(yùn)輸信息Transportinformation15.法規(guī)信息Regulatoryinformation16.其他信息Otherinformation化學(xué)品安全技術(shù)說(shuō)明書(shū)（MSDS）28以一份Documentum中公布的MSDS為例，詳細(xì)說(shuō)明。TakeoneMSDSwhichhaspublishedinBYCDocumentumforexample,introduceeverypart.BYCPortal/EHS/MSDSC00-7.5.1-00PSH-200MSDSManagement舉例Example:29C00-6.3.0-00GSH-201

GuidelineInformationCard信息卡Informationcard30R22誤吞對(duì)人體有害HarmfulbyacuteingestionR24沾及皮膚后會(huì)中毒

ToxicbyacuteskinabsorptionR26吸入會(huì)中劇毒VeryToxicbyacuteinhalationR34引致灼傷Corrosivebyacuteeye/skinabsorptionR41對(duì)眼睛造成嚴(yán)重?fù)p害IrritantbyacuteeyeabsorptionR42吸入可引起過(guò)敏SensitisingbyacuteinhalationR45(1)引致癌癥

CarcinogenbychronicexposureR46(1)可造成遺傳性的基因損害MutagenbychronicexposureR47(1)可引致先天性缺陷Teratogenicbychronicexposure風(fēng)險(xiǎn)短語(yǔ)-舉例

Riskphrase-example31S1必須上鎖

KeeplockedupS2不要讓兒童接觸KeepoutofreachofchildrenS3置于陰涼處

Keepincoolplace

S4切勿放近住所

KeepawayfromlivingquartersS1/2上鎖保管并避免兒童接觸Keeplockedup&outofreachofchildrenS3/7保持容器密閉并在陰涼處保存

Keepcontainertightlyclosed,inacoolwellventilatedplaceS3/9/14置于陰涼、通風(fēng)處，并遠(yuǎn)離存放…(由生產(chǎn)廠(chǎng)指明的不相容物質(zhì))Keepinacool,wellventilatedplaceawayfrom…(incompatiblematerialtobeindicatedbymanufacturer)安全短語(yǔ)-舉例

Safetyphrase-example32你知道危害和如何保護(hù)自己knowthehazardandhowtoprotectyourself僅用于批準(zhǔn)的用途onlyusechemicalsintheapprovedpurpose儲(chǔ)存適當(dāng)suitablestoragethechemicals使用正確的個(gè)人防護(hù)用品usecorrectpersonalprotectiveequipments(PPE)不在使用化學(xué)品的區(qū)域飲食notdrinkandeatintheareaofusingchemicals接觸化學(xué)品后立即清洗cleanoutimmediatelyaftercontactingchemicals安全地使用化學(xué)品

Safetyusechemicals33可以用個(gè)人防護(hù)用品來(lái)防護(hù)化學(xué)品危害canusePPEtoprotectthechemicalshazard針對(duì)不同的化學(xué)品使用公司規(guī)定的個(gè)人防護(hù)用品usePPEwhichareprescriptivebycompanyaccordingtodifferentchemicals在使用前檢查個(gè)人防護(hù)用品,確保無(wú)損壞checkPPEandmakesurenodisrepairbeforeusing如果有飛濺危險(xiǎn),則使用面罩或防護(hù)鏡useshieldorgogglesifthereisthedangerofsplash使用適當(dāng)?shù)暮粑鞣雷o(hù)灰塵,煙霧usesuitableairsupplyingtoprotectdustandfug在操作化學(xué)品時(shí)使用正確的手套u(yù)secorrectgloveswhenworkingonchemicals使用后正確地清潔和儲(chǔ)存?zhèn)€人防護(hù)用品cleanandstoragePPEcorrectlyafterusing不要把個(gè)人防護(hù)用品帶回家–為什么要把危險(xiǎn)帶回家呢?nottakePPEhome–whytakedangerhome?保護(hù)自己-個(gè)人防護(hù)用品

Protectyourself-PPE34每種化學(xué)品和容器都必須合適地處置everychemicalandcontainermustbesuitabledisposed在徹底洗干凈前,容器并不是真的“空”了whetherthecontainerisemptyasfaraspossiblebeforebeingthoroughlycleaned根據(jù)環(huán)保法規(guī)要求處理使用過(guò)的容器disposetheusedcontaineraccordingtotherequestofenvironmentprotectionregulation依照BYC管理程序處理未使用的化學(xué)品disposetheuntappedchemicalsaccordingtotheBYCmanagementprocedure不要把未處理的化學(xué)品倒入水池、地表、雨水溝don’tpourthechemicalswithoutdisposalintopool,theearth’ssurfaceandthechannelofrainwater安全地處置化學(xué)品Safelydisposalwithchemicals35將不兼容的化學(xué)品分開(kāi)儲(chǔ)存storageseparatelywithunincompatiblechemicals將易燃物的數(shù)量減少到最低reducet