國(guó)賽作品8.15設(shè)計(jì)ms-2010物料平衡

1、2017“東華科技陜鼓杯”第十一屆大學(xué)生化工設(shè)計(jì)競(jìng)賽云南120 萬(wàn) Nm3/h 催化裂化煙氣脫硫項(xiàng)目物算一覽表團(tuán)隊(duì)名稱：蘭州理工大學(xué)鴻成團(tuán)隊(duì)指導(dǎo)老師：、強(qiáng)、團(tuán)隊(duì)成員：、祥、完成時(shí)間：2017 年 8 月目錄第一章 物算簡(jiǎn)介31.1 概述3物物物物算的目的3算的任務(wù)4算的基本步驟4算的方法4第二章 工藝概述4第三章 物算表53.1 二氧化硫富集工段53.1.1 吸收塔（T0101）53.1.2塔（T0102）73.1.3 閃蒸罐（V0101、V0102）83.1.4 換熱器（E0101E0109）103.1.5 二氧化硫富集工段23反應(yīng)工段243.2.1 反應(yīng)器（R0201R0203）243.2

2、.2 閃蒸罐（V0201V0206）273.2.3 換熱器（E0201E0211）333.23.2.4反應(yīng)工段483.3 全裝置48第一章 物算簡(jiǎn)介1.1 概述物算是確定化工生產(chǎn)過(guò)程中物料比例和物料轉(zhuǎn)變的定量關(guān)系的過(guò)程，是化工工藝計(jì)算中最基本、最重要的內(nèi)容之一。在化學(xué)工程中，設(shè)計(jì)或改造工藝流設(shè)備，了解和控制生產(chǎn)操作過(guò)程，核算生產(chǎn)的經(jīng)濟(jì)效益，確定主副產(chǎn)品的產(chǎn)率，確定原材料消耗，確定生產(chǎn)過(guò)程的損耗量，便于技術(shù)對(duì)現(xiàn)有的工藝過(guò)程進(jìn)行分析，選擇最有效的工藝路線，確定設(shè)備容量、數(shù)量及主要尺寸，對(duì)設(shè)備進(jìn)行最佳設(shè)計(jì)以及確定最佳操作條件等都要進(jìn)行物算。毫不夸張的說(shuō)，一切化學(xué)工程的開發(fā)和放大都是以物在化工過(guò)程中，

3、物料平衡是指在算為基礎(chǔ)的。時(shí)間內(nèi)進(jìn)入系統(tǒng)（體系）的全部物料質(zhì)量必定等于離開該系統(tǒng)（體系）的全部物料質(zhì)量再加上損失掉的與累積起來(lái)的物料質(zhì)量。對(duì)物料平衡進(jìn)行計(jì)算稱為物算。物料平衡的理論依據(jù)是質(zhì)量守恒定律，即在一個(gè)鼓勵(lì)體系中不論物質(zhì)發(fā)生任何變化（不包括核反應(yīng)）它的質(zhì)量始終不變。通常物算有兩種情況，一是對(duì)已有的生產(chǎn)設(shè)備或過(guò)程利用實(shí)測(cè)的數(shù)據(jù)，計(jì)算出另一些不能直接測(cè)定的物料量，俗稱生產(chǎn)查定，用此計(jì)算結(jié)果，對(duì)生產(chǎn)情況進(jìn)行分析，做出判斷，提出改進(jìn)措施；二是設(shè)計(jì)一種新的設(shè)備或過(guò)程，由物料求出進(jìn)出各設(shè)備的物料量、組成等，然后結(jié)合能量寸及整個(gè)工藝流程。，確定設(shè)備的工藝尺物算按操作方式則可分為間歇操作、連續(xù)操作以及半

4、連續(xù)操作等三類物算；或者將其分為穩(wěn)定狀態(tài)操作和不穩(wěn)定狀態(tài)操作兩類劃分，可分為單元操作過(guò)程（或者單個(gè)設(shè)備）和全流程的兩類物。如按范圍算?；ぴO(shè)計(jì)進(jìn)行的物算是先做單元操作過(guò)程（或單個(gè)設(shè)備）的物算，然后將各個(gè)過(guò)程匯總得到整個(gè)流程的物算，進(jìn)而完成物料流程圖。1.2 物算的目的本項(xiàng)目擬建一套年產(chǎn) 萬(wàn)噸的硫磺裝置，同時(shí)副產(chǎn)二氧化硫氣體等產(chǎn)品。工藝設(shè)計(jì)中，物算是在工藝流程確定后進(jìn)行的。目的是根據(jù)原料與產(chǎn)品之間的定量轉(zhuǎn)化關(guān)系，計(jì)算原料的消耗量，各種中間產(chǎn)品、產(chǎn)品和副產(chǎn)品的產(chǎn)量，生產(chǎn)過(guò)程中各階段的消耗量以及組成，進(jìn)而為熱量、其他工藝計(jì)算及設(shè)備計(jì)算打基礎(chǔ)。對(duì)于已有裝置，物算可以弄清原料的來(lái)龍去脈，找出生產(chǎn)中的薄弱

5、環(huán)節(jié)，為改進(jìn)生產(chǎn)、完善管理提供可靠的依據(jù)和明確方向，并可作為檢查原料利用率及三廢處理完善程度的一種。1.3 物算的任務(wù)1、確定硫磺以及副產(chǎn)品的實(shí)際產(chǎn)量以及質(zhì)量指標(biāo)；2、確定工藝中的“三廢”排放量等公共經(jīng)濟(jì)指標(biāo)；3、各主要單元過(guò)程的物算，并指導(dǎo)工藝設(shè)備的尺寸確定；4、匯總?cè)鞒涛锼?，?shù)據(jù)用于完成物料流程圖等后續(xù)設(shè)計(jì)任務(wù)。1.4 物算的基本步驟1、畫出工藝流程示意圖。2、列出化學(xué)反應(yīng)方程式。3、確定計(jì)算任務(wù)書。4、收集數(shù)據(jù)資料。5、選擇計(jì)算基準(zhǔn)。6、建立物料平衡方程，展開計(jì)算。7、整理并校核計(jì)算結(jié)果。8、繪制物料流程圖、填寫正式物料平衡表。1.5 物算的方法物算是根據(jù)質(zhì)量守恒定律，利用某進(jìn)出化工過(guò)

6、程中某些已知物流的流量和組成，通過(guò)建立有關(guān)物料的平衡式和約束式，求出其他未知物流的流量和組成的過(guò)程。系統(tǒng)中物算一般表達(dá)式為：系統(tǒng)中的積累=輸入-輸出+生成-消耗式中生成或消耗項(xiàng)是由于化學(xué)反應(yīng)而生成或消耗的量；積累量可以是正值，也可以是負(fù)值，當(dāng)系統(tǒng)中積累量不為零時(shí)稱為非穩(wěn)定狀態(tài)過(guò)程；積累量為零時(shí)，稱為穩(wěn)定狀態(tài)過(guò)程。穩(wěn)定狀態(tài)過(guò)程時(shí)，可以簡(jiǎn)化為：輸入=輸出-生成+消耗對(duì)無(wú)化學(xué)反應(yīng)的穩(wěn)定過(guò)程，又可表示為：輸入=輸出第二章 工藝概述本項(xiàng)目以總廠在云南省安寧市草鋪鎮(zhèn)安寧工業(yè)園區(qū)中的催化裂化裝置脫下的煙氣和雙脫裝置的硫化氫為原料，經(jīng)過(guò)煙氣吸收后富集得到二氧化硫與硫化氫進(jìn)行反應(yīng)，產(chǎn)生液態(tài)硫磺，再將液態(tài)硫磺直接

7、送至下游裝置，精制得到本廠產(chǎn)品固體硫磺。設(shè)計(jì)過(guò)程中利用 Aspen Plus 對(duì)全流程進(jìn)行模擬，并在此基礎(chǔ)上完成物能量，Aspen plus 全模擬流程如圖 2.1-1 所示。算、圖 2.1-1 全流程模擬流程圖第三章 物算表3.1 二氧化硫富集工段3.1.1 吸收塔（T0101）表 3.1-1 吸收塔（T0101）物算一覽表streamnameunitFULEGASS3CLEANGASRICH-1Temperature C555565.0108281 66.286884Prerebar1.013251.013251.013251.01325Molar Vapor1010FractionMol

8、ar0101Liquid FractionMolar Solid0000FractionMass Vapor1010FractionMass Liquid0101FractionMass Solid0000FractionMolarkcal/mol-17.777423 -102.92452 -17.274489 -102.7997EnlpyMasskcal/kg-628.91258 -3162.0928 -611.96536 -3110.199EnlpyMolarcal/mol-K 0.96580059 -39.192466 1.18688589 -38.88702EntropyMasscal

9、/gm-K0.03416717 -1.2040884 0.04204657 -1.176524EntropyMolarkmol/cum0.03718976 73.9701057 0.03608193 64.570825DensityMasskg/cum1.05124006 2407.68946 1.01851668 2134.2248DensityEnlpyGcal/hr-793.13972 -814.54282 -763.25718 -844.4252FlowAverage MW28.26692232.5494933 28.22788733.052463Mass Flowskg/hr1261

10、128.73 257596.119 1247222.86 271501.99H2Okg/hr124539.631 76611.667119212.432 79585.326SO2kg/hr8571.87024 1.57919903 153.7877950.162101O2kg/hr69287.0016 069285.2197 1.782005CO2kg/hr184255.830184109.715 146.11408N2kg/hr874474.394 0874461.703 12.691217NA2HPO4kg/hr0000NAH2PO4kg/hr0000NA2SO4kg/hr0000H3O+

11、kg/hr00.00574501 00.0091NA+kg/hr053737.6187 053737.619H3PO4kg/hr014.0008237 2.11E-1339.114329H2PO4-kg/hr029377.0008 042004.06HSO3-kg/hr0722.100211 011252.121HPO4-kg/hr082909.6549 070455.729SO3-kg/hr07.24129767 067.887739SO4-kg/hr014034.535014034.535PO4-kg/hr0180.715132 0114.83796H2Skg/hr0000S8kg/hr0

12、000S6kg/hr00003.1.2塔（T0102）表 3.1-2塔（T0102）物算一覽表streamunit4RICH-2S2SI nameTemperatureC100.573315118.5110.88869169.656816Prerebar1.034213591.013251.013251.01325Molar10.0896822801Vapor FractionMolar00.9103177210Liquid FractionMolar Solid0000FractionMass Vapor10.0492989801FractionMass Liquid00.950701021

13、0FractionMass Solid0000FractionMolarkcal/mol-57.202548-101.234-95.226594-68.18255EnlpyMasskcal/kg-3175.2239-3062.8278-3171.3828-1460.977EnlpyMolarcal/mol-K-8.8349747-34.756854-36.6515511.6292521EntropyMasscal/gm-K-0.4904156-1.0515662-1.22062640.0349107EntropyMolarkmol/cum0.033527180.3473955861.49116

14、930.035819DensityMasskg/cum0.6040014511.48227941846.385321.6716398DensityEnlpyGcal/hr-114.4051-831.56384-971.60328-1.704564FlowAverage18.0152833.052462930.02683746.669135 MWMass Flowskg/hr36030.56271501.988306365.8191166.72843.1.3 閃蒸罐（V0101、V0102）表 3.1-3 閃蒸罐（V0101）物算一覽表stream nameunitS2S5S6Temperatu

15、reC110.888691150150Prerebar1.013251.013251.01325Molar Vapor Fraction010Molar Liquid Fraction101Molar Solid Fraction000Mass Vapor Fraction010Mass Liquid Fraction101Mass Solid Fraction000Molar Enlpykcal/mol-95.226594-57.046699-129.40611Mass Enlpykcal/kg-3171.3828-3015.9607-2943.302Molar Entropycal/mol

16、-K-36.651551-7.306294-39.208964Mass Entropycal/gm-K-1.2206264-0.3862712-0.8917958H2Okg/hr36030.5679585.3258115727.36136.99967SO2kg/hr050.162101364.6427026869.14141O2kg/hr01.7820053.26E-251.782005CO2kg/hr0146.1140841.21E-10146.11408N2kg/hr012.6912172.86E-2512.691217NA2HPO4kg/hr0000NAH2PO4kg/hr0000NA2

17、SO4kg/hr0000H3O+kg/hr00.009100010.013146590NA+kg/hr053737.618753737.61870H3PO4kg/hr039.11432911.02E+025.26E-41H2PO4-kg/hr042004.059941027.60350HSO3-kg/hr011252.12079921.41010HPO4-kg/hr070455.728971132.10530SO3-kg/hr067.8877394277.7522530SO4-kg/hr014034.53514034.5350PO4-kg/hr0114.837964341.046310H2Sk

18、g/hr0000S8kg/hr0000S6kg/hr0000表 3.1-4 閃蒸罐（V0102）物算一覽表stream nameunitS5S7S8TemperatureC1508282Prerebar1.013251.013251.01325Molar Vapor Fraction110Molar Liquid Fraction001Molar Solid Fraction000Mass Vapor Fraction110Mass Liquid Fraction001Mass Solid Fraction000Molar Enlpykcal/mol-57.046699-63.781772-6

19、7.345579Mass Enlpykcal/kg-3015.9607-1567.5523-3707.8919Molar Entropycal/mol-K-7.306294-1.167849-35.768655Molar Densitykmol/cum61.49116930.028947584.7273157Mass Densitykg/cum1846.385320.547540013725.14689Enlpy FlowGcal/hr-971.60328-335.28881-574.51588Average MW30.02683718.914934643.9663037Mass Flowsk

20、g/hr306365.819111171.48195194.339H2Okg/hr115727.36103815.19213966.1537SO2kg/hr64.64270267356.2875212.569239O2kg/hr3.26E-2500.00E+00CO2kg/hr1.21E-1000.00E+00N2kg/hr2.86E-2500.00E+00NA2HPO4kg/hr000NAH2PO4kg/hr000NA2SO4kg/hr000H3O+kg/hr0.0131465900.00135966NA+kg/hr53737.6187053737.6187H3PO4kg/hr101.731

21、8067.66E-133.88E+01H2PO4-kg/hr41027.6035029661.267HSO3-kg/hr9921.41010959.066431HPO4-kg/hr71132.1053082538.0277SO3-kg/hr277.75225300.25440431SO4-kg/hr14034.535014034.535PO4-kg/hr341.046310246.065432H2Skg/hr000S8kg/hr000S6kg/hr0003.1.4 換熱器（E0101E0109）表 3.1-5 換熱器（E0101）物算一覽表Stream NameUnitsCOLDCOLDOUH

22、OTINHOTOUTTTemperatureC2020.05789359.15576Prerebar551.013251.01325MolarVapor0.00E+000.00E+0000FractionMass Entropycal/gm-K-0.3862712-0.028702-1.9693394Molar Densitykmol/cum0.02894750.0345868553.5221117Mass Densitykg/cum0.547540011.4072963972.109683Enlpy FlowGcal/hr-335.28881-12.664121-382.25609Avera

23、ge MW18.914934640.688767118.1627677Mass Flowskg/hr111171.488078.91446103092.565H2Okg/hr103815.1921815.78823101896.632SO2kg/hr7356.287526263.12623910.425176O2kg/hr0.00E+0000.00E+00CO2kg/hr0.00E+0000.00E+00N2kg/hr0.00E+0000.00E+00NA2HPO4kg/hr000NAH2PO4kg/hr000NA2SO4kg/hr000H3O+kg/hr0054.2596721NA+kg/h

24、r000H3PO4kg/hr7.66E-130.00E+000.00E+00H2PO4-kg/hr000HSO3-kg/hr00231.248377HPO4-kg/hr000SO3-kg/hr000.00041597SO4-kg/hr000PO4-kg/hr000H2Skg/hr000S8kg/hr000S6kg/hr000MolarLiquid111.00E+001.00E+00 FractionMolarSolid0000FractionMassVapor0.00E+000.00E+0000FractionMassLiquid111.00E+001.00E+00FractionMassSo

25、lid0000FractionMolar Enlpykcal/mol-68.405703-68.4046534.3435394.28472815653434Mass Enlpykcal/kg-3797.0935-3797.0352133.4441131.63735547851Molar Entropycal/mol-39.309028-39.305446-17.17962-17.357729K7957Mass Entropycal/gm-2.1819826-2.1817838-0.527800-0.5332720K72312Molar Densitykmol/cu41.900120141.89

26、846811.99468412.057586m999493Mass Densitykg/cum754.842397754.81265390.4208392.468243040166Enlpy FlowGcal/hr-30321.462-30320.99734.3746933.909263624569Average MW18.0152818.0152832.5494832.5494855114Mass Flowskg/hr7985439.967985439.9257596.0257596.051615775H2Okg/hr7985439.967985439.976611.66976611.669

27、16155SO2kg/hr0.00E+0001.5791801.57918011772O2kg/hr0000CO2kg/hr0000N2kg/hr0000NA2HPO4kg/hr0000NAH2PO4kg/hr0000NA2SO4kg/hr0000H3O+kg/hr0.00E+000.00E+000.0057450.00574500113NA+kg/hr0053737.6353737.638表 3.1-6 換熱器（E0102）物算一覽表Stream NameUnitsCOLDCOLDOUHOTINHOTOUTTTemperatureC66.373.290430150135.371Prereba

28、r1.013251.013251.013251.01325MolarVapor1.73E-085.34E-0611FractionMolarLiquid0.999999980.99999460.00E+000.00E+00Fraction362MolarSolid0000FractionMassVapor1.48E-084.45E-0611FractionMassLiquid0.999999980.99999550.00E+000.00E+00Fraction549MassSolid0000FractionMolar Enlpykcal/mol-102.79954-102.7107-57.04

29、669-57.169030605908Mass Enlpykcal/kg-3110.1942-3107.545-3015.960-3022.4288325H3PO4kg/hr0.00E+000.00E+0014.0008114.0008133443H2PO4-kg/hr0029376.9729376.9777217HSO3-kg/hr00722.0916722.091600219HPO4-kg/hr0082909.6082909.608998SO3-kg/hr0.00E+000.00E+007.24E+007.24E+00SO4-kg/hr0014034.5214034.5299993PO4-

30、kg/hr00180.7150180.715077661H2Skg/hr0000S8kg/hr0.00E+000.00E+0000S6kg/hr0.00E+000.00E+00003495718Molar Entropycal/mol-38.886521-38.63181-7.306294-7.600529K9426142Mass Entropycal/gm-1.1765095-1.1688181-0.386271-0.401826K02129Molar Densitykmol/cu64.572689663.6833500.0289470.0300046m256536Mass Densityk

31、g/cum2134.285622104.86400.5475400.567535780122Enlpy FlowGcal/hr-844.42352-843.70451-335.2888-336.0078421213Average MW33.052450333.05203118.9149318.9149349054442Mass Flowskg/hr271501.861271501.86111171.4111171.47515897H2Okg/hr79585.335079587.212103815.1103815.19939333SO2kg/hr5.02E+0156.8438127356.286

32、7356.2864434658O2kg/hr1.782005021.782005000626CO2kg/hr146.113872146.1138700424N2kg/hr12.691217612.69121700565NA2HPO4kg/hr0000NAH2PO4kg/hr0000NA2SO4kg/hr0000H3O+kg/hr9.10E-039.38E-0300NA+kg/hr53737.624753737.624007H3PO4kg/hr3.91E+014.50E+0100H2PO4-kg/hr42003.979341995.3780001HSO3-kg/hr11252.095411245

33、.39200478HPO4-kg/hr70455.699170443.27100592SO3-kg/hr6.79E+016.62E+010.00E+000.00E+00SO4-kg/hr14034.506214034.50600727表 3.1-7 換熱器（E0103）物算一覽表Stream NameUnitsCOLDCOLDOUHOTINHOTOUTTTemperatureC22.8125.22568299.769.6615Prerebar5511MolarVapor0.00E+000.00E+0010.0103425Fraction25MolarLiquid110.00E+009.90E-

34、01 FractionMolarSolid0000FractionMassVapor0.00E+000.00E+0010.0261931Fraction82MassLiquid110.00E+009.74E-01FractionMassSolid0000FractionMolar Enlpykcal/mol-68.351083-68.307639-57.36485-67.54260267785Mass Enlpykcal/kg-3794.0616-3791.6501-3104.670-3655.504589815Molar Entropycal/mol-39.123028-38.976664-

35、8.516036-35.975444K06161Mass Entropycal/gm-2.1716580-2.1635336-0.460900-1.9470437K62341Molar Densitykmol/cu55.391236655.3579020.0324873.2162038m340528Mass Densitykg/cum997.888636997.288110.60026159.4256619098569Enlpy FlowGcal/hr-42974.825-42947.510-153.9536-181.2683429599Average MW18.0152818.0152818

36、.4769518.476957PO4-kg/hr114.846697129.8337100688H2Skg/hr0000S8kg/hr0.00E+000.00E+0000S6kg/hr0.00E+000.00E+0000表 3.1-8 換熱器（E0104）物算一覽表Stream NameUnitsCOLDCOLDOUHOTINHOTOUTTTemperatureC110.9111.06082135.311516Prerebar1.013251.013251.013251.013257657Mass Flowskg/hr11326865.111326865.49587.7749587.77891

37、98326H2Okg/hr11326865.111326865.47830.1647830.1609190765SO2kg/hr0.00E+0001593.0221593.02299659O2kg/hr001.7849071.78490799111CO2kg/hr00150.1067150.106733442N2kg/hr0012.7030012.703005696NA2HPO4kg/hr0000NAH2PO4kg/hr0000NA2SO4kg/hr0000H3O+kg/hr0.00E+000.00E+0000NA+kg/hr0000H3PO4kg/hr0.00E+000.00E+0000H2

38、PO4-kg/hr0000HSO3-kg/hr0000HPO4-kg/hr0000SO3-kg/hr0.00E+000.00E+000.00E+000.00E+00SO4-kg/hr0000PO4-kg/hr0000H2Skg/hr001106.69941106.6994441S8kg/hr0.00E+000.00E+000.20762810.2076281112S6kg/hr0.00E+000.00E+000.0027530.00275311884MolarVapor6.94E-041.04E-0211FractionMolarLiquid0.999305770.98956910.00E+0

39、00.00E+00Fraction99MolarSolid0000FractionMassVapor4.19E-046.30E-0311FractionMassLiquid0.999580710.99369850.00E+000.00E+00Fraction506MassSolid0000FractionMolar Enlpykcal/mol-95.219435-95.119169-57.16903-57.3373485112Mass Enlpykcal/kg-3171.1508-3167.8982-3022.428-3031.32689521Molar Entropycal/mol-36.6

40、33313-36.377682-7.600529-8.0232027K9744Mass Entropycal/gm-1.2200215-1.2115412-0.401826-0.4241729K8319Molar Densitykmol/cu26.33060922.91761050.0300040.0315999m1666413Mass Densitykg/cum790.62328787.6040430.5675350.597710258739Enlpy FlowGcal/hr-971.53211-970.5356-336.0078-336.997084117Average MW30.0267

41、75330.02595518.9149318.9149344084656Mass Flowskg/hr306365.778306365.77111171.48111171.4799897H2Okg/hr115727.705115732.72103815.1103815.197739222SO2kg/hr6.59E+0183.7276487356.2877356.2875865216O2kg/hr0000CO2kg/hr0000N2kg/hr0000NA2HPO4kg/hr0000NAH2PO4kg/hr0000NA2SO4kg/hr0000H3O+kg/hr1.31E-021.30E-0200

42、表 3.1-9 換熱器（E0105）物算一覽表Stream NameUnitsCOLDCOLDOUHOTINHOTOUTTTemperatureC122.2142.5387.8219362.628456742Prerebar1.013251.013251.361.36MolarVapor3.37E-015.11E-010.9999990.9999998Fraction8878MolarLiquid0.662551590.48919061.21E-071.22E-07Fraction11MolarSolid0000FractionMassVapor2.02E-013.07E-010.999999

43、0.9999998Fraction8659MassLiquid0.797517600.69349411.40E-071.41E-07Fraction154MassSolid0000FractionMolar Enlpykcal/mol-91.777305-89.838584-43.75546-44.07751547768Mass Enlpykcal/kg-3056.8503-2992.2768-1014.878-1022.34825853Molar Entropycal/mol-27.775090-22.9721169.3666608.8699105K1555619NA+kg/hr53737.

44、644753737.64400777H3PO4kg/hr1.02E+021.02E+0200H2PO4-kg/hr41024.329240977.68700527HSO3-kg/hr9920.986099914.300600746HPO4-kg/hr71135.359671182.59600541SO3-kg/hr2.77E+022.61E+020.00E+000.00E+00SO4-kg/hr14034.528214034.52800323PO4-kg/hr340.988848340.0896500164Mass Entropycal/gm-0.9251120-0.76513820.2172

45、530.2057315K813788Molar Densitykmol/cu0.091824210.05768310.0248050.0257959m7026205Mass Densitykg/cum2.756883131.73184781.0694691.1121644247499Enlpy FlowGcal/hr-6.9287342-6.7823704-19.88582-20.0321869942Average MW30.023486530.02348643.11399443.11399485833Mass Flowskg/hr2266.625282266.625219594.281959

46、4.2886868437H2Okg/hr856.3798856.37985759.6395759.6390199SO2kg/hr0.00E+000683.7461683.746133772O2kg/hr001.7820031.78200322879CO2kg/hr002346.6102346.61033547N2kg/hr0012.69121112.691211877NA2HPO4kg/hr0000NAH2PO4kg/hr0000NA2SO4kg/hr0000H3O+kg/hr9.73E-059.73E-050.0005160.00051600106NA+kg/hr397.658426397.

47、6584200161H3PO4kg/hr7.53E-017.53E-0100H2PO4-kg/hr303.604097303.6040900979HSO3-kg/hr73.418399673.4183990.0021990.00219913631659HPO4-kg/hr526.377293526.3772900636SO3-kg/hr2.055363832.05536383.91E-093.91E-09838SO4-kg/hr103.855251103.8552500414PO4-kg/hr2.523739212.523739200表 3.1-10 換熱器（E0106）物算一覽表Stream

48、 NameUnitsCOLDCOLDOUTTemperatureC122.2150.6041016Prerebar1.013251.01325Molar Vapor Fraction0.337448410.540510835Molar Liquid Fraction0.662551590.459489165Molar Solid Fraction00Mass Vapor Fraction0.2024823990.324327889Mass Liquid Fraction0.7975176010.675672111Mass Solid Fraction00Molar Enlpykcal/mol-

49、91.77730547-89.449324Mass Enlpykcal/kg-3056.85035-2979.31167Molar Entropycal/mol-K-27.77509015-22.044511Mass Entropycal/gm-K-0.925112081-0.73424221Molar Densitykmol/cum0.0918242170.053459232Mass Densitykg/cum2.7568831321.605032528Enlpy FlowGcal/hr-867.0281029-845.035461Average MW30.0234865830.023486

50、58Mass Flowskg/hr283634.4614283634.4614H2Okg/hr107163.202107163.202SO2kg/hr00O2kg/hr00CO2kg/hr00N2kg/hr00NA2HPO4kg/hr00NAH2PO4kg/hr00NA2SO4kg/hr00H3O+kg/hr0.0121737570.012173757NA+kg/hr49761.0408949761.04089H3PO4kg/hr9.42E+019.42E+01H2PO4-kg/hr37991.5398237991.53982919H2Skg/hr001106.89821106.8982217

51、S8kg/hr009650.2979650.29788993S6kg/hr0032.6207432.6207444659表 3.1-11 換熱器（E0107）物算一覽表Stream NameUnitsCOLDCOLDOUHOTINHOTOUTTTemperatureC27.0155443115824Prerebar551.013251.01325MolarVapor0.00E+000.00E+0010.0026513Fraction57MolarLiquid1100.9973486Fraction43MolarSolid0000FractionMassVapor0.00E+000.00E+00

52、10.0051156Fraction98MassLiquid1100.9948843Fraction02MassSolid0000FractionMolar Enlpykcal/mol-68.733911-68.642101-57.06153-67.2313546675Mass Enlpykcal/kg-3815.3118-3810.2156-3141.676-3701.602968434Molar Entropycal/mol-40.464532-40.133861-8.392491-35.697400K26871Mass Entropycal/gm-2.2461228-2.2277678-

53、0.462071-1.9654163K61622Molar Densitykmol/cu42.399202542.2629520.0316369.9391927m4585597Mass Densitykg/cum763.833505761.378920.574607180.523256432503HSO3-kg/hr9187.221369187.22136HPO4-kg/hr65868.2937765868.29377SO3-kg/hr257.1982316257.1982316SO4-kg/hr12995.9409212995.94092PO4-kg/hr315.8084482315.808

54、4482H2Skg/hr00S8kg/hr00S6kg/hr00表 3.1-12 換熱器（E0108）物算一覽表Stream NameUnitsHOTINHOTOUTTemperatureC150125Prerebar1.013251.01325Molar Vapor Fraction00Molar Liquid Fraction11Molar Solid Fraction00Enlpy FlowGcal/hr-43215.523-43157.798-323.8834-381.607742973Average MW18.0152818.0152818.1627618.1627677774Mas

55、s Flowskg/hr11326865.111326865.103092.5103092.569196552H2Okg/hr11326865.111326865.101896.6101896.639193216SO2kg/hr0.00E+000910.4251910.425177657O2kg/hr0000CO2kg/hr0000N2kg/hr0000NA2HPO4kg/hr0000NAH2PO4kg/hr0000NA2SO4kg/hr0000H3O+kg/hr0054.2596754.2596711992NA+kg/hr0000H3PO4kg/hr0.00E+000.00E+0000H2P

56、O4-kg/hr0000HSO3-kg/hr00231.2483231.248377656HPO4-kg/hr0000SO3-kg/hr000.0004150.00041599767SO4-kg/hr0000PO4-kg/hr0000H2Skg/hr0000S8kg/hr0000S6kg/hr0000表 3.1-13 換熱器（E0109）物算一覽表Stream NameUnitsHOTINHOTOUTTemperatureC15055Prerebar1.013251.01325Molar Vapor Fraction00Mass Vapor Fraction00Mass Liquid Frac

57、tion11Mass Solid Fraction00Molar Enlpykcal/mol-129.4060641-129.74725Mass Enlpykcal/kg-2943.301831-2951.039Molar Entropycal/mol-K-39.20893286-40.0248171Mass Entropycal/gm-K-0.891795332-0.91034528Molar Densitykmol/cum84.7539543686.98693039Mass Densitykg/cum3726.3173824.522466Enlpy FlowGcal/hr-430.8868

58、137-432.019503Average MW43.9662907643.96663325Mass Flowskg/hr146395.7278146395.7278H2Okg/hr10474.6152810474.14801SO2kg/hr9.4268765137.765162295O2kg/hr00CO2kg/hr00N2kg/hr00NA2HPO4kg/hr00NAH2PO4kg/hr00NA2SO4kg/hr00H3O+kg/hr0.0010197440.001012846NA+kg/hr40303.2335840303.23358H3PO4kg/hr2.91E+011.67E+01H

59、2PO4-kg/hr22245.9378122197.72634HSO3-kg/hr719.2995454721.4481192HPO4-kg/hr61903.4948462037.83377SO3-kg/hr0.1907985610.145658052SO4-kg/hr10525.8961710525.89617PO4-kg/hr184.5467967110.8608544H2Skg/hr00S8kg/hr00S6kg/hr003.1.5 二氧化硫富集工段表 3.1-14 二氧化硫富集工段物算一覽表見附錄 1Molar Liquid Fraction11Molar Solid Fractio

60、n00Mass Vapor Fraction00Mass Liquid Fraction11Mass Solid Fraction00Molar Enlpykcal/mol-129.4060641-130.33553Mass Enlpykcal/kg-2943.301831-2964.35013Molar Entropycal/mol-K-39.20893286-41.6110249Mass Entropycal/gm-K-0.891795332-0.94640078Molar Densitykmol/cum84.7539543691.5686613Mass Densitykg/cum3726