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1、Recently, blending of polymers has become an increasingly important area of research activity. Elastomeric blends are used for many reasons such as lowering the compound cost, for ease of fabrication and to improve the performance of the industrial rubber. Natural rubber (NR) and styrenebutadiene ru
2、bber (SBR) have been blended for a long time for these reasons. In this study, 12 different rubber compounds were prepared by using SMR-20 type of natural rubber and SBR-1502 type of styrenebutadiene rubber in different proportions, keeping fixed the total rubber quantity specified in the standard t
3、esting recipe. The mechanical and physical properties such as tensile strength, hardness, wear, carbon black, ozone resistance, density and rheological properties of the present industrial rubber were studied. Physical and mechanical test results were reported. The tensile, hardness and wear propert
4、ies of the NR/SBR blends with the increment of NR percentages were greatly enhanced. The study also indicated that filler materials affect on the physical and mechanical properties of the blends. Blending of two or more types of polymer is a useful technique for the preparation and developing materi
5、als with properties superior to those of individual constituents. It is important especially from an industrial point of view to control the state of mixing of polymer blends. An adequate polymer-blend process requires information and understanding of the blend behavior under production conditions.
6、The knowledge of the relationship among melt viscosity, elasticity, and pressure and process temperature is important for the design appropriate process equipment and for assessment of the optimum process conditions to produce materials that have required properties. Natural rubber has been studied
7、and reported on extensively because of its superior performance in tire applications. It is well installed that elastomers do not display all of the characteristics that are required. Elastomeric blends are used for many purposes such as lowering the compound cost. The complex shaped product may be
8、more easily fabricated during production. Natural rubber (NR) and styrenebutadiene rubber (SBR) have been blended for along time for these reasons. A lot of studies have demonstrated that the mechanical properties of such blends can be significantly improved by adding a suitable compatibiliser. NR b
9、lending has been widely studied and reported as good compatible blends that provide desirable mechanical properties. Another paper about the development of novel elastomeric blends containing NR and ultra-low-density polyethylene (ULDPE) reported by Tanrattanakul and Udomkichdecha. Conventional vulc
10、anization was performed and the physical and mechanical properties of the blend were determined. The results were compared with those obtained from NR blending with SBR. Blending SBR with NR can improve the tensile strength because NR crystallizes on stretching. Kim investigated the mechanical prope
11、rties of NR blended with SBR. Those study indicated that the mechanical properties of this blend were required reinforcement. Thus, filled polymer systems are very popular for the industry for both cost and performance objectives. It is also well established that carbon black (CB) is one of the most
12、 important classical reinforcing fillers, especially for the rubber technology for cheaper Vulcan sates. New materials are also considered as fillers, whether for more economical reasons or rather to impart some desirable characteristics of CB as one of the major inputs in tire industry, has some ex
13、traordinary features. Surface area of CB is one of the most critical parameters considered for degree of reinforcement, which supply necessary sites to polymer chains for wetting. As some of the polymer chains may also enter into the holes of the particles depending on the rheological (viscosity) pr
14、operties of the polymers, the so-called physical entrapment and physical crosslink may also play an important role during reinforcement of elastomeric matrices. One of the most important parameters for the performance of a composite material is the degree of adhesion at the matrix filler interface.最
15、近,聚合物混合已成為研究活動(dòng)中一個(gè)日益重要的領(lǐng)域。彈性體共混物的應(yīng)用有很多原因,如降低復(fù)合成本,易于制造,并可提高工業(yè)橡膠的性能。由于這些原因,天然橡膠和丁苯橡膠的混合已有一段時(shí)間。在這次研究中,通過(guò)使用不同比例的SMR-20型天然橡膠和SBR-1502 型丁苯橡膠,制得了12種不同的橡膠化合物,并在指定的標(biāo)準(zhǔn)測(cè)試配方中保持固定的橡膠數(shù)量。同時(shí)還對(duì)力學(xué)性能和物理性能如拉伸強(qiáng)度、硬度、耐磨性、炭黑、耐臭氧性、密度和目前工業(yè)橡膠的流變性能進(jìn)行了研究。還對(duì)物理和力學(xué)性能實(shí)驗(yàn)結(jié)果進(jìn)行了報(bào)道。隨著天然橡膠比例的增加,天然橡膠/丁苯橡膠拉伸強(qiáng)度、硬度和耐磨性大大提高了。研究還表明,填充材料影響著共混物的物
16、理和力學(xué)性能。 對(duì)于編制和開(kāi)發(fā)材料,兩種或兩種以上類型的聚合物混合是一種有用的技術(shù)。其性能優(yōu)于單個(gè)成分的編制和開(kāi)發(fā)材料。這是重要的,尤其是從產(chǎn)業(yè)的角度來(lái)控制聚合物共混物的混合狀態(tài)。充足的聚合物共混過(guò)程需要有關(guān)生產(chǎn)條件下混合性能的信息和解釋。對(duì)于適當(dāng)工藝設(shè)備的設(shè)計(jì)和生產(chǎn)所需屬性的材料的最佳工藝條件的評(píng)估,有關(guān)熔體粘度、彈性、壓力和生產(chǎn)溫度之間關(guān)系的知識(shí)是很重要的。因?yàn)樘烊幌鹉z在輪胎應(yīng)用中的優(yōu)越性能,其已被研究和報(bào)道。經(jīng)安裝好后,彈性體并不顯示必需的所有特性。彈性體共混物有多種用途,例如可降低復(fù)合成本。形狀復(fù)雜的產(chǎn)品可能更容易在生產(chǎn)過(guò)程中制造。由于這些原因,天然橡膠和丁苯橡膠已被混合有很長(zhǎng)一段時(shí)間了。諸多研究表明,這種混合物的力學(xué)和物理性能能夠通過(guò)混合添加合適的相容劑而顯著達(dá)到。由于良好的兼容性,天然橡膠共混物表現(xiàn)出理想的力學(xué)和物理性能,且得到了廣泛的研究和報(bào)道。另一個(gè)有關(guān)新型彈性天然橡膠和超低密度聚乙烯(ULDPE)混合物發(fā)展的文章是由Tanrattanakul和Udomkichdecha報(bào)道的。同時(shí)他們還對(duì)傳統(tǒng)的硫化和共混物的力學(xué)性能進(jìn)行了測(cè)定。所得結(jié)果同天然橡膠與丁苯橡膠共混物得到的結(jié)果進(jìn)行了比較。天然橡膠與丁苯橡膠共混物可以提高拉伸強(qiáng)度,是因?yàn)樘烊幌鹉z的結(jié)晶性伸展。Kim研究了天然橡膠與丁苯橡膠共混物的力學(xué)性能。這些研究表明,這種混合物的力學(xué)性能需要
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