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濰坊華纖光電科技有限公司ContinuedContinuedonnextThisMaterialSafetyDataSheet(MSDS)hasbeenpreparedinaccordancewiththerequirementsoftheOSHACommunicationStandard(CFR29MaterialSafetyDataDeSolite?950-SectionSection1.ChemicalproductandcompanyProductnameMaterialSectionSection2.Hazards :Liquid. : HazardousMaterialInformationSystem(U.S.A.)Potentialacutehealtheffects Potentialchronichealth
MAYCAUSEALLERGICSKINREACTION.MAYCAUSERESPIRATORYTRACT,EYEANDSKINIRRITATION.CONTAINSMATERIALTHATMAYCAUSETARGETORGANDAMAGE,BASEDONANIMALDATA.Moderatelyirritatingtotheeyes,skinandrespiratorysystem.Maycausesensitizationbyskincontact.Donotbreathevaporormist.Donotgetonskinorclothing.Avoidcontactwitheyes.Containsmaterialthatmaycausetargetorgandamage,basedonanimaldata.Useonlywithadequateventilation.Keepcontainertightlyclosedandsealeduntilreadyforuse.Washthoroughlyafterhandling.ThismaterialisconsideredhazardousbytheOSHAHazardCommunicationStandard(29CFR1910.1200).*211PERSONAL ThePPE(PersonalProtectionEquipment)designationintheHMISisprovidedforusebyemployeesatsuppliersitesonly.OtherusersofthisproductareencouragedtoevaluatethehazardsoftheproductandassignPPEthatisapplicabletotheirspecificsituations.Moderatelyirritatingtotherespiratorysystem.Noknownsignificanteffectsorcriticalhazards.Moderatelyirritatingtotheskin.Maycausesensitizationbyskincontact.Moderatelyirritatingtoeyes.Chroniceffects :Containsmaterialthatmaycausetargetorgandamage,basedonanimaldata.Oncesensitized,asevereallergicreactionmayoccurwhensubsequentlyexposedtoverylowPage:ContinuedContinuedonnext :Noknownsignificanteffectsorcritical :Noknownsignificanteffectsorcritical :Noknownsignificanteffectsorcriticalhazards.Developmentaleffects :Noknownsignificanteffectsorcriticalhazards. :NoknownsignificanteffectsorcriticalTarget :Containsmaterialwhichmaycausedamagetothefollowingorgans:skin,Medicalconditionsaggravatedbyover-exposure
:Pre-existingskindisordersanddisordersinvolvinganyothertargetorgansmentionedinthisMSDSasbeingatriskmaybeaggravatedbyover-exposuretothisproduct.Seetoxicologicalinformation(SectionSection3.Composition/informationonCAS%byGlycolether10-Multifunctional-1--Therearenoadditionalingredientspresentwhich,withinthecurrentknowledgeofthesupplierandintheconcentrationsapplicable,areclassifiedashazardoustohealthortheenvironmentandhencerequirereportinginthisSectionSection4.FirstaidEyecontactSkincontact
:Immediatelyflusheyeswithrunningwaterforatleast15minutes,keepingeyelidsopen.Getmedicalattention.:Takeoffimmediatelyallcontaminatedclothing.Washwithsoapandwater.Getmedical:Ifinhaled,removetofreshair.Getmedicalattentionifsymptoms:Ifswallowed,rinsemouthwithwater(onlyifthepersonisconscious).Getmedicalattentionifsymptomsoccur.Protectionoffirst-aiders :Noactionshallbetakeninvolvinganypersonalriskorwithoutsuitabletraining.Itmaybedangeroustothepersonprovidingaidtogivemouth-to-mouthresuscitation.Washcontaminatedclothingthoroughlywithwaterbeforeremovingit,orweargloves.Notesto
Nospecifictreatment.Treatsymptomatically.Contactpoisontreatmentspecialistimmediatelyiflargequantitieshavebeeningestedorinhaled.SectionSection5.Fire-fightingFlammabilityofthe :Inafireorifheated,apressureincreasewilloccurandthecontainermayHazardousthermaldecompositionproductsExtinguishing
:Incaseoffire,mayproducehazardousdecompositionproductssuchascarbonmonoxide,carbondioxide,(dense)blacksmoke,aldehydes,organicacids. :Usewater,foamordrychemicalSpecialfire-fightingProtectionoffire-
:Firewatercontaminatedwiththismaterialmustbecontainedandpreventedfrombeingdischargedtoanywaterway,sewerordrain.:Wearsuitableprotectiveclothing.Self-containedbreathingSectionSection6.AccidentalreleasePersonal
:Noactionshallbetakeninvolvinganypersonalriskorwithoutsuitabletraining.Evacuatesurroundingareas.Keepunnecessaryandunprotectedpersonnelfromentering.Donottouchorwalkthroughspilledmaterial.Avoidbreathingvaporormist.Provideadequateventilation.Wearappropriaterespiratorwhenventilationisinadequate.Putonappropriatepersonalprotectiveequipment(seeSection8).:Prevententryintosewers,basementsorconfinedareas.Dikeifnecessary.Incaseofcontaminationofaquaticenvironment,informlocalauthorities.Methodsforcleaning
Prevententryintosewers,basementsorconfinedareas.Dikeifnecessary.Absorbspillwithinertmaterial(e.g.drysandorearth)andplaceinachemicalwastecontainer.Recycle,ifpossible.Avoidreleasetotheenvironment.Thismaterialanditscontainermustbedisposedofashazardouswaste.Keepawayfromsourcesofignition.SectionSection7.Handlingand
:Preferablyuseinclosedsystems.Usewithadequateventilation.Usesuitableprotectiveequipment.Avoidcontactwitheyes,skinandclothing.Donotallowtoenterdrainsor:Storeinafireprooflocation.Keepawayfromincompatiblematerialsandavoidspecificconditions(Seesection10).UseappropriatecontainmenttoavoidenvironmentalStorage :Storebetweenthefollowingtemperatures:15and30SectionSection8.Exposurecontrols/personalEngineeringPersonalprotection
:Useonlywithadequateventilation.Ifuseroperationsgeneratedust,fumes,gas,vaporormist,useprocessenclosures,localexhaustventilationorotherengineeringcontrolstokeepworkerexposuretoairbornecontaminantsbelowanyrecommendedorstatutorylimits.:Safetyeyewearcomplyingwithanapprovedstandardshouldbeusedwhenariskassessmentindicatesthisisnecessarytoavoidexposuretoliquidsplashes,mistsordusts.:Personalprotectiveequipmentforthebodyshouldbeselectedbasedonthetaskbeingperformedandtherisksinvolvedandshouldbeapprovedbyaspecialistbeforehandlingthisproduct.:Useaproperlyfitted,air-purifyingorair-fedrespiratorcomplyingwithanapprovedstandardifariskassessmentindicatesthisisnecessary.Respiratorselectionmustbebasedonknownoranticipatedexposurelevels,thehazardsoftheproductandthesafeworkinglimitsoftheselectedrespirator.
Chemical-resistant,imperviousglovescomplyingwithanapprovedstandardshouldbewornatalltimeswhenhandlingchemicalproductsifariskassessmentindicatesthisisProduct ExposureMultifunctional AIHAWEEL(UnitedStates,5/2010).AbsorbedthroughTWA:1mg/m38 ACGIHTLV(UnitedStates,2/2010).AbsorbedthroughTWA:5mg/m38OSHAPEL1989(UnitedStates,3/1989).AbsorbedthroughTWA:5mg/m38NIOSHREL(UnitedStates,6/2009).AbsorbedthroughTWA:5mg/m310ConsultlocalauthoritiesforacceptableexposureSectionSection9.Physicalandchemical :Liquid.Flash :Closedcup:>93°C(>199.4°F)[Closedcup,ISOSpecificgravity
::::Dynamic:2200to2800mPa·s(2200to2800:Insolubleinthefollowingmaterials:coldSectionSection10.StabilityandStabilityandreactivityConditionstoavoidMaterialstoavoid
:Theproductis:Keepawayfromheat,sparksand:NospecialHazardousdecomposition
:Undernormalconditionsofstorageanduse,hazardousdecompositionproductsshouldnotbeproduced.Possibilityofhazardous
:Undernormalconditionsofstorageanduse,hazardousreactionswillnotSectionSection11.ToxicologicalAcuteMultifunctionalLD505170-LD505710-GlycoletherLD502540-LD502540-LD504660-LD504660-LD50Rat-Male,>2000-LD505-LD504-LD50>2000-LD50Rat-Male,1370-LC50InhalationDustsand>2000001 :MultifunctionalAcrylate:Mutagenicityresultsforthiscompoundaremixed.IntheAmestest,ityieldedaweaklypositiveresponsewithmetabolicactivationandanegativeresponsewithoutmetabolicactivation.ThiscompoundwasalsopositiveinthemouselymphomaassaybutnegativeintheUDSassay.Morerecently,ityieldedpositiveresultsinaninvitromammalianchromosomeaberrationtest.Adermalcarcinogenicitystudyonthiscompoundwasnegative.Photo-initiators:Ratswereadministereddietaryconcentrationsof0,1200,2000,4000or8000ppmfor3monthsfollowedbya1monthrecoveryperiod(highdoseandcontrolonly).Theliverandkidneyweretargetorgans.Malekidneysweremostprominentlyaffected.Theseeffectsincludedadose-relatedincreaseinkidneyweightandhistopathologyaccompaniedbyproteinuria.Allofthefindingswerenotcompletelyreversible.Mildlivercellchangeswereseenatthetwohighestconcentrationsbutenzymealterationsdidnotoccurandthefindingswerereversible.Thelow-dosegroup,1200ppm,equivalentto79-108mg/kg/day,wasconsideredamarginaleffectlevel.Chronic :NotGlycoletherSkin-Mild-500-Eyes-MammalMultifunctionalEyes-Moderate-100-Skin-Moderate-24hours500- :NotRouteofGuinea :Not :Not :Not :Not :NotSectionSection12.Ecological :NoknownsignificanteffectsorcriticalAquaticMultifunctionalAcrylateAcuteLC501to2.2AcuteEC50>100mg/lFreshAcuteEC50>100mg/lFreshAcuteEC5011.92mg/lFreshwaterAcuteLC5070.7mg/lFreshwaterAlgae-DesmodesmusAlgae-DesmodesmusFish-Oncorhynchusmykiss-40to60mm9672724896 :NotOECD0%-Notreadily-28100- :NotOtheradverse :NoknownsignificanteffectsorcriticalPage:SectionSection13.DisposalWaste :WastemustbedisposedofinaccordancewithnationalandlocalenvironmentalDisposalshouldbeinaccordancewithapplicableregional,nationalandlocallawsandRefertoSection7:HANDLINGANDSTORAGEandSection8:EXPOSURECONTROLS/PERSONALPROTECTIONadditionalhandlinginformationandprotectionofemployees.Consultyourlocalorregionalauthorities.Section14.TransportUNPropershippingPackingDOTTDG9LimitSUBSTANCE,N.O.S.(2,2-dimethoxy-one).Marinepollutant5SUSTANCIALIQUIDAPELIGROSASPARAELMEDIOAMBIENTE,N.E.P.Marinepollutant(2,2-9179,274ADR/RID9SUBSTANCE,N.O.S.(2,2-dimethoxy-5274335TunnelContinuedonnextPage:IMDGSUBSTANCE,N.O.S.(2,2-dimethoxy-one).Marinepollutant9F-A,S-9andliquid,n.o.s.(2,2-450Cargo450Quantities30SectionSection15.RegulatoryCleanAirActSection112(b)HazardousAirPollutants(HAPs)FormR-ReportingSupplier
:Product CAS :Glycolether :Glycolether SARA313notificationsmustnotbedetachedfromtheMSDSandanycopyingandredistributionoftheMSDSshallincludecopyingandredistributionofthenoticeattachedtocopiesoftheMSDSsubsequentlyredistributed.State
ConnecticutCarcinogenReporting:Noneofthecomponentsarelisted.ConnecticutHazardousMaterialSurvey:Noneofthecomponentsarelisted.Floridasubstances:Noneofthecomponentsarelisted.IllinoisChemicalSafetyAct:NoneofthecomponentsareIllinoisToxicSubstancesDisclosuretoEmployeeAct:NoneofthecomponentsareLouisianaReporting:NoneofthecomponentsareLouisianaSpill:NoneofthecomponentsareContinuedContinuedonnextPage:UnitedStatesinventory(TSCA8b)
MassachusettsSpill:Noneofthecomponentsarelisted.MassachusettsSubstances:Noneofthecomponentsarelisted.MichiganCriticalMaterial:Noneofthecomponentsarelisted.MinnesotaHazardousSubstances:Noneofthecomponentsarelisted.NewJerseyHazardousSubstances:Thefollowingcomponentsarelisted:GLYCOLNewJerseySpill:NoneofthecomponentsareNewJerseyToxicCatastrophePreventionAct:NoneofthecomponentsareNewYorkAcutelyHazardousSubstances:Noneofthecomponentsarelisted.NewYorkToxicChemicalReleaseReporting:Noneofthecomponentsarelisted.PennsylvaniaRTKHazardousSubstances:Thefollowingcomponentsarelisted:GLYCOLETHERSRhodeIslandHazardousSubstances:Noneofthecomponentsare:AllcomponentsarelistedorSectionSection16.OtherLabel
MAYCAUSEALLERGICSKINREACTION.MAYCAUSERESPIRATORYTRACT,EYEANDSKINIRRITA
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