CdTe薄膜太陽(yáng)能電池ppt課件

1、CdTeCdTe薄膜太陽(yáng)能電池；一、一、CdTeCdTe薄膜太陽(yáng)能電池原理薄膜太陽(yáng)能電池原理二、二、CdTeCdTe薄膜太陽(yáng)能電池構(gòu)造薄膜太陽(yáng)能電池構(gòu)造三、三、TiO2TiO2作緩沖層文獻(xiàn)分析作緩沖層文獻(xiàn)分析四、四、CdTeCdTe太陽(yáng)能電池展望太陽(yáng)能電池展望五、參考文獻(xiàn)五、參考文獻(xiàn)；CdTeCdTe太陽(yáng)能電池的原理chE光子的能量公式可見(jiàn)光的波長(zhǎng)：380760nm 能量：1.643.19eV；CdTe的能隙值為1.45eV，是直接能隙。TCO的能隙為3.24.3eV，是間接能隙。；CdTe太陽(yáng)能電池的構(gòu)造類型由于Substrate型太陽(yáng)能電池CdS/CdTe的界面質(zhì)量較差，歐姆接觸性差，所以

2、轉(zhuǎn)化效率較低，普通不常用。；CdTe太陽(yáng)能電池構(gòu)造圖 ；降低CdTe與金屬電極接觸勢(shì)壘P型半導(dǎo)體N型半導(dǎo)體透明導(dǎo)電氧化層；玻璃襯底普通選用鈣鈉玻璃作為太陽(yáng)能電池的襯底，主要起支架、防止污染和太陽(yáng)光入射的作用。；TCO 透明導(dǎo)電氧化層TCO(透明導(dǎo)電氧化物薄膜）ITO（摻Sn的In2O3)AZO(摻Al的ZnO)FTO(摻F的SnO2)ATO(摻Sb的SnO2)；05000001000000150000020000002500000300000035000004000000SnSbZnInAlCuAg各種金屬的價(jià)格（元各種金屬的價(jià)格（元/噸）噸）；CdS窗口層1、CdS的能隙普通在2.4eV，幾

3、乎一切的可見(jiàn)光都能透過(guò)。2、CdS層與CdTe層構(gòu)成p-n結(jié)。3、為了使太陽(yáng)能電池獲得更高的效率，CdS層要盡量的薄， 普通在不超越500nm；1 1、CdTeCdTe能隙值為能隙值為1.45eV,1.45eV,位于理想的太陽(yáng)能電池的能隙之位于理想的太陽(yáng)能電池的能隙之 間，且具有很高的吸光系數(shù)，是非常理想的光伏資料間，且具有很高的吸光系數(shù)，是非常理想的光伏資料2 2、CdTeCdTe層的厚度普通在層的厚度普通在2-8m.2-8m.CdTe吸收層；背接觸層和背電極降低降低CdTeCdTe和金屬電極的接觸勢(shì)壘，引出電流，是金屬電和金屬電極的接觸勢(shì)壘，引出電流，是金屬電極與極與CdTeCdTe構(gòu)成歐

4、姆接觸構(gòu)成歐姆接觸；Performance improvement of solution-processed CdS/CdTe solarcells with a thin compact TiO2 buffer layerQuestionIn order to reduce the light absorption loss in CdS, the CdS thickness is usually less than 500 nm. However, pinholes in CdS and non-conformal coverage of CdS on transparent condu

5、ctingoxide layer will cause shunting thus leading to device performance degradation and failure. Solution In order to alleviate this problem , a layer of TiO2 was inserted between the FTO and CdS as a buffer layer.；Materials and methods1、Substrate cleaning (the soda-lime glasses coated with 600nm FT

6、O)2、TiO2 was deposited using DC magnetron sputtering3、 CdS chemical bath deposition4、CdTe electrochemical deposition5、CdCl2 treatment the wafe in CdCl2 methanol solution at 60 for 20 min)6、50nm Au dots were deposited by thermal evaporation as back contact .；1、TiO2 in solar cells helps in improving e

7、fficiency by stopping holes from going to TCO front contact . 2、TiO2 window layer helps in the separation of charge carriers and reduces the recombination rate.；In order to identify the optimum thickness for TiO2,solar cell devices with 20-, 40-, 60-, 80- and 100-nm-thick；Conclusions1、By inserting a

8、 compact TiO2 layer with 20 nm thickness, device yield was improved to more than 80 % with a peak efficiency of 8.0 %. 2 、TiO2 buffer layer helps to solve the short-circuiting problems caused by thinnon-uniform CdS. The addition of a compact TiO2 layer was also found to significantly improve device stability.；CdTe太陽(yáng)能電池開(kāi)展前景CdTe薄膜太陽(yáng)能電池具有本錢低，工藝制備簡(jiǎn)單，其吸收層與光譜最一致的優(yōu)點(diǎn)，是未來(lái)太陽(yáng)能電池開(kāi)展的方向First Solar公司是