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1、課程名稱：化學文獻及查閱方法 班級：化工一班 姓名：高秦 學號：50905031001數(shù)據(jù)庫：維普數(shù)據(jù)庫查找方式：關(guān)鍵詞：二氧化鈦，降解有機物作者：孫根行 蔡祥 俞從正 王全杰出處：中國皮革 2006年 第9期題目：TiO2光催化降解有機物及其在制革廢水處理中的應用展望摘要：介紹了TiO2光催化降解有機物的基本原理,總結(jié)國內(nèi)外TiO2光催化劑,尤其是納米TiO2光催化劑降解有機物的研究現(xiàn)狀,并對TiO2光催化技術(shù)在制革廢水處理中的應用進行展望關(guān)鍵詞：二氧化鈦，納米，光催化降解，制革廢水，有機物數(shù)據(jù)庫：維普數(shù)據(jù)庫查找方式：關(guān)鍵詞：二氧化鈦，降解有機物作者：劉淑杰 尹篤林 馬銘 銀董紅出處 ：化工

2、環(huán)保 2004年 第1期題目：二氧化鈦的改性及其對降解水中有機污染物的促進作用摘要：綜述了TiO2光催化劑的改性方法及其對光催化降解水中有機污染物的促進作用，介紹了復合物、煅燒溫度、摻雜量、摻雜金屬離子的種類和濃度對TiO2光催化性能的影響。關(guān)鍵詞：二氧化鈦，改性，光催化降解，有機物數(shù)據(jù)庫：中國知網(wǎng)查找方式：關(guān)鍵詞：二氧化鈦，降解，有機物作者：江紅； 戴春愛出處：北方交通大學學報 , 2003年06期題目：納米TiO_2光催化降解技術(shù)在污水處理方面的研究進展摘要：光催化技術(shù)是一種新興的高效節(jié)能現(xiàn)代污水處理技術(shù),目前還處于實驗研究階段.本文綜述了TiO2光催化降解水中有機物技術(shù)的近況,討論了催化

3、劑顆粒度、pH值、表面改性、載體、外加氧化劑對其光催化活性的影響,還概述了有機物結(jié)構(gòu)及其它因素與降解效果的關(guān)系關(guān)鍵詞：催化化學； 二氧化鈦； 光催化降解； 有機物； 影響因素數(shù)據(jù)庫：中國知網(wǎng)查找方式：關(guān)鍵詞：二氧化鈦，降解，有機物作者：陳浩春；出處：市場周刊, 2009年12期題目：TiO2光催化降解水環(huán)境中有機污染物的研究進展摘要：應用半導體TiO2催化降解環(huán)境中常見的有機污染物是一種有效的處理技術(shù)。本文對TiO2的光催化機理、光催化活性TiO2的性質(zhì)、影響光催化的內(nèi)素外因等進行了討論,并就其在廢水處理等環(huán)境保護方面的應用作了綜述。 關(guān)鍵詞：有機污染物； 二氧化鈦； 光催化； 降解

4、； 催化劑；數(shù)據(jù)庫：ACS Publications查找方式：關(guān)鍵詞：TiO2，degradation，organic作者：Wenxin Dai, Xuxu Wang, Ping Liu, Yiming Xu, Guangshe Li, and Xianzhi Fu出處：Research Institute of Photocatalysis, Chemistry and Chemical Engineering College, Fuzhou University, Fuzhou 350002, P. R. China題目：Effects of Electron Transfer betwe

5、en TiO2 Films and Conducting Substrates on the Photocatalytic Oxidation of Organic Pollutants摘要：TiO2 films on Al alloy (Al), indium-tin oxide glass (ITO/glass), and glass were prepared by a dip-coating method. ITO is found to have a higher work function, while the work function for Al is lower than

6、that of TiO2 films. An electron transfer is indicated to occur in the interfaces between TiO2 films and conducting substrate Al or ITO, which results in an Ohm contact or Schottky barrier under the transient equilibrium UV radiation conditions. Photocatalytic measurements showed that the TiO2 films

7、on Al have a higher activity for photocatalytic oxidation of C2H4, but the activity for photocatalytic degradation of oleic acid is lower as compared with TiO2 films on glass. Alternatively, TiO2 films on ITO give completely contrary photocatalytic performance to those on Al. These observations coul

8、d be associated with the electron transfer, in which Al acts as an electron donor and offers electrons to TiO2, allowing photocatalytic oxidation of ethylene to proceed by the photogenerated electrons, while ITO could be an acceptor for the photogenerated electrons, which is beneficial to photocatal

9、ytic degradation of oleic acid by the photogenerated holes. This electron-transfer model could be extended to other photocatalytic systems.數(shù)據(jù)庫：ACS Publications查找方式：關(guān)鍵詞：TiO2，degradation，organic作者：Hyunwoong Park and Wonyong Choi出處：J. Phys. Chem. B, 2005, 109 (23), pp 1166711674題目：Photocatalytic Reacti

10、vities of Nafion-Coated TiO2 for the Degradation of Charged Organic Compounds under UV or Visible Light摘要：Nafion (perfluorinated polymer with sulfonate groups)-coated TiO2 particles (Nf/TiO2) were prepared and their reactivities for the photocatalytic degradation (PCD) of charged organic substrates

11、were investigated. The presence of Nafion adlayers drastically changed the positive TiO2 surface charge to a negative one over the entire pH range and significantly influenced the PCD kinetics and mechanisms. The UV-induced PCD of tetramethylammonium (TMA; cationic substrate) was greatly enhanced in

12、 the presence of Nafion adlayers on TiO2 because the ion-exchange sites within the Nafion can hold cationic substrates. On the other hand, despite the unfavorable electrostatic interaction between the Nf/TiO2 and anionic substrates, the PCD of dichloroacetate (DCA) and acid orange 7 (AO7) with Nf/Ti

13、O2 was not significantly inhibited. The visible-light-sensitized degradation of dyes was enhanced with Nf/TiO2 not only for cationic dyes (methylene blue (MB) and rhodamine B (RhB) whose uptake on Nf/TiO2 is enhanced, but also for an anionic dye (AO7) that is less adsorbed on Nf/TiO2. The unexpected

14、 behavior in AO7 degradation seems to be related to the role of the Nafion layer in retarding the charge recombination. These observations indicate that Nf/TiO2 can enhance the PCD reactivity for cationic substrates without sacrificing the PCD reactivity for anionic substrates. In addition, it was f

15、ound that the sensitized degradation of RhB followed a different path when the surface of TiO2 was coated with Nafion. The N-de-ethylation of RhB that leads to the generation of rhodamine-110 was a prevailing path with Nf/TiO2, whereas the cleavage of the chromophoric ring structure was dominant wit

16、h pure TiO2. The effects of Nafion adlayers on the photoinduced electron transfer and PCD kinetics and mechanisms are discussed.數(shù)據(jù)庫：SpringerLink查找方式：關(guān)鍵詞：TiO2，degradation，organic作者：Chenzhong Jia, Yanxin Wang, Caixiang Zhang and Qiaoyan Qin出處：Water, Air, & Soil Pollution Volume 217, Numbers 1-4, 3

17、75-385, DOI: 10.1007/s11270-010-0594-7 題目：UV-TiO2 Photocatalytic Degradation of Landfill Leachate 摘要：Mature landfill leachate contains some macromolecular organic substances that are resistant to biodegradation. The photocatalytic process helps to enhance biodegradability of landfill leachate. Batch

18、 experiments were employed to determine the optimum conditions for removal of organic matter by UV-TiO2 photocatalysis. Under optimum conditions, the removal of chemical oxygen demand (COD), dissolved organic carbon (DOC), biological oxygen demand (BOD), and color was determined. Moreover, gas chrom

19、atography coupled with mass spectrometry (GC/MS) was used to analyze the organic matter in the treated leachate before and after treatment by the photocatalysis. The experimental results indicated that the removal of COD, DOC, and color by UV-TiO2 photocatalysis could reach above 60%, 70% and 97%, r

20、espectively. Under optimal conditions, the ratio of biological oxygen demand (BOD)/chemical oxygen demand (COD) was elevated from 0.09 to 0.39, representing substantial improvement in biodegradability. GC/MS analysis revealed that 37 out of 72 kinds of organic pollutants in the leachate remained aft

21、er 72 h treatment. Esters were produced during photocatalytic process and ketones, hydrocarbons, aromatic hydrocarbons, hydroxybenzenes, and acids were easier to be degraded during photocatalytic oxidation processes. The UV-TiO2 photocatalysis systems proposed may be a cost-effective approach f

22、or pre-treatment of landfill leachate.數(shù)據(jù)庫：SpringerLink查找方式：關(guān)鍵詞：TiO2，degradation，organic作者：Jinglong Zhang, Huasheng Xu, Haijun Chen and Mazakazu Anpo出處：Research on Chemical Intermediates Volume 29, Numbers 7-9, 839-848, DOI: 10.1163/156856703322601843 題目：Study on the formation of H2O2 on TiO2 photoca

23、talysts and their activity for the photocatalytic degradation of X-GL dye 摘要：Titanium dioxide (TiO2) nanoparticles of both anatase and rutile phases were synthesized by hydrothermal treatment of microemulsions, and their photocatalytic activity for the degradation of X-GL dye was investigated. The o

24、nly difference between the two methods used was that different acids were added to the microemulsions to make a direct comparison of the photocatalytic activity of the polymorphs possible. UV Vis reflectance and XRD spectroscopic investigations of these titanium dioxides indicated that a rutile stru

25、cture could be formed (PR) when hydrochloric acid was used, and anatase formed (PA) when nitric acid was used. The activity of the two polymorphs and P-25 for the photocatalytic degradation of dye in water was also examined. It was found that P-25 consisting of anatase and rutile has the highest act

26、ivity, and PR consisting of rutile has the lowest. Photodegradation of X-GL in the presence of these different TiO2 particles under air-equilibrated controlled conditions led to the formation of hydrogen peroxide. The formation rate of H2O2 depended on the difference in crystalloid phase. These resu

27、lts indicate that the observed differences in the photocatalytic activity for the three TiO2 photocatalysts are directly related to the formation rate of H2O2.數(shù)據(jù)庫：sciencedirect查找方式：關(guān)鍵詞：TiO2作者：yanjun xin出處：a College of Resource and Environment, Qingdao Agricultural University, Qingdao 266109, Chinab

28、School of Municipal and Environmental engineering, Harbin Institute of Technology, Harbin 150090, China題目：Study on preparation and photocatalytic degradation of alachlor on TiO2/Ti photoelectrodes prepared by microarc oxidation method摘要：Wormhole-shaped TiO2/Ti photoelectrodes were prepared by microa

29、rc oxidation method in H2SO4 solution. The morphology and structure were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The photocatalytic (PC) activity of TiO2/Ti photoelectrodes was evaluated by the degradation rates of alachlor in aqueous solution. All results sh

30、owed that their porous increased with the anodization voltage, and the crystal structure transferred from anatase to rutile TiO2. The photoelectrodes, which were anodized 10 min at 160 V in 0.5 M H2SO4 solution, were composed of mixed crystal structures of anatase and rutile TiO2 and have optimal PC

31、 performance. Alachlor was almost completely removed by TiO2/Ti photoelectrodes after 120 min under the illumination of 150W xenon light數(shù)據(jù)庫：sciencedirect查找方式：關(guān)鍵詞：TiO2作者：Pengwei Huo, Yongsheng Yan, Songtian Li, Huaming Li, Weihong Huang出處：a School of Chemistry & Chemical Engineering, Jiangsu Univ

32、ersity, Jiangsu, Zhenjiang 212013, PR Chinab School of Environment, Jiangsu University, Jiangsu, Zhenjiang 212013, PR Chinac School of Chemistry & Chemical Engineering, Pingdingshan Uinversity, Pingdingshan 467000, PR China題目：Preparation of poly-o-phenylenediamine/TiO2/fly-ash cenospheres and its photo-degradation property on antibiotics摘要：A series of poly-o-phenylenediamine/TiO2/fly-ash cenospheres(POPD/TiO2/fly-ash cenospheres) composites have been prepare